FOSSIL FUELS: OIL AND NATURAL GAS (+ UNCONVENTIONAL SOURCES) Filip Černoch ESS411 – Environmental aspects of energy Exploration and production of oil  Onshore  Limited impacts – considerable experience, physically limited possibility of spillage  Impacts similar to mining operations in non-energy industry – land use, water and air pollution, dust, noise, transportation damages of habitats.  Long history of regulation in the EU and USA 2 Exploration and production of oil Offshore  Complicated technology increases the risk of accidents and consequent damages due to the hostile environmental conditions  Worse impacts of oil spillages (1m3 = spillage up to 1km2)  Increase in a number of off-shore installations accompanied by more stringent regulation (2010 Gulf of Mexico - Directive 2013/30/EU on safety of offshore oil and gas operations) 3  Klasická ropa, liší se schopností migrovat v hornině.  IEA: konvenční ropa: směs uhlovodíků, existující za normálních povrchových podmínek v kapalném skupenství (vzlínání), nekonvenční ropa je ta, kterou je třeba získávat za pomocí nekonvenčních technologií, protože v přirozeném stavu ji nelze (bez zahřívání či ředění) těžit.  Těžká a velmi těžká ropa  Bitumen (ropné písky)  Kerogen (břidličná ropa)  Ropa z velkých hloubek, biopaliva, ropa získávána konverzí uhlí a zemního plynu (Fischer-Tropschova syntéza).  Hranice jsou prostupné. 4 Unconventional oil  = produced or extracted using techniques other than the conventional (oil well) methods.  Conventional crude: mineral oil consisting of a mixture of hydrocarbons of natural origin, exists in liquid form under normal surface temperatures and pressure, unconventional oil: to be extracted non-conventional technology is needed, in natural state (without heating or diluting) couldn´t be extracted.  Oil sands  Tight oil  Oil shale  Oil produced from coal  … 5 Oil sands, tight oil, oil shale…  Consistency – extremely dense and viscous, almost solid.  High level of sulphur and metals (nickel, vanadium).  Venezuela – Orinoco Belt (1200 bn. barrels = approximately equal the world´s reserves of lighter oil, 200 billion barrels technically recoverable)  Alberta, Canada – reserves of 1700 -250 bn. barrels (11 % of world oil reserves, 3rd on the world), 99 % oil sands. Export around 2 mil. barrels/day. 6 7 Producing techniques  In – situ mining (Oil shale-kerogen). Injecting hot fluids (or steam) into the rock formation, shale oil is recovered through vertical wells. Increased water and energy (natural gas) consumption. 2-4 barrels of water/1 barrel of oil, 70-90% could be recycled. Steam-Assisted Gravity Drainage (SAGD) 8 Producing techniques  Open pit (ex-situ) mining (max 70m) (oil sand-bitumen, also shale oil). Excavation, when sand is cooped out by power shovels, carried away, then hot water is used to separate bitumen from the sand. Then it is refined. 8-10 barrels of water/1 barrel of oil, 40 – 70% could be recycled. About 2 (but up to 4) tons of material/1 barrel of oil. 1,5x more GHG then in case of conventional crude oil.  EROI cca 5:1  http://www.youtube.com/watch?v=YkwoRivP17A 9 Shale gas  Natural gas (= clean fuel) trapped within shale formations.  Fracking – combination of horizontal drilling and hydraulic fracturing.  High consumption of water, 0,5-2% of injected liquid represents added chemicals.  One well – 280 000 hl of water.  2-4 hectares/1 drilling pad (= up to 30 wells), 3-6km between pads.  Transport – one well/700-2000 trucks (during installation one car every 4 minutes)  Methane leackages, earthquakes.  https://www.youtube.com/watch?v=Ag9GUogWEa0 10 Shale gas 11 EROEI of different sources of energy 12 Oil in the beginning of oil business 100 Oil in Texas around 1930 60 Oil in the Middle East 30 Other oil 10-35 Natural gas 20 High quality coal 10-20 Low quality coal 4-10 Water power plants 10-40 Wind power plants 5-10 Shale oil 5 PV power plants 2-5 Nuclear energy 4-5 Oil sands max. 3 Shale oil max. 1,5 Biofuels (in Europe) 0,9 - 4 Transport of oil  Dominated by marine transport (2/3 of world production vs. 1/3 transported by pipelines)  Liquid bulk carriers (tankers) – 77% of all tankers transport crude, 33 % oil and chemical products. 13 Transport of oil  One of the biggest threats in ship transportation – accident and oil spill. Intentional accidents (terorism, piracy), unintentional (accident, collision,, running ashore, failure of the ship).  Risk is significantly higher in highly frequent areas – in 1995-2005 in Turkish Straits 269 accidents.  To stop VLCC or ULCC tanker 14 minutes and 3km are needed.  In 70s there were 25,2 leaks annually, in 80s 9,3 leaks, in 90s 7,8 and after 2000 3,4 leaks annually.  But with increasing capacity of tankers the oil spills are more severe with increasing environmental impacts. 14 Oil accidents  Exxon Valdez – 3/1989 at Alaska, 37 000 tons of oil leaked. Impacts still visible.  Deep Water Horizon – 2010, at Louisiana. Oil spill almost 10 000 km2. 15 Cleanup and recovery  Bioremediation – use of microorganisms or biological agents (bacterias) to break down oil  Controlled burning – air pollution  Dispersants – to dissipate oil slick.  Wath and wait.  Solidifying – changing the physical state of spilled oil from liquid to a semi-solid.  Skimming  = usually no more than 20% of oil is re-captured. 16