Výpočet závislosti Gmkapalne Vody na teplotě a tlaku n= 1 mol Cpm(l)= 75.383 J K-1 mol-1 Vm(l)= 0.000018 m3 mol-1 liquid od do n step Termod funkce při: 298.15 K rozsah T 298.15 473 20 8.7425 H0(l)= -285838 J mol-1 rozsah p 101325 5066250 20 248246.25 S0 (l)= 69.94 J K-1 mol-1 G0(l)= -306690.611 J mol-1 Vzory: posun T posun p: T= 373.15 K p= 101325 Pa H(T)= -280184.275 J mol-1 S(T)= 86.85472158 J K-1 mol-1 G(T)= -312594.1144 J mol-1 G(T)= -312594.1144 J mol-1 Plocha G(liquid): T\p 101325 349571.25 597817.5 846063.75 1094310 1342556.25 1590802.5 1839048.75 2087295 2335541.25 2583787.5 2832033.75 3080280 3328526.25 3576772.5 3825018.75 4073265 4321511.25 4569757.5 4818003.75 5066250 298.15 -306690.611 -306686.1426 -306681.6741 -306677.2057 -306672.7373 -306668.2688 -306663.8004 -306659.332 -306654.8635 -306650.3951 -306645.9267 -306641.4582 -306636.9898 -306632.5214 -306628.0529 -306623.5845 -306619.1161 -306614.6476 -306610.1792 -306605.7108 -306601.2424 306.8925 -307311.6307 -307307.1622 -307302.6938 -307298.2254 -307293.7569 -307289.2885 -307284.8201 -307280.3516 -307275.8832 -307271.4148 -307266.9463 -307262.4779 -307258.0095 -307253.541 -307249.0726 -307244.6042 -307240.1357 -307235.6673 -307231.1989 -307226.7304 -307222.262 315.635 -307951.4269 -307946.9585 -307942.4901 -307938.0216 -307933.5532 -307929.0848 -307924.6163 -307920.1479 -307915.6795 -307911.211 -307906.7426 -307902.2742 -307897.8057 -307893.3373 -307888.8689 -307884.4004 -307879.932 -307875.4636 -307870.9951 -307866.5267 -307862.0583 324.3775 -308609.4796 -308605.0112 -308600.5427 -308596.0743 -308591.6059 -308587.1374 -308582.669 -308578.2006 -308573.7321 -308569.2637 -308564.7953 -308560.3268 -308555.8584 -308551.39 -308546.9215 -308542.4531 -308537.9847 -308533.5162 -308529.0478 -308524.5794 -308520.1109 333.12 -309285.2965 -309280.8281 -309276.3596 -309271.8912 -309267.4228 -309262.9543 -309258.4859 -309254.0175 -309249.549 -309245.0806 -309240.6122 -309236.1437 -309231.6753 -309227.2069 -309222.7384 -309218.27 -309213.8016 -309209.3331 -309204.8647 -309200.3963 -309195.9278 341.8625 -309978.4113 -309973.9429 -309969.4744 -309965.006 -309960.5376 -309956.0691 -309951.6007 -309947.1323 -309942.6638 -309938.1954 -309933.727 -309929.2585 -309924.7901 -309920.3217 -309915.8533 -309911.3848 -309906.9164 -309902.448 -309897.9795 -309893.5111 -309889.0427 350.605 -310688.3816 -310683.9132 -310679.4447 -310674.9763 -310670.5079 -310666.0394 -310661.571 -310657.1026 -310652.6341 -310648.1657 -310643.6973 -310639.2288 -310634.7604 -310630.292 -310625.8235 -310621.3551 -310616.8867 -310612.4182 -310607.9498 -310603.4814 -310599.0129 359.3475 -311414.7869 -311410.3185 -311405.8501 -311401.3816 -311396.9132 -311392.4448 -311387.9763 -311383.5079 -311379.0395 -311374.571 -311370.1026 -311365.6342 -311361.1657 -311356.6973 -311352.2289 -311347.7604 -311343.292 -311338.8236 -311334.3551 -311329.8867 -311325.4183 368.09 -312157.2274 -312152.759 -312148.2906 -312143.8221 -312139.3537 -312134.8853 -312130.4168 -312125.9484 -312121.48 -312117.0115 -312112.5431 -312108.0747 -312103.6062 -312099.1378 -312094.6694 -312090.2009 -312085.7325 -312081.2641 -312076.7956 -312072.3272 -312067.8588 376.8325 -312915.3222 -312910.8537 -312906.3853 -312901.9169 -312897.4484 -312892.98 -312888.5116 -312884.0431 -312879.5747 -312875.1063 -312870.6378 -312866.1694 -312861.701 -312857.2325 -312852.7641 -312848.2957 -312843.8272 -312839.3588 -312834.8904 -312830.4219 -312825.9535 385.575 -313688.7078 -313684.2394 -313679.771 -313675.3026 -313670.8341 -313666.3657 -313661.8973 -313657.4288 -313652.9604 -313648.492 -313644.0235 -313639.5551 -313635.0867 -313630.6182 -313626.1498 -313621.6814 -313617.2129 -313612.7445 -313608.2761 -313603.8076 -313599.3392 394.3175 -314477.0378 -314472.5693 -314468.1009 -314463.6325 -314459.164 -314454.6956 -314450.2272 -314445.7587 -314441.2903 -314436.8219 -314432.3534 -314427.885 -314423.4166 -314418.9481 -314414.4797 -314410.0113 -314405.5428 -314401.0744 -314396.606 -314392.1375 -314387.6691 403.06 -315279.9805 -315275.5121 -315271.0436 -315266.5752 -315262.1068 -315257.6383 -315253.1699 -315248.7015 -315244.233 -315239.7646 -315235.2962 -315230.8277 -315226.3593 -315221.8909 -315217.4224 -315212.954 -315208.4856 -315204.0171 -315199.5487 -315195.0803 -315190.6119 411.8025 -316097.2191 -316092.7506 -316088.2822 -316083.8138 -316079.3453 -316074.8769 -316070.4085 -316065.94 -316061.4716 -316057.0032 -316052.5347 -316048.0663 -316043.5979 -316039.1294 -316034.661 -316030.1926 -316025.7241 -316021.2557 -316016.7873 -316012.3188 -316007.8504 420.545 -316928.4499 -316923.9815 -316919.513 -316915.0446 -316910.5762 -316906.1077 -316901.6393 -316897.1709 -316892.7024 -316888.234 -316883.7656 -316879.2971 -316874.8287 -316870.3603 -316865.8918 -316861.4234 -316856.955 -316852.4865 -316848.0181 -316843.5497 -316839.0812 429.2875 -317773.3821 -317768.9137 -317764.4452 -317759.9768 -317755.5084 -317751.0399 -317746.5715 -317742.1031 -317737.6346 -317733.1662 -317728.6978 -317724.2293 -317719.7609 -317715.2925 -317710.824 -317706.3556 -317701.8872 -317697.4187 -317692.9503 -317688.4819 -317684.0134 438.03 -318631.7366 -318627.2681 -318622.7997 -318618.3313 -318613.8628 -318609.3944 -318604.926 -318600.4575 -318595.9891 -318591.5207 -318587.0522 -318582.5838 -318578.1154 -318573.6469 -318569.1785 -318564.7101 -318560.2416 -318555.7732 -318551.3048 -318546.8363 -318542.3679 446.7725 -319503.2454 -319498.777 -319494.3085 -319489.8401 -319485.3717 -319480.9032 -319476.4348 -319471.9664 -319467.4979 -319463.0295 -319458.5611 -319454.0926 -319449.6242 -319445.1558 -319440.6873 -319436.2189 -319431.7505 -319427.282 -319422.8136 -319418.3452 -319413.8767 455.515 -320387.6511 -320383.1827 -320378.7143 -320374.2458 -320369.7774 -320365.309 -320360.8405 -320356.3721 -320351.9037 -320347.4353 -320342.9668 -320338.4984 -320334.03 -320329.5615 -320325.0931 -320320.6247 -320316.1562 -320311.6878 -320307.2194 -320302.7509 -320298.2825 464.2575 -321284.7063 -321280.2378 -321275.7694 -321271.301 -321266.8325 -321262.3641 -321257.8957 -321253.4272 -321248.9588 -321244.4904 -321240.0219 -321235.5535 -321231.0851 -321226.6166 -321222.1482 -321217.6798 -321213.2113 -321208.7429 -321204.2745 -321199.806 -321195.3376 473 -322194.1725 -322189.7041 -322185.2356 -322180.7672 -322176.2988 -322171.8303 -322167.3619 -322162.8935 -322158.4251 -322153.9566 -322149.4882 -322145.0198 -322140.5513 -322136.0829 -322131.6145 -322127.146 -322122.6776 -322118.2092 -322113.7407 -322109.2723 -322104.8039 ##### Sheet/List 2 ##### Výpočet závislosti Gm plynne Vody na teplotě a tlaku n= 1 mol Cpm(g)= 30.12 11.3 *T J K-1 mol-1 t.j.: a +b*T Vm(l)= 0 g mol-1 Termod funkce při: "T=373,15" 373.15 K H373(l)= -280184.275 J mol-1 S373 (l)= 86.85472158 J K-1 mol-1 G373(l)= -312594.1144 J mol-1 Vzory: Fázový přechod při 373K Hvýp= 40670 J mol-1 H373(g)= -239514.275 J mol-1 S373 (g)= 195.845744 J K-1 mol-1 G373(g)= -312594.1144 J mol-1 posun T posun p: T= 473.15 K p0= 101325 Pa H(T)= 241657.225 J mol-1 S(T)= 1332.997195 J K-1 mol-1 gas G(T)= -389050.3979 J mol-1 od do n step G(T)= -389050.3979 J mol-1 rozsah T 298.15 473.15 20 8.75 rozsah p 101325 5066250 20 248246.25 Plocha G(gas): T\p 101325 349571.25 597817.5 846063.75 1094310 1342556.25 1590802.5 1839048.75 2087295 2335541.25 2583787.5 2832033.75 3080280 3328526.25 3576772.5 3825018.75 4073265 4321511.25 4569757.5 4818003.75 5066250 298.15 -329930.9049 -326861.022 -325530.8651 -324669.8988 -324032.1 -323525.2727 -323104.6841 -322745.2102 -322431.3227 -322152.7501 -321902.3434 -321674.9266 -321466.6307 -321274.4885 -321096.1738 -320929.8292 -320773.9482 -320627.2922 -320488.8298 -320357.6938 -320233.1477 306.9 -324606.202 -321446.2252 -320077.0314 -319190.7977 -318534.281 -318012.5795 -317579.6476 -317209.624 -316886.5247 -316599.7766 -316342.0211 -316107.9301 -315893.5213 -315695.7401 -315512.1922 -315340.9658 -315180.5102 -315029.5501 -314887.0242 -314752.0397 -314623.8385 315.65 -320154.1704 -316904.0998 -315495.8689 -314584.3679 -313909.1333 -313372.5576 -312927.2825 -312546.7091 -312214.398 -311919.4744 -311654.3701 -311413.6049 -311193.0831 -310989.6631 -310800.8821 -310624.7738 -310459.7434 -310304.4793 -310157.8899 -310019.0568 -309887.2005 324.4 -316574.6017 -313234.4372 -311787.1694 -310850.4011 -310156.4486 -309604.9987 -309147.3803 -308756.2572 -308414.7342 -308111.6352 -307839.1821 -307591.7427 -307365.1079 -307156.049 -306962.0348 -306781.0448 -306611.4396 -306451.8715 -306301.2185 -306158.537 -306023.0255 333.15 -313867.2988 -310437.0405 -308950.7358 -307988.7001 -307276.0297 -306709.7056 -306239.7439 -305838.0711 -305487.3362 -305176.0618 -304896.2598 -304642.1463 -304409.3986 -304194.7007 -303995.4534 -303809.5815 -303635.4017 -303471.5295 -303316.813 -303170.2829 -303031.1163 341.9 -312032.0749 -308511.7229 -306986.3811 -305999.0781 -305267.6899 -304686.4916 -304204.1866 -303791.9641 -303432.0173 -303112.5675 -302825.4166 -302564.629 -302325.7682 -302105.4314 -301900.951 -301710.1973 -301531.4427 -301363.2666 -301204.4865 -301054.1079 -300911.2861 350.65 -311068.7529 -307458.307 -305893.9283 -304881.358 -304131.2518 -303535.1793 -303040.5311 -302617.7589 -302248.6003 -301920.9749 -301626.4752 -301359.0135 -301114.0397 -300888.0639 -300678.3505 -300482.7149 -300299.3856 -300126.9054 -299964.0618 -299809.8347 -299663.3578 359.4 -310977.1644 -307276.6246 -305673.209 -304635.3713 -303866.5473 -303255.6006 -302748.609 -302315.2871 -301936.9166 -301601.1159 -301299.2673 -301025.1314 -300774.0447 -300542.43 -300327.4834 -300126.966 -299939.062 -299762.2778 -299595.3706 -299437.2949 -299287.1629 368.15 -311757.1492 -307966.5156 -306324.0629 -305260.9579 -304473.416 -303847.5951 -303328.2603 -302884.3887 -302496.8063 -302152.8301 -301843.6327 -301562.8227 -301305.6229 -301068.3693 -300848.1896 -300642.7904 -300450.3116 -300269.2234 -300098.2527 -299936.3285 -299782.5414 376.9 -313408.5547 -309527.8273 -307846.3377 -306757.9653 -305951.7055 -305311.0105 -304779.3323 -304324.911 -303928.1168 -303575.9651 -303259.4189 -302971.9347 -302708.6219 -302465.7294 -302240.3166 -302030.0356 -301832.9821 -301647.5899 -301472.5556 -301306.7828 -301149.3406 385.65 -315931.2355 -311960.4143 -310239.8877 -309126.248 -308301.2703 -307645.7011 -307101.6797 -306636.7086 -306230.7026 -305870.3754 -305546.4804 -305252.322 -304982.8963 -304734.3648 -304503.7189 -304288.5561 -304086.9278 -303897.2316 -303718.1338 -303548.5125 -303387.4151 394.4 -319325.0528 -315264.1377 -313504.5742 -312365.6671 -311521.9715 -310851.5281 -310295.1634 -309819.6427 -309404.4248 -309035.9222 -308704.6783 -308403.8457 -308128.307 -307874.1367 -307638.2576 -307418.213 -307212.0099 -307018.0097 -306834.8484 -306661.3786 -306496.626 403.15 -323589.8738 -319438.8649 -317640.2644 -316476.09 -315613.6765 -314928.3589 -314359.651 -313873.5805 -313449.1507 -313072.4727 -312733.8799 -312426.3732 -312144.7215 -311884.9123 -311643.8001 -311418.8736 -311208.0958 -311009.7916 -310822.5667 -310645.2484 -310476.8407 411.9 -328725.5716 -324484.4689 -322646.8314 -321457.3897 -320576.2583 -319876.0665 -319295.0153 -318798.3951 -318364.7535 -317979.9 -317633.9584 -317319.7776 -317032.0129 -316766.5647 -316520.2193 -316290.4111 -316075.0586 -315872.4503 -315681.1619 -315499.995 -315327.9322 420.65 -334732.0247 -330400.8282 -328524.1537 -327309.4447 -326409.5954 -325694.5294 -325101.1349 -324593.965 -324151.1115 -323758.0826 -323404.7921 -323083.9371 -322790.0594 -322518.9723 -322267.3939 -322032.7038 -321812.7766 -321605.8643 -321410.5123 -321225.4969 -321049.779 429.4 -341609.1166 -337187.8262 -335272.1148 -334032.1384 -333113.5712 -332383.6311 -331777.8933 -331260.1736 -330808.1083 -330406.9039 -330046.2646 -329718.7355 -329418.7448 -329142.0188 -328885.2072 -328645.6353 -328421.1333 -328209.9171 -328010.5015 -327821.6376 -327642.2645 438.15 -349356.7355 -344845.3513 -342890.6029 -341625.3592 -340688.0741 -339943.2598 -339325.1787 -338796.9093 -338335.6321 -337926.2523 -337558.2642 -337224.0609 -336917.9572 -336635.5923 -336373.5476 -336129.0939 -335900.0172 -335684.4969 -335481.0178 -335288.3053 -335105.2771 446.9 -357974.7742 -353373.2962 -351379.5108 -350088.9998 -349132.9968 -348373.3083 -347742.8839 -347204.0648 -346733.5758 -346316.0205 -345940.6835 -345599.8061 -345287.5894 -344999.5856 -344732.3078 -344482.9722 -344249.3208 -344029.4965 -343821.9539 -343625.3929 -343438.7095 455.65 -367463.1296 -362771.5578 -360738.7354 -359422.957 -358448.2362 -357673.6735 -357030.9058 -356481.5371 -356001.8361 -355576.1054 -355193.4196 -354845.868 -354527.5384 -354233.8955 -353961.3846 -353707.1673 -353468.9411 -353244.8128 -353033.2066 -352832.7971 -352642.4586 464.4 -377821.7027 -373040.037 -370968.1776 -369627.1319 -368633.6932 -367844.2563 -367189.1453 -366629.2269 -366140.3141 -365706.4079 -365316.3733 -364962.1475 -364637.7049 -364338.4231 -364060.6791 -363801.5799 -363558.779 -363330.3467 -363114.677 -362910.4189 -362716.4253 473.15 -389050.3979 -384178.6384 -382067.7421 -380701.429 -379689.2724 -378884.9613 -378217.5071 -377647.0389 -377148.9143 -376706.8326 -376309.4491 -375948.5493 -375617.9936 -375313.073 -375030.0958 -374766.1148 -374518.7391 -374286.0028 -374066.2696 -373858.163 -373660.5142 ##### Sheet/List 3 ##### Liquid T\p 101325 349571.25 597817.5 846063.75 1094310 1342556.25 1590802.5 1839048.75 2087295 2335541.25 2583787.5 2832033.75 3080280 3328526.25 3576772.5 3825018.75 4073265 4321511.25 4569757.5 4818003.75 5066250 298.15 -306690.611 -306686.1426 -306681.6741 -306677.2057 -306672.7373 -306668.2688 -306663.8004 -306659.332 -306654.8635 -306650.3951 -306645.9267 -306641.4582 -306636.9898 -306632.5214 -306628.0529 -306623.5845 -306619.1161 -306614.6476 -306610.1792 -306605.7108 -306601.2424 306.8925 -307311.6307 -307307.1622 -307302.6938 -307298.2254 -307293.7569 -307289.2885 -307284.8201 -307280.3516 -307275.8832 -307271.4148 -307266.9463 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