C9888 Modern Trends in Inorganic Chemistry

Přírodovědecká fakulta
jaro 2019
Rozsah
1/0/0. 1 kr. Doporučované ukončení: zk. Jiná možná ukončení: k.
Vyučující
prof. RNDr. Jiří Pinkas, Ph.D. (přednášející)
Mgr. Zdeněk Moravec, Ph.D. (přednášející)
Mgr. Aleš Stýskalík, Ph.D. (přednášející)
Garance
prof. RNDr. Jiří Pinkas, Ph.D.
Ústav chemie - Chemická sekce - Přírodovědecká fakulta
Kontaktní osoba: prof. RNDr. Jiří Pinkas, Ph.D.
Dodavatelské pracoviště: Ústav chemie - Chemická sekce - Přírodovědecká fakulta
Předpoklady
C4010 Inorganic Chemistry III
Thorough knowledge of Inorganic Chemistry, Coordination Chemistry, Inorganic Materials Chemistry, and Organometallic Chemistry is expected in order to be able to follow advanced topics covered in this course.
Omezení zápisu do předmětu
Předmět je nabízen i studentům mimo mateřské obory.
Mateřské obory/plány
Cíle předmětu
This course Modern Trends in Inorganic Chemistry is specifically prepared for doctoral students in Inorganic Chemistry. It will aim to provide current knowledge and state-of-the-art in different fields of inorganic chemistry. The course will cover advanced topics of current research and it will broaden student knowledge gained in courses of Inorganic Chemistry, Coordination Chemistry, Inorganic Materials Chemistry, and Organometallic Chemistry.
Výstupy z učení
After attending this course, students will be able to:
- understand current major trends in research in following areas:
Main Group Compounds
Transition Metal Complexes
Inorganic Materials Chemistry
Spectroscopic Methods employed in Inorganic Chemistry
Magnetochemistry
Catalysis
- recognize important work of research and discoveries in current literature
- apply gained knowledge in his/her dissertation work
- prepare a short research proposal
Osnova
  • 1. Main Group Compounds. New compounds with unusual oxidation states, bonding situations and coordination environments. High-energy compounds. Compounds of rare gasses. Chemistry of superacids and superbases.
  • 2. Transition Metal Complexes. Complexes with pincer ligands, polynuclear complexes, chiral complexes. Coordination polymers. Molecules with multiple metal-metal bonds.
  • 3. Inorganic Materials. Materials for energy generation and storage. Materials for as adsorption and sieving, zeolites, micro, meso, macro porous materials, hierarchical materials, MOFs.
  • 4. Advanced Spectroscopic Methods. NMR and EPR spectroscopy of transition metal complexes. Vibrational spectroscopy.
  • 5. Magnetic Materials. Magnetochemistry. Spin crossovers. Spin frustration. Molecular magnets. Spintronics.
  • 6. Transition Metals in Catalysis. Oxidation, hydrogenation, carbonylation, polymerization, isomerization. Metallocene catalysis. Solid acid catalysts.
  • 7. Complexes of Unusual Ligands. Macrocyclic ligands, cavitands, rotaxenes, helicates.
  • 8. Medicinal and Diagnostic Applications of Metal Complexes. New Pt a Ru compounds in cancer therapy. Contrast agents for magnetic resonance imaging.
Literatura
    doporučená literatura
  • Inorganic Chemistry - ACS journal
  • Angewandte Chemie International Edition. 2009. ISSN 1433-7851. info
  • COTTON, F. Albert. Advanced inorganic chemistry. 6th ed. New York: John Wiley & Sons, 1999. xv, 1355. ISBN 0471199575. info
Výukové metody
Lectures, reading assignments, presentations, research proposal
Metody hodnocení
Grading of student presentations, research proposals, final oral examination.
Vyučovací jazyk
Angličtina
Další komentáře
Předmět je vyučován každoročně.
Výuka probíhá každý týden.
Předmět je zařazen také v obdobích jaro 2020.