prvek Ar prvek Ar prvek Ar Ag 107.8682 Cu 63.546 S 32.0675 As 74.9216 Fe 55.845 Sb 121.76 Bi 208.9804 Hg 200.59 Se 78.96 Cd 112.411 Mn 54.938045 Zn 65.38 Co 58.933195 Pb 207.2 Ni 58.6934 weight % detection limit ppm DataSet/Point Comment Ag S Pb Hg Cd Cu Fe Zn Ni Co Mn As Se Sb Total Ag S Pb Hg Cd Cu Fe Zn Ni Co Mn As Se Sb 13 / 1 . HB bl 22 0.03 33.57 0.08 0.00 0.05 0.00 6.77 60.02 0.01 0.00 0.19 0.12 0.00 0.00 100.82 2412 551 1686 1112 1281 -1 360 472 340 363 256 2291 0 0 14 / 1 . HB bl 22 0.00 33.29 0.00 0.06 0.02 0.00 6.61 60.19 0.00 0.00 0.20 0.00 0.00 0.04 100.43 1 585 0 1449 1273 474 358 478 -1 0 252 0 0 1552 hodnoty nad detekčním limitem M 32.0675 55.845 65.38 54.938045 DataSet/Point Comment S Fe Zn Mn total 13 / 1 . HB bl 22 33.57 6.77 60.02 0.19 100.54 14 / 1 . HB bl 22 33.29 6.61 60.19 0.20 100.30 n prvku 2 1 DataSet/Point Comment S Fe Zn Mn suma prvku koeficient normalizece koeficient normalizace 13 / 1 . HB bl 22 1.047 0.121 0.918 0.003 2.089 0.957203046 0.955214322 14 / 1 . HB bl 22 1.038 0.118 0.921 0.004 2.081 0.961129769 0.963161531 empirický vzorec normalizací na Σ prvku = 2 DataSet/Point Comment S Fe Zn Mn R2+ 13 / 1 . HB bl 22 1.002 0.116 0.879 0.003 0.998 14 / 1 . HB bl 22 0.998 0.114 0.885 0.003 1.002 empirický vzorec normalizací na S = 1 DataSet/Point Comment S Fe Zn Mn R2+ 13 / 1 . HB bl 22 1.000 0.116 0.877 0.003 0.996 14 / 1 . HB bl 22 1.000 0.114 0.887 0.004 1.004 ##### Sheet/List 2 ##### prvek Ar prvek Ar prvek Ar Ag 107.8682 Cu 63.546 S 32.0675 As 74.9216 Fe 55.845 Sb 121.76 Bi 208.9804 Hg 200.59 Se 78.96 Cd 112.411 Mn 54.938045 Zn 65.38 Co 58.933195 Pb 207.2 Ni 58.6934 Weight% Det.Lim ppm DataSet/Point Comment Ag S Pb Hg Cd Cu Fe Zn Ni Co Mn As Se Sb Total Ag S Pb Hg Cd Cu Fe Zn Ni Co Mn As Se Sb 11 / 1 . HB bl 22 0 21.5 0.06 0 0.027 0 35.531 0.007 0.152 0.024 0.008 42.74 0 0.088 100.137 -1 548 1743 0 1296 0 558 363 404 435 279 2813 0 1598 15 / 1 . HB bl 22 0.01 21.39 0.00 0.00 0.00 0.00 35.73 0.00 0.01 0.00 0.03 42.58 0.00 0.22 99.95 2223 527 0 0 -2 -1 560 0 398 0 266 2863 0 1576 hodnoty nad DL 32.07 55.85 58.69 54.94 74.92 121.76 DataSet/Point Comment Ag S Pb Hg Cd Cu Fe Zn Ni Co Mn As Se Sb total 11 / 1 . HB bl 22 0 21.5 0 0 0 0 35.531 0 0.152 0 0 42.74 0 0 99.923 15 / 1 . HB bl 22 0 21.393 0 0 0 0 35.725 0 0 0 0.027 42.583 0 0.215 99.943 n prvku 3 DataSet/Point Comment S Fe Ni Mn As Sb suma koef. 11 / 1 . HB bl 22 0.670460747 0.636243173 0.002589729 0 0.570462991 0 1.87975664 1.595951272 15 / 1 . HB bl 22 0.667124035 0.639717074 0 0.000491463 0.568367467 0.001765769 1.877465808 1.597898608 empirické vzorce DataSet/Point Comment S Fe Ni Mn As Sb 11 / 1 . HB bl 22 1.070022682 1.015413101 0.004133081 0 0.910431136 0 15 / 1 . HB bl 22 1.065996567 1.022203022 0 0.000785308 0.908193584 0.002821519 ##### Sheet/List 3 ##### tetraedrit A12D4X13 "A=Cu, Fe, Zn, Hg,…" "B=As,Sb" "X=S, Se" Weight% Det.Lim ppm DataSet/Point Comment Ag S Pb Hg Bi Cd Cl Cu Fe Zn Ni Co Mn As Se Sb Total Comment Ag S Pb Hg Bi Cd Cl Cu Fe Zn Ni Co Mn As Se Sb Date 1 / 1 . D2 0.044 21.643 0 19.591 0.012 0.015 0.008 33.036 0.045 0.3 0 0.012 0 0.443 0 24.576 99.724 D2 1726 336 0 1142 1684 1003 190 416 278 316 0 295 0 1814 -1 1324 3/19/2010 11:19 2 / 1 . D2 0 22.282 0 18.481 0.039 0 0.006 34.282 0.267 0.817 0.001 0.031 0 4.672 0 18.668 99.546 D1 1587 353 -7 1137 1563 1006 191 403 272 307 -2 286 -1696 1831 804 1270 3/19/2010 12:11 11 / 1 . D12 0.216 25.095 0 0.091 0 0 0.007 38.119 0.546 7.483 0 0 0.008 0.78 0 28.092 100.437 D12 1382 345 0 980 0 -1 174 407 263 312 -1 0 193 1968 0 1212 3/19/2010 12:16 12 / 1 . D12 0.27 25.312 0.025 0.065 0 0.039 0.006 38.56 0.756 7.297 0 0 0.001 2.855 0 25.252 100.437 D12 1505 341 0 1033 0 -28 179 408 256 308 -1 -1 192 1937 0 1193 3/19/2010 12:36 16 / 1 . D5 0.201 24.369 0 8.592 0.304 0 0.015 37.664 3.091 0.18 0.001 0 0 3.401 0 22.254 100.074 D5 1582 327 0 1104 1636 0 178 408 276 302 300 -3 -7 1846 0 1232 3/19/2010 14:23 17 / 1 . D5 0.232 24.366 0 8.483 0.425 0 0 37.587 3.089 0.172 0 0 0 3.76 0 22.004 100.12 D5 1533 362 -1 1058 1550 0 0 413 275 305 0 -4 -2 1868 -1 1256 3/19/2010 14:28 18 / 1 . D5 0.213 24.336 0 9.285 0.35 0 0.006 37.573 2.876 0.157 0 0.009 0 3.977 0.014 21.452 100.249 D5 1582 346 -1 1077 1619 0 184 405 281 311 -4 280 -2 1884 832 1242 3/19/2010 14:33 19 / 1 . D5 0.17 24.301 0 8.982 0.362 0 0.006 37.472 2.899 0.279 0 0 0 3.398 0.013 22.367 100.247 D6 1559 351 0 1057 1569 0 188 404 268 303 0 -2 207 1864 -3 1216 3/19/2010 15:10 26 / 1 . D7 0.178 25.667 0 2.321 0.171 0 0.007 40.776 4.657 0.204 0.006 0.001 0.003 6.144 0.014 20.159 100.31 D7 1489 357 0 1001 1527 -1 178 400 270 302 289 274 194 2017 850 1233 3/19/2010 15:15 27 / 1 . D7 0.23 25.743 0 2.242 0.185 0 0 40.693 4.586 0.214 0 0.012 0 6.017 0 20.721 100.644 D7 1475 345 0 991 1515 -1 -1 399 279 299 -2 269 -1 1951 -1 1201 3/19/2010 15:20 28 / 1 . D7 0.279 25.803 0 2.339 0.11 0 0 40.856 4.648 0.173 0 0.011 0 6.432 0.036 20.018 100.705 D7 1430 334 0 995 1519 -1 -1 400 275 300 0 264 0 1958 858 1234 3/19/2010 15:26 29 / 1 . D7 0.194 25.679 0 2.411 0.153 0 0 40.693 4.554 0.15 0.012 0.001 0 6.052 0 20.514 100.414 D7 1474 347 0 985 1506 0 -1 406 281 304 295 283 0 1928 0 1270 3/19/2010 15:31 30 / 1 . D7 0.237 25.788 0 2.27 0.087 0 0.007 40.629 4.518 0.158 0 0.019 0 5.965 0.008 20.823 100.509 D7 1463 343 0 992 1610 0 180 402 275 300 -2 271 0 1940 858 1217 3/19/2010 15:36 31 / 1 . D13 0.123 24.813 0 5.963 1.159 0 0.005 38.349 3.423 1.177 0.004 0.008 0 5.036 0.003 20.555 100.616 D13 1560 346 0 1101 1598 0 187 408 277 307 297 279 -1 1949 860 1266 3/19/2010 15:41 32 / 1 . D13 0.103 25.035 0 5.529 0.94 0.002 0.014 38.852 3.706 1.123 0.005 0.001 0.001 6.645 0 18.368 100.323 D21 1569 335 0 1007 1484 -1 0 411 286 307 0 0 -2 1954 -1 1250 3/19/2010 19:47 79 / 1 . D22 0.441 23.147 0 11.984 0 0 0 35.633 1.514 1.373 0 0.027 0 2.815 0.004 23.411 100.35 D22 1486 335 1230 1117 -1 0 0 408 276 313 -1 279 0 1865 846 1302 3/19/2010 19:52 80 / 1 . D22 0.375 22.938 0 12.892 0.062 0 0.013 35.295 1.338 1.277 0.003 0.017 0 2.609 0.022 23.436 100.276 D24 1797 363 0 1163 0 0 193 408 271 310 -2 285 0 1743 -1 1340 3/19/2010 20:45 90 / 1 . D24 0.267 22.995 0 15.086 0 0 0 35.339 0.635 1.642 0.002 0.01 0.002 6.364 0.022 16.986 99.349 D24 1794 353 0 1156 -32 0 -1 407 266 310 306 280 216 1860 845 1296 3/19/2010 20:51 91 / 1 . D24 0.235 22.79 0 15.488 0 0 0 34.649 0.483 1.554 0.003 0.017 0 5.936 0 17.788 98.941 D24 1640 348 0 1121 -2 -1 195 405 269 305 0 280 -1 1855 0 1292 3/19/2010 21:07 nad DL 107.8682 32.0675 207.2 200.59 208.9804 112.411 35.45 63.546 55.845 65.38 58.6934 58.933195 54.938045 74.9216 78.96 121.76 DataSet/Point Comment Ag S Pb Hg Bi Cd Cl Cu Fe Zn Ni Co Mn As Se Sb Total Ag Cu S 1 / 1 . D2 0 21.643 0 19.591 0 0 0 33.036 0.045 0.3 0 0 0 0.443 0 24.576 99.634 As Fe Sb 2 / 1 . D2 0 22.282 0 18.481 0 0 0 34.282 0.267 0.817 0.001 0.031 0 4.672 0 18.668 99.501 Bi Hg Se 11 / 1 . D12 0.216 25.095 0 0 0 0 0 38.119 0.546 7.483 0 0 0 0.78 0 28.092 100.331 Cd Mn Zn 12 / 1 . D12 0.27 25.312 0.025 0 0 0.039 0 38.56 0.756 7.297 0 0 0 2.855 0 25.252 100.366 Co Pb Ni 16 / 1 . D5 0.201 24.369 0 8.592 0.304 0 0 37.664 3.091 0.18 0 0 0 3.401 0 22.254 100.056 17 / 1 . D5 0.232 24.366 0 8.483 0.425 0 0 37.587 3.089 0.172 0 0 0 3.76 0 22.004 100.118 18 / 1 . D5 0.213 24.336 0 9.285 0.35 0 0 37.573 2.876 0.157 0 0 0 3.977 0 21.452 100.219 19 / 1 . D5 0.17 24.301 0 8.982 0.362 0 0 37.472 2.899 0.279 0 0 0 3.398 0.013 22.367 100.243 26 / 1 . D7 0.178 25.667 0 2.321 0.171 0 0 40.776 4.657 0.204 0 0 0 6.144 0 20.159 100.277 27 / 1 . D7 0.23 25.743 0 2.242 0.185 0 0 40.693 4.586 0.214 0 0 0 6.017 0 20.721 100.631 28 / 1 . D7 0.279 25.803 0 2.339 0 0 0 40.856 4.648 0.173 0 0 0 6.432 0 20.018 100.548 29 / 1 . D7 0.194 25.679 0 2.411 0.153 0 0 40.693 4.554 0.15 0 0 0 6.052 0 20.514 100.4 30 / 1 . D7 0.237 25.788 0 2.27 0 0 0 40.629 4.518 0.158 0 0 0 5.965 0 20.823 100.388 31 / 1 . D13 0 24.813 0 5.963 1.159 0 0 38.349 3.423 1.177 0 0 0 5.036 0 20.555 100.475 32 / 1 . D13 0 25.035 0 5.529 0.94 0.002 0.014 38.852 3.706 1.123 0.005 0.001 0.001 6.645 0 18.368 100.221 79 / 1 . D22 0.441 23.147 0 11.984 0 0 0 35.633 1.514 1.373 0 0 0 2.815 0 23.411 100.318 80 / 1 . D22 0.375 22.938 0 12.892 0.062 0 0 35.295 1.338 1.277 0.003 0 0 2.609 0.022 23.436 100.247 90 / 1 . D24 0.267 22.995 0 15.086 0 0 0 35.339 0.635 1.642 0 0 0 6.364 0 16.986 99.314 91 / 1 . D24 0.235 22.79 0 15.488 0 0 0 34.649 0.483 1.554 0.003 0 0 5.936 0 17.788 98.926 16 n prvku DataSet/Point Comment Ag S Pb Hg Bi Cd Cl Cu Fe Zn Ni Co Mn As Se Sb suma ABCD koef. 1 / 1 . D2 0 0.67492009 0 0.097666883 0 0 0 0.519875366 0.000805802 0.004588559 0 0 0 0.005912848 0 0.201839685 0.830689142 19.2611161 2 / 1 . D2 0 0.694846808 0 0.092133207 0 0 0 0.539483209 0.004781091 0.012496176 1.70377E-05 0.000526019 0 0.062358519 0 0.153318003 0.865113261 18.49468817 11 / 1 . D12 0.002002444 0.782568021 0 0 0 0 0 0.599864665 0.009777062 0.114453961 0 0 0 0.010410883 0 0.230716163 0.967225177 16.54216657 12 / 1 . D12 0.002503055 0.789334996 0.000120656 0 0 0.000346941 0 0.60680452 0.01353747 0.111609055 0 0 0 0.038106501 0 0.20739159 0.980419787 16.31954007 16 / 1 . D5 0.001863385 0.759928276 0 0.042833641 0.001454682 0 0 0.592704498 0.055349628 0.002753136 0 0 0 0.045394119 0 0.182769382 0.92512247 17.29500743 17 / 1 . D5 0.002150773 0.759834724 0 0.042290244 0.002033684 0 0 0.591492777 0.055313815 0.002630774 0 0 0 0.050185794 0 0.180716163 0.926814023 17.26344185 18 / 1 . D5 0.001974632 0.758899197 0 0.046288449 0.001674798 0 0 0.591272464 0.051499687 0.002401346 0 0 0 0.053082155 0 0.176182654 0.924376186 17.30897036 19 / 1 . D5 0.001575997 0.757807749 0 0.044777905 0.00173222 0 0 0.589683064 0.051911541 0.00426736 0 0 0 0.045354077 0.00016464 0.183697438 0.922999602 17.33478537 26 / 1 . D7 0.001650162 0.800405395 0 0.011570866 0.000818259 0 0 0.641676895 0.08339153 0.00312022 0 0 0 0.082005723 0 0.165563403 0.989797059 16.16492982 27 / 1 . D7 0.002132232 0.802775396 0 0.011177028 0.00088525 0 0 0.640370755 0.082120154 0.003273172 0 0 0 0.080310618 0 0.170179041 0.99044825 16.15430185 28 / 1 . D7 0.00258649 0.804646449 0 0.011660601 0 0 0 0.642935826 0.08323037 0.002646069 0 0 0 0.085849742 0 0.164405388 0.993314485 16.10768819 29 / 1 . D7 0.001798491 0.800779606 0 0.012019542 0.000732126 0 0 0.640370755 0.081547139 0.00229428 0 0 0 0.080777773 0 0.168478975 0.988019082 16.19401922 30 / 1 . D7 0.002197126 0.804178686 0 0.011316616 0 0 0 0.639363611 0.080902498 0.002416641 0 0 0 0.079616559 0 0.171016754 0.986829805 16.21353542 31 / 1 . D13 0 0.77377407 0 0.029727304 0.005545975 0 0 0.60348409 0.061294655 0.018002447 0 0 0 0.067216931 0 0.168815703 0.954087105 16.76995728 32 / 1 . D13 0 0.780696967 0 0.027563687 0.004498029 1.77919E-05 0.000394922 0.611399616 0.066362253 0.017176507 8.51885E-05 1.69684E-05 1.82023E-05 0.088692713 0 0.150854139 0.966685096 16.55140859 79 / 1 . D22 0.004088323 0.721821158 0 0.059743756 0 0 0 0.560743398 0.027110753 0.021000306 0 0 0 0.037572609 0 0.192271682 0.902530827 17.72792631 80 / 1 . D22 0.003476465 0.715303656 0 0.064270402 0.000296679 0 0 0.555424417 0.023959173 0.019531967 5.11131E-05 0 0 0.034823068 0.000278622 0.192477004 0.894310288 17.89088219 90 / 1 . D24 0.002475243 0.717081157 0 0.075208136 0 0 0 0.556116829 0.011370758 0.025114714 0 0 0 0.084942126 0 0.139503942 0.894731748 17.88245475 91 / 1 . D24 0.002178585 0.710688392 0 0.077212224 0 0 0 0.545258553 0.008648939 0.023768737 5.11131E-05 0 0 0.079229488 0 0.14609067 0.882438308 18.13157912 vzorce A B C D Y+Z DataSet/Point Comment Ag S Pb Hg Bi Cd Cl Cu Fe Zn Ni Co Mn As Se Sb Ag Cu Cu Fe Zn Hg Ni+Co+Mn As Sb S Se 1 / 1 . D2 0.000 13.000 0.000 1.881 0.000 0.000 0.000 10.013 0.016 0.088 0.000 0.000 0.000 0.114 0.000 3.888 0.000 6.013 6.013 4 0.016 0.088 1.881 0.000 1.985 0.114 3.888 4.002 13.000 0.000 2 / 1 . D2 0.000 12.851 0.000 1.704 0.000 0.000 0.000 9.978 0.088 0.231 0.000 0.010 0.000 1.153 0.000 2.836 0.000 5.978 5.978 4 0.088 0.231 1.704 0.010 2.034 1.153 2.836 3.989 12.851 0.000 11 / 1 . D12 0.033 12.945 0.000 0.000 0.000 0.000 0.000 9.923 0.162 1.893 0.000 0.000 0.000 0.172 0.000 3.817 0.033 5.923 5.956 4 0.162 1.893 0.000 0.000 2.055 0.172 3.817 3.989 12.945 0.000 12 / 1 . D12 0.041 12.882 0.002 0.000 0.000 0.006 0.000 9.903 0.221 1.821 0.000 0.000 0.000 0.622 0.000 3.385 0.041 5.903 5.944 4 0.221 1.821 0.000 0.008 2.050 0.622 3.385 4.006 12.882 0.000 16 / 1 . D5 0.032 13.143 0.000 0.741 0.025 0.000 0.000 10.251 0.957 0.048 0.000 0.000 0.000 0.785 0.000 3.161 0.032 6.251 6.283 4 0.957 0.048 0.741 0.000 1.746 0.785 3.161 3.946 13.143 0.000 17 / 1 . D5 0.037 13.117 0.000 0.730 0.035 0.000 0.000 10.211 0.955 0.045 0.000 0.000 0.000 0.866 0.000 3.120 0.037 6.211 6.248 4 0.955 0.045 0.730 0.000 1.730 0.866 3.120 3.986 13.117 0.000 18 / 1 . D5 0.034 13.136 0.000 0.801 0.029 0.000 0.000 10.234 0.891 0.042 0.000 0.000 0.000 0.919 0.000 3.050 0.034 6.234 6.268 4 0.891 0.042 0.801 0.000 1.734 0.919 3.050 3.968 13.136 0.000 19 / 1 . D5 0.027 13.136 0.000 0.776 0.030 0.000 0.000 10.222 0.900 0.074 0.000 0.000 0.000 0.786 0.003 3.184 0.027 6.222 6.249 4 0.900 0.074 0.776 0.000 1.750 0.786 3.184 3.971 13.136 0.003 26 / 1 . D7 0.027 12.938 0.000 0.187 0.013 0.000 0.000 10.373 1.348 0.050 0.000 0.000 0.000 1.326 0.000 2.676 0.027 6.373 6.399 4 1.348 0.050 0.187 0.000 1.585 1.326 2.676 4.002 12.938 0.000 27 / 1 . D7 0.034 12.968 0.000 0.181 0.014 0.000 0.000 10.345 1.327 0.053 0.000 0.000 0.000 1.297 0.000 2.749 0.034 6.345 6.379 4 1.327 0.053 0.181 0.000 1.560 1.297 2.749 4.046 12.968 0.000 28 / 1 . D7 0.042 12.961 0.000 0.188 0.000 0.000 0.000 10.356 1.341 0.043 0.000 0.000 0.000 1.383 0.000 2.648 0.042 6.356 6.398 4 1.341 0.043 0.188 0.000 1.571 1.383 2.648 4.031 12.961 0.000 29 / 1 . D7 0.029 12.968 0.000 0.195 0.012 0.000 0.000 10.370 1.321 0.037 0.000 0.000 0.000 1.308 0.000 2.728 0.029 6.370 6.399 4 1.321 0.037 0.195 0.000 1.552 1.308 2.728 4.036 12.968 0.000 30 / 1 . D7 0.036 13.039 0.000 0.183 0.000 0.000 0.000 10.366 1.312 0.039 0.000 0.000 0.000 1.291 0.000 2.773 0.036 6.366 6.402 4 1.312 0.039 0.183 0.000 1.534 1.291 2.773 4.064 13.039 0.000 31 / 1 . D13 0.000 12.976 0.000 0.499 0.093 0.000 0.000 10.120 1.028 0.302 0.000 0.000 0.000 1.127 0.000 2.831 0.000 6.120 6.120 4 1.028 0.302 0.499 0.000 1.828 1.127 2.831 3.958 12.976 0.000 32 / 1 . D13 0.000 12.922 0.000 0.456 0.074 0.000 0.007 10.120 1.098 0.284 0.001 0.000 0.000 1.468 0.000 2.497 0.000 6.120 6.120 4 1.098 0.284 0.456 0.002 1.841 1.468 2.497 3.965 12.922 0.000 79 / 1 . D22 0.072 12.796 0.000 1.059 0.000 0.000 0.000 9.941 0.481 0.372 0.000 0.000 0.000 0.666 0.000 3.409 0.072 5.941 6.013 4 0.481 0.372 1.059 0.000 1.912 0.666 3.409 4.075 12.796 0.000 80 / 1 . D22 0.062 12.797 0.000 1.150 0.005 0.000 0.000 9.937 0.429 0.349 0.001 0.000 0.000 0.623 0.005 3.444 0.062 5.937 5.999 4 0.429 0.349 1.150 0.001 1.929 0.623 3.444 4.067 12.797 0.005 90 / 1 . D24 0.044 12.823 0.000 1.345 0.000 0.000 0.000 9.945 0.203 0.449 0.000 0.000 0.000 1.519 0.000 2.495 0.044 5.945 5.989 4 0.203 0.449 1.345 0.000 1.997 1.519 2.495 4.014 12.823 0.000 91 / 1 . D24 0.040 12.886 0.000 1.400 0.000 0.000 0.000 9.886 0.157 0.431 0.001 0.000 0.000 1.437 0.000 2.649 0.040 5.886 5.926 4 0.157 0.431 1.400 0.001 1.989 1.437 2.649 4.085 12.886 0.000