Melt inclusions in migmatites Cesare et al. (2009) have described Ml in a regional anatectic terrane. Appear in many anatectic terranes. Very small, crystallized, "nanogranites". Melt inclusions in migmatites Melt inclusions in migmatites Melt inclusions, definition modified by Césare et al. (2015), to include those present in regional migmatites: Small droplets of melt that are trapped in minerals during their growth in the presence of a melt phase (Cesare et al. 2009, 2015). NANOGRANITOIDS Roedder(1979) Schiano (2003) Audétat & Lowerstern (2014) Frezzotti & Ferrando (2015) Melt inclusions in anatectic enclaves Grt-Bt-Sil Cesare et al. (1997), Cesare (2008) Melt inclusions in anatectic enclaves Melt inclusions in anatectic enclaves Melt inclusions in anatectic enclaves Acosta et al. (2007) Cesare et al. (1997), Cesare (2008) Melt inclusions in anatectic enclaves Inclusions in UHP crustal rocks Inclusions, reported by 2001 in high-grade crustal rocks, taken to mantle depths, i.e. UHP crustal rocks: Melt, polyphase or multiphase inclusions Stöckhertet al. (2001), Erzgebirge, Germany St 6102/2 Ll -09 Korsakov & Hermann (2006) Kokchetav, Kazakhstan Gao et al. (2001) Dabie-Sulu, China Lang & Gilotti (2007) Caledonian, Greenland Inclusions in UHP crustal rocks Inclusions, reported by 2001 in high-grade crustal rocks, taken to mantle depths, i.e. UHP crustal rocks: Melt, polyphase or multiphase inclusions Stóckhertet al. (2001), Erzgebi St 6102/2 Ll -09 0.01 mm 10 n 0 Wang etal. (2017) Korsakov & Hermann (2006) Kokchetav, Kazakhstan 1111111111111111111111111111111111111111111111111111111 500 600 700 800 900 Temperature (°C) & Gilotti (2007) Ionian, Greenland Primary vs secondary melt inclusions Cesare et al. (2015) See Roedder (1979) Bartoli etal. (2016) Stóckhertl et al. (2009) Melt inclusions in anatectic rocks versus volcanic rocks Melt inclusions in anatectic rocks represent primary melts produced at the source rocks of crustal granites upon melting Cesareet al. J Virt Expl (2011) & Bartoli etal. EPSL(2014) Melt inclusions in anatectic rocks versus volcanic rocks Melt inclusions in anatectic rocks represent primary melts produced at the source rocks of crustal granites upon melting 1 - Peritectic Ti entrapment of melt inclusions m -Migmatites, granulites -Enclaves and xenoliths in lavas -Host growth in solid framework -Entrapment during heating -Primary melt composition suprasolidus ^ 2 - Igneous t -Intrusive and extrusive rocks -Leucosomes in migmatites -Host growth in magma -Entrapment during cooling -Evolved melt composition Cesare et al. (2015) Identifying melt inclusions in migmatites 1. Optical microscope on regular, but well-polished, thin sections - Regular, crystal-negative shape, brownish color (at least 20x) - Polycristalline and/or glassy nature, multiple birefringent phases and/or isotropic Cesare et al. (2015) Identifying melt inclusions in migmatites 1. Optical microscope on regular, but well-polished, thin sections - Regular, crystal-negative shape, brownish color (a - Polycristalline and/or glassy nature, multiple birefringent phases and/or isotropic urn Cesare et al. (2015) Barich et al. (2014), Acosta-Vigil et al. (2016) Characterization of melt inclusions 2. SEM (Field Emission, 5-10 microns Ml) Cesareetal. (2015) Characterization of melt inclusions 2. SEM (Field Emission, 5-10 microns Ml) JU-8, core Bt (no Ti, Fe>Mg) 1/17/2013 WD Mag Spol HV Det HFW 1 3803 PM 10 0 mm4000x 50 20 0 kV SSD 64 00 urn low Zn-| Spl • 1 » o/1 PI («andesine) St 6102/2 LI-09 0.01 mm 1/15/2013 WD Mag Spol HV Del HFW 2:01 01 PM 10 0 min 2900X 5 1 20 0 kV SSD 88 28 prr 20 urn Bt Barich etal. (2014), Ronda 8.5kV X3.700 1pm WD 9.1 mm Ferrero etal. (2012), Himalaya Characterization of melt inclusions Kumdykolite, polymorph of albite Kokchetavite, polymorph of alkali feldspar Cristobilite, polymorph of quartz Ferrero etal. (2016) Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (pressure) - Prepare several thin sections from the rock under study (focus on Grt) - Identify the thin section with the most abundant and best preserved Ml (no offshots!) - Prepare double polished, >200 micron thick, sections - Select areas under the microscope rich in Ml, individualize Ml-rich areas. Ferrero etal. (2012) Bartolietal. (2016) Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (pressure) - Prepare several thin sections from the rock under study (focus on Grt) - Identify the thin section with the most abundant and best preserved Ml (no offshots!) - Prepare double polished, >200 micron thick, sections - Select areas under the microscope rich in Ml, individualize Ml-rich areas. Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (P) Australian National University, Canberra Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (P) Bartolietal. (2013) Mb I Thermocouple MgO-salt (0 = 10 mm) Au capsule (0 = 3 mm) Graphite heatei (0 = 12 mm) NaCl sleeve (0 = 22 mm) Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (P) b Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (P) ✓ WD Mag Spot HV Det HFW I0.0mm5215x 5.2 20.0 kVSSD 49.09 urn Acosta-Vigil etal. (2016) Bartolietal. (2013) Cesare etal. (2015) 20 jam 3/21/2014 WD Mag Spot HV Det HFW 12:14:36 PM 10.0 mm 2063x 5.0 20.0 kV SSD 0.12 mm Analysis of melt inclusions 4. Re-homogenization experiments: piston cylinder (P) Bartolietal. (2013)_ I Barich et al. (2014) Analysis of melt inclusions 5. Electron microprobe analyses (major elements) Comparison of melt inclusions with leucosomes in migmatites and granites intruded in the upper continental crust _i_i_i_i_,_i_i_i_i_i_i_i_._ 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1 Cesareetal. (2015) Analysis of melt inclusions 6. Laser ablation ICP-MS (trace elements) Australian National University, Canberra smaller beam diameter was 19 microns Analysis of melt inclusions 6. Laser ablation ICP-MS (trace elements) Oh a c 700 500 Li O MI in PI O MI in Grt H Mat gl enclaves I Mat gl dacites 0.0001 0.00001 • P° " O - o o _ □ t ft^Q) - HO-50A ................................. Cs Ba Li B U Ta Co Nd Zr Eu Gd Y Yh V Cu Sc Ni Rb Pb Be Th Nb La Sr Sm HI Ti Dy Er Lu Zn Cr Co 10 Primary Ml, glassy, leucogranitic, peraluminous, similar to gl in experiments. > Gl of each microstructural location: variable, distinctive, non eutectic. > H20 concentrations indicate H20-undersaturated anatexis. > Melt inclusions in PI and Grt represent former melt films in contact with crystals, remains of first anatectic melts we have access to for study. > Ml in PI, most heterogeneous and evolved compositions, lowest Zrn-Mnz saturation T. Matrix melt, more homogeneous and less compositionally evolved, highest Zrn-Mnz saturation T. Ml in Grt, in between both. > Differences among gl in several locations: not related to syn-, post-entrapment processes, likely reflecting matrix melt compositions at different T. > Melt inclusions analyzed in several crystals/enclaves: matrix melt with well defined LILE-rich, HFSE- and REE-poor geochemical character. Matrix melt likely at or close to equilibrium with the residue (except Grt). > Matrix glass: melts produced after Ml, mostly at or close to equilibrium with rims of most minerals (except Grt). Pedogenesis of crustal anatectic systems from the study of melt inclusions Pedogenesis of crustal anatectic systems from the study of melt inclusions Melt inclusions in granulites from the Betic Cordillera Ronda area S Spain < 5 km Malaguide complex <330°C Jubrique unit > 650°C Ronda peridotite Dynamothermal aureole Blanca unit j q Jubrique Unit Ron Metamorphic isograds Ronda Peridotite d Grt-Spl Spl tectonite Recrystallization mvlnnitp frnTLf Estepona MapbetTa " Alboran Sea Barich et al. (2014), Barich PhD (2015) - ?' 9 , ' I v. ■ :'V,'wt: ' y~ Field geology Petrography Petrography & SEM of the melt inclusions • :'.V<». p. Grt ■■t 20 urn 1 flT\» 1/17/2013 WD Mag Spot HV Det HFW 1:38:03 PM 10.0 mm 4000x 5.0 20.0 kVSSD 64.00 urn SEM of the melt inclusions Barich et al. (2014) P-T of host rocks Barich etal. (2014) Melt inclusions in granulites from the Betic Cordillera, Bonda area, S Spain Field geology, petrography, SEM * Melt inclusions are primary based on their distribution in the host garnet. Mostly crystallized. • They appear from core to rim of large garnets and hence most garnets grew in the presence of melt. • Melt inclusions were trapped both at peak conditions (12-14 kbar, 800-850°C; Grt cores) and post-peak conditions (5-6 kbar, 750-800°C; Grt rims+Matrix). * They appear to have granitic mineral compositions (daughter minerals are Qz, Fds, micas). Experimental remelting: rehomogenizion Experimental remelting: rehomogenizion 850 °C 4 Experiments 15 Kbar Dry (no added H20) 24h 825 °C 825 °C 800 °C Barich PhD (2014) Acosta-Vigil et al. (2016) Experimental remelting: SEM study Rehomogenized melt inclusions: having glass, and also - Rregular walls, - No daughter minerals, - No offshots, - No host recrystallization, - No reactions between melt-accidental minerals. Acosta-Vigil et al. (2016) Experimental remelting: EMPA study ff> 0.6 ^ 0.5 0.4, toiialite 0.3 Apjw8s 0.1 L ?ri""N-...A ^ramre \0.9 'tiondhje _^_ 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 albite Leucogranitic: plot close to water undersaturated haplogranitic eutectics Granodioritic to Tonalitic: plot close to Qz-Ab joint Two main compositions: -Leucogranites -Granodiorites to Tonalites Acosta-Vigil et al. (2016) # Haplogramtic eutectics at 0.5-2 GPaandajjjosl -----Cotectic lmes at 0.5 GPa H-,0 j Haplogramte-NaCl-KCl eutectics t} at 0.6 GPa, aH:0 - 0 86-0 35 £j at 1.0 GPa, aH:0- 0.63*34 £j at 1.4 GPa. aH:0-0.74-0.44 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 albite Experimental remelting: EMPA study Peraluminous High Si02 Low FeO+MgO+Ti02 Variable CaO, alkalis and H20 Leucogranitic: Low Ca, H20; high K Granodioritic to Tonalitic: high Ca, H20; low K Large Grt Rims .2 2 CaO O 800 °C n A 825 °C □ □ 850 °C H Cores of large Grt ■ Rims of large Grt □ Small Grt f WR mylonilic gneiss <^ WR leucosome □ a kO SiO, 60 65 70 4 75 —1-1-1-1-1-1-1-r CaO □ □ ä A# ' • A J J_i_I_i_I_i_L 0 12 3 4 Concentration (wt%) 1 1 1 1 1 1 1 1 ■ i i i i - v •J - 0 12 3 4 5 6 " K20 i,i, 5 6 7 CaO ~i—1—i—1—i—1—i—1—r b A O 8 10 CaO n—1—i—1—i—1—i—1—i—1—i—1—r ▲ Al A A °A H,0 i.i,_i_i_i_i_i_i_i_ 4 8 12 Concentration (wt%) 16 20 Jubrique granulites: Pedogenesis r iui iiuiu a akdown me CD Q_ o e =5 CO CD 600 700 800 900 1000 Acosta-Vigil et al. (2016) Temperature (°C) Jubrique granulites: Pedogenesis Type II Ml / Grt Rims: •Trapped in Grt rims P-T •Granodioritic-tonalitic compositions, high H20 ( mean of 10-12 wt%) •Composition and H20 content similar to melt in H20-present experimental melting of metapelites •Low F and CI, hence no brines involved 03 Q_ Ě =5 if)