Hask Waki Masu Naka Even Laul A&E Boyn T&M W&K A&G A&G Palm M&S 68/71 1971 1973 1974 1978 1979 1982 1985 1985 1988 1989 ×1.36 1988 1995 OC OC OC(L6) OC CI OC CI vfCI vfCI OC CI vfCI CI CI Y 1.96 1.44 2.1 1.8 1.56 2.12 1.57 1.57 La 0.332 0.34 0.378 0.329 0.2446 0.34 0.236 0.31 0.367 0.29 0.2347 0.319 0.245 0.237 Ce 0.876 0.91 0.976 0.865 0.6379 0.85 0.616 0.808 0.957 0.763 0.6032 0.82 0.638 0.613 Pr 0.112 0.121 0.09637 0.12 0.0929 0.122 0.137 0.117 0.0891 0.121 0.096 0.0928 Nd 0.6 0.64 0.716 0.63 0.4738 0.64 0.457 0.6 0.711 0.572 0.4524 0.615 0.474 0.457 Sm 0.183 0.195 0.23 0.203 0.154 0.195 0.149 0.195 0.231 0.183 0.1471 0.2 0.154 0.148 Eu 0.0685 0.073 0.0866 0.077 0.05802 0.073 0.056 0.0735 0.087 0.069 0.056 0.0761 0.058 0.0563 Gd 0.252 0.26 0.311 0.276 0.2043 0.26 0.197 0.259 0.306 0.249 0.1966 0.267 0.204 0.199 Tb 0.047 0.047 0.03745 0.047 0.0355 0.0474 0.058 0.043 0.0363 0.0493 0.037 0.0361 Dy 0.317 0.3 0.39 0.343 0.2541 0.3 0.245 0.322 0.381 0.302 0.2427 0.33 0.254 0.246 Ho 0.07 0.078 0.0567 0.078 0.0547 0.0718 0.0851 0.0693 0.0556 0.0755 0.057 0.0546 Er 0.201 0.2 0.255 0.225 0.166 0.2 0.16 0.21 0.249 0.198 0.1589 0.216 0.166 0.16 Tm 0.03 0.032 0.02561 0.032 0.0247 0.0324 0.0356 0.03 0.0242 0.0329 0.026 0.0247 Yb 0.207 0.22 0.249 0.22 0.1651 0.22 0.159 0.209 0.248 0.2 0.1625 0.221 0.165 0.161 Lu 0.0325 0.034 0.0387 0.0339 0.02539 0.034 0.0245 0.0322 0.0381 0.03 0.0243 0.033 0.025 0.0246 "1)  Haskin L. A., Wildeman T. R., and Haskin M. A. (1968) ""An accurate procedure for the determination of the rare earths by neutron activation"" Journal of Radioanalytical Chemistry 1, 337-348." "Haskin L. A., Helmke P. A., Paster T. P., and Allen R. O. (1971) ""Rare earths in meteoritic, terrestrial, and lunar matter"" In Activation Analysis in Geochemistry and Cosmochemistry, A. Brunfelt and E. Steinnes, eds., Proc. NATO Conf. on Activation Analysis in Geochemistry, pp. 201-218, Universitetsforlaget, Oslo." Composite of nine (ordinary?) chondrites; error-weighted mean of 1968 and 1971 analyses "2)  Wakita H., Rey P., and Schmitt R. A. (1971) Elemental abundances of major, minor, and trace elements in Apollo 11 lunar rocks, soil and core samples. Proceedings of the Apollo 11 Lunar Science Conference, 1685-1717." """composite of 12 chondrites,"" data in caption to Fig. 1" "3)  Masuda A., Nakamura N., and Tanaka T. (1973) ""Fine structure of mutually normalized rare-earth patterns of chondrites"" Geochimica et Cosmochimica Acta 37, 239-248." """Leedy"" (Leedey) chondrite (L6). Note that LL chondrites have high REE concentrations compared to H and L chondrites [Fig. 1, W&K (1988)]." "4)  Nakamura N. (1974) ""Determination of REE, Ba, Fe, Mg, Na, and K in carbonaceous and ordinary chondrites"" Geochimica et Cosmochimica Acta 38, 757-775." Average of ten ordinary chondrites "5)  Evensen N.M., Hamilton P.J., and O'Nions R.K. (1978) ""Rare-earth abundances in chondritic meteorites"" Geochimica et Cosmochimica Acta 42, 1199-1212." """CI avg."", best estimate of unfractionated chondrites, many literature analyses. The data averaged include data for normalized ordinary chondrites." "6)  Laul J.C. (1979) ""Neutron activation analysis of geologic materials"" Atomic Energy Review 17, 603-695. (Fig. 20 caption, p. 683)" "Same as values of Wakita et al. (1971), except for Ce" "7)  Anders E. and Ebihara M. (1982) ""Solar-system abundances of the elements""" "Geochimica et Cosmochimica Acta 46, 2363-2380.  (Table 6)" "Essentially, values of Evensen et al. (1978) divided by 1.0366, except Tb (/1.055)" "These values also favored by Wasson J.T. (1985) Meteorites: Their Record of Early Solar-System History, 267 pp., Freeman, New York. (Table D-1) and Wasson and Kallemeyn (1988) ""Composition of chondrites,"" Philosophical Transactions of the Royal Society A 325, 535-544." "8)  Boynton W. V. (1985) Chapter 3. Cosmochemistry of the rare earth elements: Meteorite studies, In Rare Earth Element Geochemistry (P. Henderson, ed.), (Developments in Geochemistry 2), pp. 115-1522, Elsevier, Amsterdam." Values of Evensen et al. multiplied by 1.267 to be consistent with the average values of Haskin et al. (1968) and Wakita et al. (1972) "9)  Taylor S. R. and McClennan S. M. (1985) The Continental Crust: Its Composition and Evolution Blackwell, Oxford. 312 pp. " "Values of Evensen et al. multiplied by 1.5 [""type 1 carbonaceous chondrite (volatile-free: 1.5× original data)""]" "These values are are distinctly higher than any of the other ""volatile-free"" values (Fig. 2)." "10) Wasson J. T. and Kallemeyn G. W. (1988) ""Compositions of chondrites"" Philosophical Transactions of the Royal Society A 325, 535-544." "I never actually seen these values used; I include them here only for reference. W&K (1988) list means for H, L, and LL chondrites (Fig. 1). It's not clear from the paper what data were averaged. I have averaged their means with a 45.8% H, 39.7% L, and 14.6% LL weighting. These are the relative abundance ratios at this writing for ~32,000 ordinary chondrites listed in the Meteoritical Bulletin Database of the Meteoritical Society. Note that the agreement is good with the original OC data of columns 1 and 2." "11)  Anders E. and Grevesse N. (1989) ""Abundances of the elements: Meteoritic and solar""" "Geochimica et Cosmochimica Acta 53, 197-214." """Mean C1 Chondr."" of Table 1" 12)  Values of Anders & Grevesse times 1.3596.   This factor gives Sm = 0.2000 µg/g and results in values for all REE in the vicinity those for the early ordinary chondrite composites. Some references in which this approach is taken are listed below: "Korotev R. L. (1996) A self-consistent compilation of elemental concentration data for 93 geochemical reference samples. Geostandards Newsletter 20, 217–245." "Korotev R. L. (1996) On the relationship between the Apollo 16 ancient regolith breccias and feldspathic fragmental breccias, and the composition of the prebasin crust in the Central Highlands of the Moon. Meteoritics and Planetary Science 31, 403–412. 13)  Palme. H. (1988)" """ Chemical abundances in meteorites""" "Reviews in Modern Astronomy (G. Klare, editor), Springer, Berlin pp. 28-51." These are the author's data for the Orgueil CI chondrite. "14)  McDonough W. F. and Sun S.- s. (1995) "" The composition of the Earth"" Chemical Geology 120, 223–253." These data are averages for CI chondrites based on data of the previously publshed means and new data. ##### Sheet/List 2 ##### ELEMENT SiO2 Al2O3 Fe2O3 MgO CaO Na2O K2O TiO2 P2O5 MnO Cr2O3 Ni Sc LOI TOT/C TOT/S SUM SAMPLES % % % % % % % % % % % ppm ppm % % % % MB1-1 75.72 13.60 .62 .02 .94 4.03 4.69 .03 .02 .12 .002 6 2 .4 .03 <.01 100.19 MB1-52 74.90 14.09 .71 .02 1.11 4.21 4.61 .03 .04 .13 <.001 7 2 .3 .03 .03 100.15 MB1-55 74.61 13.83 .93 .03 1.10 3.82 4.94 .03 .05 .32 <.001 8 3 .5 .05 <.01 100.17 WILK 48.17 10.37 7.44 13.03 9.12 1.11 5.80 .97 2.46 .11 .143 28 29 1.3 .03 <.01 100.04 RE WILK 48.10 10.31 7.58 13.06 9.04 1.09 5.73 .97 2.50 .11 .144 27 29 1.4 .03 <.01 100.04 ELEMENT Ba Be Co Cs Ga Hf Nb Rb Sn Sr Ta Th U V W Zr Y La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu SAMPLES ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm MB1-1 16.9 3 <.5 3.9 18.0 4.5 28.0 182.0 2 13.3 4.0 12.5 6.9 <5 .4 66.9 45.5 2.3 5.7 .75 3.4 1.85 .14 2.91 .76 5.79 1.35 4.91 1.02 7.30 1.35 MB1-52 3.7 3 <.5 3.1 18.5 6.3 11.2 180.3 2 13.4 2.0 14.5 5.8 <5 .4 101.6 64.3 2.3 5.9 .92 4.9 2.15 .17 3.58 .94 7.56 1.90 7.34 1.47 10.42 1.95 MB1-55 30.9 3 <.5 2.9 18.0 6.8 12.8 170.4 2 21.6 2.1 18.0 7.9 <5 .2 107.7 116.0 3.0 8.5 1.25 5.9 2.93 .18 5.62 1.66 12.97 3.14 11.32 2.24 15.90 2.75 WILK 1052.8 5 35.9 12.7 11.7 1.7 5.3 582.3 2 181.5 .3 7.8 3.4 341 .2 60.3 26.8 25.5 64.8 9.51 43.8 10.14 1.47 7.85 1.08 5.36 .88 2.27 .33 1.77 .27 RE WILK 1075.5 7 36.8 12.7 11.8 1.7 5.7 599.9 2 185.6 .3 5.9 3.5 347 .2 60.4 27.4 26.5 68.0 9.71 47.3 10.45 1.53 8.06 1.09 5.74 .96 2.32 .35 1.78 .28 ##### Sheet/List 3 ##### normalizace prvků vzácných zemin normalizace chondritem obsahy REE a Y v chondritu mol hm La 0.237 ppm 138.91 Ce 0.613 ppm 140.12 Pr 0.093 ppm 140.91 Nd 0.457 ppm 144.24 Sm 0.148 ppm 150.36 Eu 0.056 ppm 151.96 Gd 0.199 ppm 157.25 Tb 0.036 ppm 158.93 Dy 0.246 ppm 162.5 Ho 0.055 ppm 164.93 Er 0.160 ppm 167.26 Tm 0.025 ppm 16893 Yb 0.161 ppm 173.04 Lu 0.025 ppm 174.96 Y 1.570 ppm 88.91 monazit P2O5 CaO ThO2 UO2 SiO2 PbO Y2O3 La2O3 Ce2O3 Pr2O3 Nd2O3 Sm2O3 Eu2O3 Gd2O3 Dy2O3 Er2O3 Yb2O3 30.817 1.657 8.131 0.946 0.3 0.166 0.866 11.803 27.101 3.142 10.777 2.186 0.035 1.168 0.385 0.068 0.02 30.813 2.654 10.439 0.926 0.306 0.219 0.992 10.775 25.221 2.835 10.42 2.461 0.045 1.603 0.558 0.031 0.015 30.439 0.262 1.097 0.186 0.375 0.051 0.075 23.803 33.711 2.639 6.898 0.51 0.02 0.159 0 0.066 0.022 30.211 3.341 16.036 2.251 0.423 0.334 2.21 7.366 19.947 2.445 9.111 2.789 0.117 1.745 1.041 0.146 0.05 30.79 1.667 8.734 0.644 0.359 0.173 0.946 10.6 23.302 2.728 10.406 2.315 0.095 1.484 0.605 0.098 0.03 25.722 0.275 13.523 0.746 3.252 0.211 0.115 18.58 26.921 2.185 6.699 0.661 0.02 0.124 0 0.034 0.015 xenotim Comment P2O5 SO3 CaO La2O3 Ce2O3 PbOcorr ThO2 UO2 korr Y2O3 As2O5 ZrO2 Al2O3 SiO2 Yb2O3 Er2O3 Dy2O3 Gd2O3 Sm2O3 Nd2O3 MnO Fe2O3 Sc2O3 Tb2O3 Ho2O3 Tm2O3 Lu2O3 P136 32.187 0.203 0.81 0 0.028 0.050785189 0 0.679525012 37.5 1.099 0.505 0 0.252 2.238 3.071 6.848 5.306 1.3 0.337 0.01 3.256 0.084 0.986 1.156 0.572 0.401 P136 31.366 0.205 0.793 0.012 0.03 0.037569679 0.021 0.709930523 37.103 1.106 0.486 0 0.352 2.125 2.962 6.696 5.2 1.276 0.341 0.014 5.495 0.07 0.92 1.14 0.522 0.373 P136 30.867 0.181 0.785 0.009 0.017 0.012592876 0.009 0.632918898 37.565 1.108 0.449 0 0.259 2.163 3.045 6.806 5.304 1.299 0.305 0.011 3.046 0.077 1.002 1.114 0.563 0.35 P136 30.525 0.171 0.784 0.026 0.022 -0.000935886 0 0.660239661 36.925 1.111 0.472 0 0.331 2.173 2.964 6.646 5.097 1.274 0.365 0.009 4.435 0.074 0.973 1.193 0.567 0.379 P136 30.965 0.197 0.784 0 0.015 0.014240522 0.021 0.665699457 37.488 1.038 0.468 0 0.217 2.203 3.079 7.013 5.313 1.301 0.356 0.072 2.235 0.07 1.039 1.125 0.622 0.431 ##### Sheet/List 4 ##### zivce Na2O SiO2 Al2O3 BaO P2O5 K2O CaO SrO Total 3.14 49.84 31.38 0.00 0.00 0.12 14.35 0.32 99.17 2.94 49.60 31.83 0.00 0.00 0.15 15.00 0.36 99.93 2.96 50.22 31.46 0.00 0.00 0.14 14.52 0.32 99.66 6.13 56.89 27.01 0.00 0.00 0.25 8.84 0.31 99.45 5.40 55.38 27.68 0.00 0.02 0.18 10.25 0.26 99.18 0.34 43.42 36.04 0.00 0.02 0.03 19.80 0.28 99.98 0.85 44.73 34.97 0.00 0.02 0.00 18.44 0.26 99.26 0.57 44.12 35.56 0.00 0.02 0.03 19.42 0.23 99.93 4.64 53.82 29.01 0.00 0.01 0.11 11.57 0.23 99.40 6.63 56.95 26.70 0.11 0.00 0.22 8.59 0.41 99.78 7.31 59.38 25.90 0.12 0.00 0.24 7.27 0.41 100.73 slidy dopocet OH DataSet/Point TiO2 K2O FeO MnO Na2O SiO2 Al2O3 MgO F Total 1 / 1 . 2.03 9.71 21.20 0.20 0.10 34.63 20.09 7.72 0.25 95.93 2 / 1 . 2.02 10.00 20.91 0.14 0.08 34.38 20.31 7.59 0.20 95.63 13 / 1 . 2.61 9.80 23.55 0.23 0.16 34.13 20.34 5.58 0.25 96.66 48 / 1 . 0.64 9.36 0.99 0.02 1.67 46.07 36.14 0.57 0.12 95.58 49 / 1 . 3.18 9.82 19.02 0.13 0.13 34.70 19.66 8.50 0.29 95.42 50 / 1 . 2.45 9.97 18.39 0.09 0.09 35.48 20.01 9.03 0.38 95.90 dopocet CO2 CaO FeO MgO MnO SrO SiO2 Total 0.670 8.889 40.385 0.000 0.000 0.000 49.944 0.812 8.486 40.527 0.000 0.000 0.000 49.825 54.349 1.439 0.446 0.143 0.068 0.000 56.445 54.235 1.556 0.310 0.074 0.093 0.000 56.268 54.287 1.232 0.357 0.143 0.000 0.000 56.019 56.006 0.201 0.145 0.000 0.129 0.000 56.481 30.255 0.240 21.723 0.000 0.000 0.000 52.218 9.088 16.958 2.159 32.290 0.000 0.000 60.495