C4660 Basic Physical Chemistry

Faculty of Science
spring 2018
Extent and Intensity
2/0/0. 2 credit(s) (plus extra credits for completion). Recommended Type of Completion: zk (examination). Alternate Types of Completion: k (colloquium).
Teacher(s)
doc. Mgr. Markéta Munzarová, Dr. rer. nat. (lecturer)
doc. Mgr. Dominik Heger, Ph.D. (lecturer)
doc. RNDr. Jan Hrbáč, Ph.D. (lecturer)
Supervisor
doc. Mgr. Markéta Munzarová, Dr. rer. nat.
Department of Chemistry - Chemistry Section - Faculty of Science
Supplier department: Department of Chemistry - Chemistry Section - Faculty of Science
Prerequisites
Mathematics course in the extent of the first semester of bachelor's study fields of biochemistry, chemistry, biology, or biophysics.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
Fields of study the course is directly associated with
there are 41 fields of study the course is directly associated with, display
Course objectives
A. Understanding basic concepts of chemical thermodynamics and kinetics with a relation to previous, simultaneous and following courses. B. Step-by-step development of abstract thinking.
Learning outcomes
After completing this course students will understand, at an introductory level, fundamental concepts of chemical thermodynamics and kinetics. Students will be able to solve corresponding computational exercises and will develop skills to derive basic thermodynamic relationships.
Syllabus
  • (1) Equilibrium thermodynamics. Thermodynamic system and its description, thermodynamic processes, zeroth and first law, heat and work. (2) State functions. Enthalpy, heat capacity, thermochemistry, reaction and formation enthalpy, standard state. (3) Thermodynamic criterion for spontaneity. Entropy, second law, Clausius inequality, Gibbs and Helmholtz function, maximum work, third law, absolute entropy. (4) Ideal and real systems. Combined first and second laws, temperature and pressure dependence of Gibbs function, chemical potential, fugacity, activity, solutions, change of composition. (5) Phase equilibrium. Condition of phase equilibrium, Gibbs phase rule, phase diagrams for one and more components. (6) Chemical equilibrium. Reaction and standard reaction Gibbs function, reaction quotient, equilibrium constant and its temperature dependence. (7) Transport. Diffusion, kinetics of simple reactions, mechanism, activated complex theory, reaction coordinate, activation energy.
Literature
    recommended literature
  • ATKINS, P. W. and Julio DE PAULA. Fyzikální chemie. Vyd. 1. Praha: Vysoká škola chemicko-technologická v Praze, 2013. xxvi, 915. ISBN 9788070808306. info
  • ATKINS, P. W. and Julio DE PAULA. Atkins' physical chemistry. 8th ed. Oxford: Oxford University Press, 2006. xxx, 1064. ISBN 0198700725. info
    not specified
  • ATKINS, P. W. and Julio DE PAULA. Atkins' physical chemistry. 7th ed. Oxford: Oxford University Press, 2002. xxi, 1150. ISBN 0198792859. info
  • ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998. 1014 s. ISBN 0198501013. info
  • ATKINS, P. W. Fyzikálna chémia. 6. vyd. Bratislava: Slovenská technická univerzita v Bratislave, 1999. 308 s. ISBN 80-227-1238-8. info
  • KUBÁČEK, Pavel and Zdena MICHALIČKOVÁ. Základy fyzikální chemie. Elportál, Brno: Masarykova univerzita, 2011. ISSN 1802-128X. URL info
  • Kubáček, Pavel. Základy fyzikální chemie. Hypertext, MU 2004; http://cheminfo.chemi.muni.cz/ianua/ZFCh
  • MOORE, Walter J. Fyzikální chemie. 2. vyd. Praha: Nakladatelství technické literatury, 1981. 974 s. info
  • Comprehensive dictionary of physical chemistry. Edited by Ladislav Ulický - Terence James Kemp. 1st pub. New York: Ellis Horwood, 1992. 472 s. ISBN 0-13-151747-3. info
Bookmarks
https://is.muni.cz/ln/tag/PříF:C4660!
Teaching methods
Thirteen non-obligatory lectures.
Assessment methods
Written test (non-electronic one) in 100 minutes length. Both open and closed questions will be included, covering both computational and theoretical questions. A minimum score of 50% points is required for a successful completion of the course.
Language of instruction
Czech
Follow-Up Courses
Further comments (probably available only in Czech)
The course is taught each semester.
The course is taught: every week.
Listed among pre-requisites of other courses

Zobrazit další předměty

Teacher's information
Předmět C3150 Fyzikální chemie I - seminář je silně doporučen jako významná pomoc k úspěšnému absolvování předmětu C4660.
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Autumn 2010 - only for the accreditation, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Autumn 2005, Spring 2006, Autumn 2006, Spring 2007, Autumn 2007, Spring 2008, Autumn 2008, Spring 2009, Autumn 2009, Spring 2010, Autumn 2010, Spring 2011, Spring 2012, Autumn 2011 - acreditation, spring 2012 - acreditation, Spring 2013, Spring 2014, Spring 2015, Spring 2016, Spring 2017.
  • Enrolment Statistics (recent)
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