NATURAL POLYMERS MU SCI 4_1 2018 1 NATURAL POLYMERS POLYTERPENES HOPEFUL HERB: Taraxanum koksagyz Dr. Ladislav Pospíšil 29716@mail.muni.cz January 2018/4_1 Time schedule January 2018/4_1 NATURAL POLYMERS MU SCI 4_1 2018 2 LECTURE SUBJECT 1 Introduction to the subject – Structure & Terminology of nature polymers, literature 2 Derivatives of acids – natural resins, drying oils, shellac 3 Waxes 4 Plant (vegetable) gums, Polyterpene – natural rubber (extracting, processing and modification), Taraxacum_kok-saghyz 5 Polyphenol – lignin, humic acids 6 Polysaccharides I – starch 7 Polysaccharides II – celullosis 8 Protein fibres I 9 Protein fibres II 10 Casein, whey, protein of eggs 11 Identification of natural polymers Laboratory methods of natural polymers’ evaluation •POLYTERPENE - are contained in approx. 2000 plants from various geographic regions •Trees, Bush, Herbs •The most important is the Tree: Hevea brasiliensis •HOPEFUL HERB: Taraxanum koksagyz • • January 2018/4_1 NATURAL POLYMERS MU SCI 4_1 2018 3 POLYTERPENE = POLYISOPRENE Appearance in NATURE 11. 10. 2017 PŘÍRODNÍ POLYMERY PŘF MU 4 DODATEK I 2017 4 Rubber bush (Ficus elastica) yields a milky white latex, a chemical compound separate from its sap and carried and stored in different cells. This latex was formerly used to make rubber, but it should not be confused with the Pará rubber tree, the main commercial source of latex for rubber making. Just as with Hevea brasiliensis, the latex of Ficus elastica is an irritant to the eyes and skin and is toxic if taken internally. Gutta-percha (Palaquium gutta) refers to trees of the genus Palaquium and the rigid natural latex produced from the sap of these trees, particularly from Palaquium gutta. Palaquium gutta trees are 5–30 m tall and up to 1 m in trunk diameter. The leaves are evergreen, alternate or spirally arranged, simple, entire, 8–25 cm long, glossy green above, and often yellow or glaucous below. 11. 10. 2017 PŘÍRODNÍ POLYMERY PŘF MU 4 DODATEK I 2017 5 Balatá (Manilkara bidentata) Balatá is a large tree, growing to 30–45 m (98–148 ft) tall. The leaves are alternate, elliptical, entire, and 10–20 cm (3.9–7.9 in) long. The flowers are white, and are produced at the beginning of the rainy season. The fruit is a yellow berry, 3–5 cm (1.2–2.0 in) in diameter, which is edible; it contains one (occasionally two) seed(s). Its latex is used industrially for products such as chicle. The latex is extracted in the same manner in which sap is extracted from the rubber tree. It is then dried to form an inelastic rubber-like material. It is almost identical to gutta-percha (produced from a closely related southeast Asian tree), and is sometimes called gutta-balatá. . Rubber root (Taraxacum_kok-saghyz ) is a perennial plant with a yellow composite flower. The Rubber latex is extracted from the Root of this Herb. It is NOT the Dandelion! 11. 10. 2017 PŘÍRODNÍ POLYMERY PŘF MU 4 DODATEK I 2017 6 708px-Taraxacum_kok-saghyz.png Taraxacum kok-saghyz ! Benchmark is in Inches! 11. 10. 2017 PŘÍRODNÍ POLYMERY PŘF MU 4 DODATEK I 2017 7 img623.jpg Taraxacum kok-saghyz •It is no Dandelion, it is only looking like! • Latex is in the Root (approx. 10 - 20 % w/w) •Per-hectare yield is stated as 200 kg/ha (hectare) • Experiments were conducted mainly in USSR and in USA CONTINENTAL Company informs: The Tire based on the Taraxacum kok-saghyz we launch in five years! 100 % w/w of the Natural products in 2020 year 45 % w/w of the Natural products in 2013 year 11. 10. 2017 PŘÍRODNÍ POLYMERY PŘF MU 4 DODATEK I 2017 8 img555.jpg Rubber bush Made of the Taraxacum kok-saghyz Natural Rubber