(E120)0P.
O
Ph
hv
O
BDP
R.
O
Ph ROH
O
BZ (R = H) in H20
BZ (R = CH2CF3) in TFE
Si
t~ 3 ps Amax=300 nm
ISC
ISC
Ti (n,7ŕ)
t ~ 10 ns Amax=350 nm
H20 or TFE
PO(OEt2)0(
CH3CN or H20 - PO(OEt2)OH
z = 430 ns (H20) Amax=570 nm
PBF
Amax=300 nm
J/ÍCS2000, 722, 611; D. L. Phillips, C/zew. Eur. J. 2007,73, 2290
Med
Ph      hv     MeO^^A^Ph ISC
°       CH3CN O
OMe OMe
dmb-X q     /      s, (intramol. CT)
330 nm, t= 17 ps
MeO
420 nm, r> 1
KJ °
OMe
MeO
OMe OMe dmbf, 301 nm
Corrie, Wan, JOC, 1997, 62, 8278. JPG A 2007, 777, 2811. Phillips, Chem. Eur. J. 2010, 16, 5102