Solvent-induced changes in dimensionality of praseodymium
coordination polymers with diphenylphosphorylvalerate ligand

J 2012

Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand

SPÍCHAL, Zdeněk; Jiří PINKAS and Marek NEČAS

Basic information

Original name

Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand

Authors

SPÍCHAL, Zdeněk (203 Czech Republic, belonging to the institution); Jiří PINKAS (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

Polyhedron, Elsevier Science Ltd. 2012, 0277-5387

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

References:

URL

Impact factor

Impact factor: 1.813

RIV identification code

RIV/00216224:14740/12:00057643

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1016/j.poly.2012.08.056

UT WoS

000311927700012

Keywords in English

Diphenylphosphorylvaleric acid; Praseodymium; Coordination polymers; X-ray crystallography

Abstract

In the original language

Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1–H)3(NO3)3 (1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1–H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

GAP207/11/0555, research and development project

Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation

GA203/08/1111, research and development project

Name: Syntéza a vlastnosti anorganicko-organických polymerních materiálů

Investor: Czech Science Foundation, Synthesis and properties of inorganic-organic polymeric materials

Cite

SPÍCHAL, Zdeněk; Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. Polyhedron. Elsevier Science Ltd., 2012, vol. 48, No 1, p. 99-103. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056.

@article{1068870,
   author = {Spíchal, Zdeněk and Pinkas, Jiří and Nečas, Marek},
   article_number = {1},
   doi = {http://dx.doi.org/10.1016/j.poly.2012.08.056},
   keywords = {Diphenylphosphorylvaleric acid; Praseodymium; Coordination polymers; X-ray crystallography},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand},
   url = {http://dx.doi.org/10.1016/j.poly.2012.08.056},
   volume = {48},
   year = {2012}
}

TY  - JOUR
ID  - 1068870
AU  - Spíchal, Zdeněk - Pinkas, Jiří - Nečas, Marek
PY  - 2012
TI  - Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand
JF  - Polyhedron
VL  - 48
IS  - 1
SP  - 99-103
EP  - 99-103
PB  - Elsevier Science Ltd.
SN  - 02775387
KW  - Diphenylphosphorylvaleric acid
KW  - Praseodymium
KW  - Coordination polymers
KW  - X-ray crystallography
UR  - http://dx.doi.org/10.1016/j.poly.2012.08.056
L2  - http://dx.doi.org/10.1016/j.poly.2012.08.056
N2  - Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1–H)3(NO3)3 (1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1–H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques.
ER  -

SPÍCHAL, Zdeněk; Jiří PINKAS and Marek NEČAS. Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand. \textit{Polyhedron}. Elsevier Science Ltd., 2012, vol.~48, No~1, p.~99-103. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2012.08.056.

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