C7780 Inorganic Materials Chemistry Fall 2019 prof. RNDr. Jiří Pinkas, Ph.D. Introduction History of Materials, Materials Science, Materials Engineering, Materials Chemistry Chemical Compounds versus Materials Structure, Properties, Function Traditional Materials: Ceramics, Polymers, Metals New Materials: Composites, Semiconductors, Biomaterials, Hybrid Materials Size Domains, Shape Fabrication, Chemical Synthesis of Materials, Imaging Basic Structural Chemistry Basic Inorganic Structure Types Metals, sc, ccp (fcc), hcp, bcc Ionic and Covalent Compounds, CsCl, NaCl, Cubic and Hexagonal Diamond, Sphalerite, Wurzite, NiAs, WC, CaF2, Rutile, SiO2, BiF3, ReO3, Perovskite, Spinel, Corundum, Graphite, h-BN, Pauling’s Rules, Radius Ratio, Ionicity Physicochemical Methods of Characterization Structure and Properties Real Structure and Defects, Diffusion Electronic Structure of Solids, Chemical Bonding, Band Theory Electrical Properties, Metals, Insulators, Semiconductors, Ionic Conductors Mechanical Properties, Elastic and Plastic Deformation, Stress-Strain, Young Modulus, Bulk Modulus, Hardness Thermal Properties, Melting Point, Thermal Conductivity, Thermal Expansion, Materials with a Negative Thermal Expansion Coefficient Optical, Magnetic Properties Direct Reactions of Solids Powder Mixing Method, Synthesis of Spinel, Kirkendall Ratio Kinatics of Solid State Reactions, Nucleation, Growth Self-Sustaining Reactions, Combustion Reactions Carbothermal Reduction Fusion-Crystallization from Glass Polymer Pyrolysis Mechanochemical Synthesis Microwave-Assisted Synthesis Dry High-Pressure Methods Coordination Number - Bond Length Paradox Belt-Type Apparatus, Diamond Anvil Detonation Reactions Diamond Synthesis, Hard Materials Gas Phase Reactions Gas-Solid Reactions- Tarnishing Aerosol Routes, Spray Pyrolysis, Spray Drying Fullerenes, Carbon Nanotubes Gas-Gas Reactions- Flame Hydrolysis Vapor Phase Transport Laser-induced Homogeneous Pyrolysis Liquid Phase Reactions Precipitation / Coprecipitation, Precursor Method Freeze-Drying, Double-Salt Precursor Pechini and Citrate Method Flux or Molten Salt Method, Eutectics, Acid-Base Reactions, Lux-Flood Formalism Ionic Liquids Sonochemical Synthesis Sol-Gel Methods Sol (Colloidal Solution), Gel Precursors and Their Syntheses Hydrolysis, Condensation, Drying, Calcination, Sintering Colloid Processing, Metal Salt Hydrolysis, Keggin Structures Metal Alkoxide Hydrolysis Aerogels, Emulsion Method, Inverse Micelles Non-aqueous Sol-Gel Methods. Hybrid Materials Spin- and Dip-Coating Hydrothermal and Solvothermal Synthesis. Reactor, Mineralizers, Solvents, Supercritical State Zeolites and Zeolitic Materials Primary and Secondary Building Units, Sodalite Cage, Pores and Channles, Templating, Pauling Rules, Loewenstein Rule, Acidity, Shape Selectivity, Catalysis Aluminophosphates Reticular Chemistry, Metallo-organic Frameworks (MOF), Covalent-organic Frameworks (COF) Mesoporous Materials Surfactants, Micelles, Critical Packing Parameter Liquid Crystalline Phases Supramolecular Templating Mechanisms XRD, TEM, Gas Adsorption Mesoporous Silica, Metal Oxides, Metal Phosphates, Metals Layered Materials Intercalation, Layered and Pillared Materials Graphite, Graphene, Graphene-like Materials Zirconium Phosphates, Clay Minerals, Layered Double Hydroxides, Li Intercalation Compounds Growth of Single Crystals Czochralski/Kyropoulos Method Stockbarger and Bridgman Methods Zone Melting Verneuil Fusion Flame Method Gel Method, Solution, Flux, and Hydrothermal Methods Electrochemical Growth Vapor Phase Transport Synthesis of Thin Films Surface Chemistry and Properties Anodic Oxidation, Porous Alumina Physical Methods, Sputtering, Vacuum Evaporation, Molecular Beam Epitaxy Porous Silicon, Chemistry on Si-Surfaces Self-Assembled Monolayers Chemical Vapor Deposition and Atomic Layer Deposition CVD process, Reactions Precursor Properties and Synthesis, Single-Source Precursor Metals, Oxides, Nitrides, Semiconductors, Superconductors Atomic and Molecular Layer Deposition Nanostructured Materials and Nanochemistry Nanoscopic Materials, Quantum dots, Nanoparticles, Nanowires, Nanorods, Nanotubes, Nanofibers, Thin films Surface Effects Quantum-Size Effects Top-Down and Bottom-Up Preparation Methods Literature: SCHUBERT, U. a N. HÜSING. Synthesis of Inorganic Materials. Weinheim: Wiley-VCH CALLISTER, W.D.J. Materials Science and Engineering, An Introduction. John Wiley and Sons SMART, L. a E. MOORE. Solid state chemistry : an introduction. 2nd ed. London: Chapman & Hall Plinio Innocenzi, The Sol to Gel Transition, Springer International Publishing Mary Anne White, Physical Properties of Materials, 2nd Edition, CRC Press Ulrich Muller, Inorganic Structural Chemistry, 2nd Edition, Wiley OZIN, G.A., A.C. ARSENAULT a L. CADEMARTIRI. Nanochemistry : a chemical approach to nanomaterials. 2nd ed. Cambridge: RSC Publishing, 2009. liii, 820. ISBN 9781847558954 CADEMARTIRI, L. a G.A. OZIN. Concepts of nanochemistry. Edited by Jean-Marie Lehn. Weinheim: WileyVCH, 2009. xix, 261. ISBN 9783527325979.