Composites Chemically bonded mixture of organic matrix (resin) ane inorganic filler 00 0 x 1—~~ o o Composition • Organic phase - resin Bowen's monomer - bisfenol A a glycidylmetacrylate- Bis GMA Other dimetacrylate UDMA TEGMA 3 Composition • Inorganic phase - filler Milled qua Baryumaluminium glass Silica Prepolymer 6284 4 Composition • Initiatory system initiator a activator • Stabilizers • Pigments • UV absorbers • Antioxidants 5 Curing of com Polymerization Activator Iniciátor Splitting of double bonds Creation of the polymer network Composite according to mode of curing öDChemically curing öDLight curing fíDDual curing fíDWarm curing o v°o\ o < 0VA o Polymerization Monomer Polymer '@l irrn, m, to© Polymerization shrinkage Pre -gel G-point Post -gel Classification according to type of fillers (Philips & Lutz 1984) Macrofiller Macrofiller Composite Microfilier (pyrogenic Si02) Hybrid Composite homogenious Microfilier Composite Microfiller-complexes inhomogenious Microfiller-Composite Filler particles Filler size (medium particle size) Composite category < 10 |jm hybrid composite < 5 |jm fine particle hybrid < 3 |jm ultrafine particle hybrid < 1 |jm submicron hybrid Use of Composites • Aesthetic restorations • - class III., IV., V., I., II. Ablation of the aprismatic enamel Acid etching Dentin o More water and organic substances o Low surface energy o Tubular liquid o Comunication with the pulp chamber o Smear layer Removing of the smear layer Acid etching Konditioner Demineralization Increase of the surface energy Phosphoric acid Primer Opening og the collagen network of dentin Bond • Penetrates into the retentive pattern in enamel and the collagen network of dentin (hybrid layer) Glasionomer cements • Composition Powder: asluminiumsilicate glass Tekutina: Polyacrylic acid or polymaleic acid Tartaric acid Water Curing of GIC Aluminium calcium polyacrylate Properties > Chemical fixation to tooth structure > Fluoride release > Favorable thermal expansion > Acceptable aesthetics GIC according to mode of curing > Chemically curing (acid - base reaction) > - conventional > - high strength > Light curing (acid -base reaction + polymerization of the resin) LiUULS LOJ .[ľ® [/DCs GIC - indication • Class V, small class I., class III. • Base - sandwich fillings • Luting cements • Root canal filling Glasionomers • Hand mixed Check the mixing ratio - the drop without any bubbles • Power mixed - capsulated- aktiovation of a Capsula Forceps fo activation, forceps for application