Solvent-induced changes in dimensionality of praseodymium
coordination polymers with diphenylphosphorylvalerate ligand

J 2012

Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand

SPÍCHAL, Zdeněk, Jiří PINKAS and Marek NEČAS

Basic information

Original name

Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand

Authors

SPÍCHAL, Zdeněk (203 Czech Republic, belonging to the institution), Jiří PINKAS (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

Polyhedron, Elsevier Science Ltd. 2012, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.813

RIV identification code

RIV/00216224:14740/12:00057643

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1016/j.poly.2012.08.056

UT WoS

000311927700012

Keywords in English

Diphenylphosphorylvaleric acid; Praseodymium; Coordination polymers; X-ray crystallography

Abstract

V originále

Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1–H)3(NO3)3 (1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1–H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

GAP207/11/0555, research and development project

Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation

GA203/08/1111, research and development project

Name: Syntéza a vlastnosti anorganicko-organických polymerních materiálů

Investor: Czech Science Foundation, Synthesis and properties of inorganic-organic polymeric materials

Citovat

SPÍCHAL, Zdeněk, Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. Polyhedron. Elsevier Science Ltd., 2012, vol. 48, No 1, p. 99-103. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056.

@article{1068870,
   author = {Spíchal, Zdeněk and Pinkas, Jiří and Nečas, Marek},
   article_number = {1},
   doi = {http://dx.doi.org/10.1016/j.poly.2012.08.056},
   keywords = {Diphenylphosphorylvaleric acid; Praseodymium; Coordination polymers; X-ray crystallography},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand},
   url = {http://dx.doi.org/10.1016/j.poly.2012.08.056},
   volume = {48},
   year = {2012}
}

TY  - JOUR
ID  - 1068870
AU  - Spíchal, Zdeněk - Pinkas, Jiří - Nečas, Marek
PY  - 2012
TI  - Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand
JF  - Polyhedron
VL  - 48
IS  - 1
SP  - 99-103
EP  - 99-103
PB  - Elsevier Science Ltd.
SN  - 02775387
KW  - Diphenylphosphorylvaleric acid
KW  - Praseodymium
KW  - Coordination polymers
KW  - X-ray crystallography
UR  - http://dx.doi.org/10.1016/j.poly.2012.08.056
L2  - http://dx.doi.org/10.1016/j.poly.2012.08.056
N2  - Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1–H)3(NO3)3 (1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1–H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques.
ER  -

SPÍCHAL, Zdeněk, Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. \textit{Polyhedron}. Elsevier Science Ltd., 2012, vol.~48, No~1, p.~99-103. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056.

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