Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl
Sulfoxide As a New Probing for Water Measurement”

J 2012

Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”

PEKÁRKOVÁ, Pavla, Přemysl LUBAL and Petr TÁBORSKÝ

Basic information

Original name

Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”

Name in Czech

Komentář ke článku“Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”

Authors

PEKÁRKOVÁ, Pavla (203 Czech Republic, belonging to the institution), Přemysl LUBAL (203 Czech Republic, belonging to the institution) and Petr TÁBORSKÝ (203 Czech Republic, guarantor, belonging to the institution)

Edition

Analytical Chemistry, Washington, D.C., (USA), American Chemical Society, 2012, 0003-2700

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

pdf

Impact factor

Impact factor: 5.695

RIV identification code

RIV/00216224:14740/12:00074643

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1021/ac301934d

UT WoS

000309493200051

Keywords in English

europium(III) luminiscence; luminiscence decay; water determination; organic solvent; ionic liquid

Abstract

V originále

Yao and Chen(see Analytical Chemistry (Washington, DC, United States) (2011), 83 (6), 1879-1882) have shown a method for determination of water traces in dimethyl sulfoxide (DMSO). The described method is interesting, but in our opinion, it can be entirely replaced by other methods using the same reagents and based on measurement of Eu(III) luminescence lifetimes. Moreover, there is quite a lot of inaccuracy in the article which we would like to comment. Finally, we want to briefly show a few other possible applications of the method described in this comment.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

ME09065, research and development project

Name: Výzkum nových detekčních systémů na bázi senzorových polí pro použití ve speciační analýze

Investor: Ministry of Education, Youth and Sports of the CR, Research of new detection systems based on sensor arrays for application in speciation analysis, Research and Development Programme KONTAKT (ME)

Citovat

PEKÁRKOVÁ, Pavla, Přemysl LUBAL and Petr TÁBORSKÝ. Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”. Analytical Chemistry. Washington, D.C., (USA): American Chemical Society, 2012, vol. 84, No 19, p. 8427-8428. ISSN 0003-2700. Available from: https://dx.doi.org/10.1021/ac301934d.

@article{1075153,
   author = {Pekárková, Pavla and Lubal, Přemysl and Táborský, Petr},
   article_location = {Washington, D.C., (USA)},
   article_number = {19},
   doi = {http://dx.doi.org/10.1021/ac301934d},
   keywords = {europium(III) luminiscence; luminiscence decay; water determination; organic solvent; ionic liquid},
   language = {eng},
   issn = {0003-2700},
   journal = {Analytical Chemistry},
   title = {Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”},
   url = {http://pubs.acs.org/doi/pdf/10.1021/ac301934d},
   volume = {84},
   year = {2012}
}

TY  - JOUR
ID  - 1075153
AU  - Pekárková, Pavla - Lubal, Přemysl - Táborský, Petr
PY  - 2012
TI  - Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”
JF  - Analytical Chemistry
VL  - 84
IS  - 19
SP  - 8427-8428
EP  - 8427-8428
PB  - American Chemical Society
SN  - 00032700
KW  - europium(III) luminiscence
KW  - luminiscence decay
KW  - water determination
KW  - organic solvent
KW  - ionic liquid
UR  - http://pubs.acs.org/doi/pdf/10.1021/ac301934d
N2  - Yao and Chen(see Analytical Chemistry (Washington, DC, United States) (2011), 83 (6), 1879-1882) have shown a method for determination of water traces in dimethyl sulfoxide (DMSO). The described method is interesting, but in our opinion, it can be entirely replaced by other methods using the same reagents and based on measurement of Eu(III) luminescence lifetimes. Moreover, there is quite a lot of inaccuracy in the article which we would like to comment. Finally, we want to briefly show a few other possible applications of the method described in this comment.
ER  -

PEKÁRKOVÁ, Pavla, Přemysl LUBAL and Petr TÁBORSKÝ. Comment on “Hypersensitive Luminiscence of Eu3+ in Dimethyl Sulfoxide As a New Probing for Water Measurement”. \textit{Analytical Chemistry}. Washington, D.C., (USA): American Chemical Society, 2012, vol.~84, No~19, p.~8427-8428. ISSN~0003-2700. Available from: https://dx.doi.org/10.1021/ac301934d.

Detailed Information on Publication Record