SPÍCHAL, Zdeněk, Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. Polyhedron. Elsevier Science Ltd., 2012, vol. 48, No 1, p. 99-103. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056. |
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@article{1068870, author = {Spíchal, Zdeněk and Pinkas, Jiří and Nečas, Marek}, article_number = {1}, doi = {http://dx.doi.org/10.1016/j.poly.2012.08.056}, keywords = {Diphenylphosphorylvaleric acid; Praseodymium; Coordination polymers; X-ray crystallography}, language = {eng}, issn = {0277-5387}, journal = {Polyhedron}, title = {Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand}, url = {http://dx.doi.org/10.1016/j.poly.2012.08.056}, volume = {48}, year = {2012} }
TY - JOUR ID - 1068870 AU - Spíchal, Zdeněk - Pinkas, Jiří - Nečas, Marek PY - 2012 TI - Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand JF - Polyhedron VL - 48 IS - 1 SP - 99-103 EP - 99-103 PB - Elsevier Science Ltd. SN - 02775387 KW - Diphenylphosphorylvaleric acid KW - Praseodymium KW - Coordination polymers KW - X-ray crystallography UR - http://dx.doi.org/10.1016/j.poly.2012.08.056 L2 - http://dx.doi.org/10.1016/j.poly.2012.08.056 N2 - Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1–H)3(NO3)3 (1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1–H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques. ER -
SPÍCHAL, Zdeněk, Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. \textit{Polyhedron}. Elsevier Science Ltd., 2012, vol.~48, No~1, p.~99-103. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056.
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