ISHIHARA, Shinsuke, Jan LABUTA, Tomáš ŠIKORSKÝ, Jaroslav V. BURDA, Naoko OKAMOTO, Hideki ABE, Katsuhiko ARIGA and Jonathan P HILL. Colorimetric detection of trace water in tetrahydrofuran using N,N '-substituted oxoporphyrinogens. Chemical Communications. London: Royal Society of Chemistry, 2012, vol. 48, No 33, p. 3933-3935. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c2cc31118f.
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Basic information
Original name Colorimetric detection of trace water in tetrahydrofuran using N,N '-substituted oxoporphyrinogens
Authors ISHIHARA, Shinsuke (392 Japan), Jan LABUTA (392 Japan), Tomáš ŠIKORSKÝ (703 Slovakia, guarantor, belonging to the institution), Jaroslav V. BURDA (203 Czech Republic), Naoko OKAMOTO (392 Japan), Hideki ABE (392 Japan), Katsuhiko ARIGA (392 Japan) and Jonathan P HILL (392 Japan).
Edition Chemical Communications, London, Royal Society of Chemistry, 2012, 1359-7345.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10600 1.6 Biological sciences
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 6.378
RIV identification code RIV/00216224:14740/12:00074619
Organization unit Central European Institute of Technology
Doi http://dx.doi.org/10.1039/c2cc31118f
UT WoS 000301958500004
Keywords in English MAIN-GROUP THERMOCHEMISTRY; ORGANIC-SOLVENTS; NONCOVALENT INTERACTIONS; DYES; SOLVATOCHROMISM; OXIDATION; KINETICS
Tags kontrola MP, rivok
Tags International impact, Reviewed
Changed by Changed by: Martina Prášilová, učo 342282. Changed: 2/4/2015 13:03.
Abstract
Oxoporphyrinogens (OxPs) bind water molecules at pyrrolic NH and quinonoid carbonyl groups leading to visible colour changes due to variation in the pi-electronic structure of OxPs. Introduction of hydrophilic substituents at two pyrrole NH groups improves sensitivity to H2O, and one OxP derivative is a colorimetric indicator of trace H2O (similar to 50 ppm) in THF.
Links
ED1.1.00/02.0068, research and development projectName: CEITEC - central european institute of technology
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