The course is also offered to the students of the fields other than those the course is directly associated with.
Fields of study the course is directly associated with
there are 14 fields of study the course is directly associated with, display
Course objectives
This course is a logical counterpart of the lecture Structure and Reactivity. It discusses all the details of the chemical transformations and at the same time the physico-chemical methods which are used for the mechanism elucidation.
Syllabus
1. Art of writing the reaction mechanism.
2. How chemistry studies the reaction mechanisms.
3. Reactive intermediates. Radicals, carbebes, nitrenes etc.
4. Pericylic reactions. Selection rules.
5. Nucleophilic aliphatic and aromatic substitution.
6. Eliminations.
7. Electrophilic aromatic substitution.
8. Additions to C=C bond.
9. Reactions of carbonyl compounds
10. Rearrangements.
11. Free radical reactions.
12. Oxidation and reductions.
13. Transient metal catalysis.
14. Photochemical reactions.
Literature
O. Červinka: Mechanismy organických reakcí. SNTL/ALFA, Praha 1981.
A: Jurášek: Fyzikálne princípy a mechanizmy organických reakcií. Veda, Bratislava 1989.
F. A. Carey, R. J. Sundberg: Advanced Organic Chemistry, 3rd edition, Parts A and B. Plenum Press, New York, 1993.