C6190 Advanced laboratory course of inorganic chemistry.

Faculty of Science
Autumn 2020
Extent and Intensity
0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).
Taught in person.
Teacher(s)
Mgr. Iaroslav Doroshenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)
Guaranteed by
prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry - Chemistry Section - Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry - Chemistry Section - Faculty of Science
Prerequisites
C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.
Learning outcomes
After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;
Syllabus
  • Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné

    Úloha 2. Příprava tetraacetoxysilanu

    Úloha 3. Příprava cyklického aluminofosfátu

    Úloha 4. Příprava silikofosfátového xerogelu

    Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)

    Úloha 6. Příprava komplexů dppf

    Charakterizace produktů:

    1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature
  • Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
  • GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998. xiii, 272. ISBN 0-935702-48-2. info
  • SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969. xiii, 299. info
Teaching methods
Laboratory course, literature search, practical execution of synthetic experiments
Assessment methods
Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.
Language of instruction
Czech
Follow-Up Courses
Further comments (probably available only in Czech)
The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2000, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Autumn 2011 - acreditation, Autumn 2019.
  • Enrolment Statistics (recent)
  • Permalink: https://is.muni.cz/course/sci/autumn2020/C6190