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@article{1086866, author = {Hlaváček, Antonín and Skládal, Petr}, article_location = {Hoboken, USA}, article_number = {9-10}, doi = {http://dx.doi.org/10.1002/elps.201100696}, keywords = {quantum dots; isotachoforesis; fluorescence; quantum yield}, language = {eng}, issn = {0173-0835}, journal = {Electrophoresis}, title = {Isotachophoretic purification of nanoparticles: tuning optical properties of quantum dots}, url = {http://onlinelibrary.wiley.com/doi/10.1002/elps.201100696/pdf}, volume = {33}, year = {2012} }
TY - JOUR ID - 1086866 AU - Hlaváček, Antonín - Skládal, Petr PY - 2012 TI - Isotachophoretic purification of nanoparticles: tuning optical properties of quantum dots JF - Electrophoresis VL - 33 IS - 9-10 SP - 1427-1430 EP - 1427-1430 PB - Wiley-Blackwell SN - 01730835 KW - quantum dots KW - isotachoforesis KW - fluorescence KW - quantum yield UR - http://onlinelibrary.wiley.com/doi/10.1002/elps.201100696/pdf L2 - http://onlinelibrary.wiley.com/doi/10.1002/elps.201100696/pdf N2 - Synthesized nanoparticles often require fine fractionation according to shape, dimension, mass, chemical composition, charge, and other properties in order to become suitable for practical use. Quantum dots (QDs) are luminescent nanocrystals with narrow emission peaks. This property has been widely utilized for the multiplexed sensing and barcoding of microparticles. QDs with narrower emission peaks are preferred for such applications. The width of the emission peaks can be significantly reduced after purification. A newly developed preparative isotachophoretic method employs the dependence of spectral properties and electrophoretic mobility on the diameter of QDs. Separated fractions of QDs revealed narrower emission peaks (72% of the original width) and improved quantum yield (two-fold). The usefulness of the developed isotachophoresis for purification and analysis of other nanostructures, for example, plasmonic nanoparticles and nanobioconjugates, is expected, too. ER -
HLAVÁČEK, Antonín and Petr SKLÁDAL. Isotachophoretic purification of nanoparticles: tuning optical properties of quantum dots. \textit{Electrophoresis}. Hoboken, USA: Wiley-Blackwell, 2012, vol.~33, 9-10, p.~1427-1430. ISSN~0173-0835. Available from: https://dx.doi.org/10.1002/elps.201100696.
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