Vybrané aplikace FD dvou a tří složkové H,0 Zubní amalgam Temp /°C 1000 800 600 400 200 0 10 Atom% H g 30 50 70 90 Ag-Hg M0.5* 1 1 1 1 1 Liquid 1 1 1 a + a Liquid ŕ + L + — y 7 + L 7 250 Temperature /°C 200 150 100 20 40 60 80 100 Mass% H g 25° C 10 Atom% 30 50 70 90 Liquid 1 i i 1 1 i i Liquid y + Li quid f J ď 7 a + y 232" 20 40 60 80 100 Mass% Sn mass% Hg y V í Liquid https ://pocketdentistryxom/l 4-silver-amalgam Vznik zubní plomby Ag-Sn-Hg Namíchání Brinell Hardness n only solid 20 phases present mass% Ag y Ag3Sn Liquid Hg present rnass% Sn Ag Variation in Brinell indentation hardness (numbered contours) with composition in the Ag-Hg-Sn system corresponding to the reaction stage shown in . The line between the points labelled jl and y2 represents compositions of stoichiometric complete Hg reaction; it is the solidus. Směsi rozpouštědel ff^ff_ff^ fy/^Y t^V^třcfas - IIOÍO /*CfH ha Z C4fC - lilou, WiH •&> **t^ I Podíly fází /i 4 |Temp. ŮC Peritectic reaction omitted for clarity 1600 v-jk-i i Slitiny 1500 1400 1300 ■ Austen ite Solid Solution i Austerale Liquid 90 Ternan Eutectic Poinl —r i Cementite plus Liquid Liquid us Lines plus Liquid Auslernte plus Cementite Cementile (plus Lecfeounfe. the Eutectic mixture ofAustenite and Cementite) r_ ' y_ Lower Critica j_Tťmperah^Unej J25"Cj\PPfo?^ j solidus Lir>e Austen le jIjs FerritOj 2Ä Ferrite rt Ii O. O Eutectpid Point Cementite plus Pea rlite and Ledeburite 0.0 0.5 1.0 1-5 2.0 2.5 3.0 3.5 4 0 4.5 5.0 5 5 6.0% Carbon Hypo- Hyper-eutectoid eulectoid I Mild, Tool Cast Iron 316L stainless steel 5 10 15 2G 25 30 35 40 WEIGHT PERCENT MI Phase diagram of commercial 316L stainless steel plotted by using ThermoCalc program. A typical composition of 18% chromium and 10% nickel + stopy C Legovaná Cr ocel —i-1-1-r 0.2 0.3 0.4 0.5 Phase diagram of Uddeholm AEB-L stainless steel (in deg. Celsius) calculated with Thermo-Calc, coupled with TCFE3 thermodynamic database. Silicon and manganese were excluded from thermodynamic calculations. C = 0.65wt% Cr = 12.8 Si = 0.4 Mn = 0.65 MASS PERCENT C Binary phase diagram of AISI D2 tool steel with variable carbon content i + c h I + C + M7CjU I + MjC i r i ! | i i i i | i t r i | t 1 2 3 1 I 1 " 1 1 I 1 4 5 wc [ i i t t | i r i 6 7 8 Typical chemical composition of AISI D2 Steel C SI Cr Mo 1.50% 0.30% 12.00% 0.80% K. FRISK 0 0.2 0.4 0.6 0.8 1.0 Mole-Fraction Mn bcc+c+M2N FIG. 11 The calculated isothermal section at 1073K through the Cr-Mn-N phase diagram, showing equilibria with 30 atm N2 gas. The full lines show the calculations, and the dashed lines have been redrawn from the experimental study by Ettmayer et aL<4). The Mn6N4 phase is stable in the calculated phase diagram, but it was not found experimentally. FIG. 12 The calculated isothermal section at 1073K through the Cr-Mn-N phase 'diagram, showing equilibria with 30 atm N2 gas. The full lines show the calculations, and the dashed lines have been redrawn from the experimental study by Ettmayer et ah(4) ♦ The MngN4 and the Mn^N5 phases were suspended from the calculation. THERMO - CflLO ; DfMO mé M Quaternární soustavy s=4 Dr.6a: Vypočtený izotermický řez rovnovážným fázovým diagraraem soustavy Fe-Cr-Ni-C. pro teplotu 1000"C. V diagramu jsou vyznačeny body reprezentující celkové chemické složení experimentálních slitin. —— 11 \ \\ \ 1000"C ( cetkovc stožeht \ řez typ čáry Fe-Cr- 8%ííi-C Fe-Cr-18%Ni-C Fe-Cr-3 0%Ni-C ---- 7 +m-7c 7*-3 8ŠIJÍ 3.8%NÍ JO%Ni oc -O- -O- + r -""23=6 O ■ ■ +M23C6 O O -hm7c3 A* O. 25 O. 50 O - 75 1 . O0 C [hm. %] 0.80 Vlastní měření 0 fcc/M7C3 9 fcc/M23c6 o Q) ■H n d A! > 0.60 £^ X U x \ a 0.40 : i Rovnovážné rozdělení chrómu v soustavě Fe-Cr-C 2a teploty 1000°C mezi fázi fcc a karbid M23C6 resp, karbid M7C3 získané teoretickým výpočtem -získanými experimentálně. ve srovnání s hodnotami 3enz o fcc/M7C3 a fcc/M23c6 0.05 0.10 Nishizawa a fcc/H7C3 A fcc/M23C6 0.15 xcr/ (xCr-r^pG ■Xp-) v fcc Rovnovážne rc-tíěleni chromú v soustavě ?e-Cr-Ni-C z?, tep 1000°C mezi iázi zcc r. V.arbic: ^>3có -*s?- karbid >!7č získané teoretickým výpočtem vn srovnáni s hodnotám získanými experimentálně. 0-10 0.15_ 0.20 0.25 0.3 0 XCr/(XCr+XNi+XFe) v fcc