Simultaneous determination of metal traces using SPE
preconcentration on Amberlite XAD-7 by ICP-MS in environmental
water and sample ecotoxicology assessment.

J 2012

Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment.

HOLUBOVA, Z., L. SOMMER, M. MOOS and Jan KUTA

Basic information

Original name

Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment.

Authors

HOLUBOVA, Z. (203 Czech Republic, guarantor), L. SOMMER (203 Czech Republic), M. MOOS (203 Czech Republic) and Jan KUTA (203 Czech Republic, belonging to the institution)

Edition

Fresenius Environmental Bulletin, FREISING, Germany, PARLAR SCIENTIFIC PUBLICATIONS (P S P), 2012, 1018-4619

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10511 Environmental sciences

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.641

RIV identification code

RIV/00216224:14310/12:00063907

Organization unit

Faculty of Science

UT WoS

000312412700018

Keywords in English

Solid Phase Extraction; Amberlite XAD-7; ICP-MS and Waters; Ecotoxicology

Abstract

V originále

This study has been focused on the determination of nine trace elements Be-9, V-51, Co-59, Ni-60, Y-89, led, (208)pb, Th-232 and U-238 by inductively coupled plasma mass spectrometry (ICP-MS) in natural waters and water samples after mining and processing of uranium.An ICP-MS spectrometer Agilent 7500ce, with a plasma generator of 27.12 MHz, power output of 1500 W and concentric nebulizer MicroMist (TM) with a cooled Scott chamber was used. The nonspectral interferences were eliminated by using a solution of internal standards Li-6 for Be-9, Sc-45 (V-51), Ge-72 (Co-59, Ni-60, (89)y), Rh-103 (Cd-111), Bi-209 ((208)pb, Th-232, U-238) The spectral interferences were eliminated by using the Helium collision cell during measurement. Monitored interfering elements were K+, Na+, NH4+ Ca2+, Mg2+, Al3+, Fe3+ and Cl-, HCO3-, SO42-, PO43-. For the preconcentration polymeric sorbent Amberlite XAD-7 was used. Elements were retained as their chelates with different organic reagents: 4-(2-pyridylazo) resorcinol (PAR), 3,4-Dihydroxy-9,10-dioxo-2-anthracenesulfonic acid sodium salt (ALS), 8-Hydroxyquinoline-5-sulphonic acid (8HQS) and Ammonium pyrrolidinedithiocarbamate (APDC).The sorption process was studied under various conditions with respect to pH. Sorbents were also conditioned with different surfactants: Benzyldimethyltetradecylammonium chloride (Zephyramine), 1-etoxycarbonyl-pentadecyl-trimethyl-ammonium bromide (Septonex (R)), Brij 35 or Sodium Dodecylsulphate (SDS). Various elution mixtures were also tested, the best results were obtained for the mixture of acetone and ethanol (1:1) in the presence of 1 mol.l(-1) HCl. The excess of acid and organic solvents were evaporated in Teflon (R) dishes prior to the determination by ICP-MS. The Thamnocephalus platyurus as THAMNOTOXKIT F (TM), Daphnia magna as a DAPHTOXKIT F (TM) and Artemia sauna as Artoxkit M (TM) are organisms, which were used for ecotoxicology assessment of water samples after mining of uranium.

Links

ED0001/01/01, research and development project

Name: CETOCOEN

Citovat

HOLUBOVA, Z., L. SOMMER, M. MOOS and Jan KUTA. Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment. Fresenius Environmental Bulletin. FREISING, Germany: PARLAR SCIENTIFIC PUBLICATIONS (P S P), 2012, vol. 21, 10A, p. 3127-3135. ISSN 1018-4619.

@article{1087985,
   author = {Holubova, Z. and Sommer, L. and Moos, M. and Kuta, Jan},
   article_location = {FREISING, Germany},
   article_number = {10A},
   keywords = {Solid Phase Extraction; Amberlite XAD-7; ICP-MS and Waters; Ecotoxicology},
   language = {eng},
   issn = {1018-4619},
   journal = {Fresenius Environmental Bulletin},
   title = {Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment.},
   volume = {21},
   year = {2012}
}

TY  - JOUR
ID  - 1087985
AU  - Holubova, Z. - Sommer, L. - Moos, M. - Kuta, Jan
PY  - 2012
TI  - Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment.
JF  - Fresenius Environmental Bulletin
VL  - 21
IS  - 10A
SP  - 3127-3135
EP  - 3127-3135
PB  - PARLAR SCIENTIFIC PUBLICATIONS (P S P)
SN  - 10184619
KW  - Solid Phase Extraction
KW  - Amberlite XAD-7
KW  - ICP-MS and Waters
KW  - Ecotoxicology
N2  - This study has been focused on the determination of nine trace elements Be-9, V-51, Co-59, Ni-60, Y-89, led, (208)pb, Th-232 and U-238 by inductively coupled plasma mass spectrometry (ICP-MS) in natural waters and water samples after mining and processing of uranium.An ICP-MS spectrometer Agilent 7500ce, with a plasma generator of 27.12 MHz, power output of 1500 W and concentric nebulizer MicroMist (TM) with a cooled Scott chamber was used. The nonspectral interferences were eliminated by using a solution of internal standards Li-6 for Be-9, Sc-45 (V-51), Ge-72 (Co-59, Ni-60, (89)y), Rh-103 (Cd-111), Bi-209 ((208)pb, Th-232, U-238) The spectral interferences were eliminated by using the Helium collision cell during measurement. Monitored interfering elements were K+, Na+, NH4+ Ca2+, Mg2+, Al3+, Fe3+ and Cl-, HCO3-, SO42-, PO43-. For the preconcentration polymeric sorbent Amberlite XAD-7 was used. Elements were retained as their chelates with different organic reagents: 4-(2-pyridylazo) resorcinol (PAR), 3,4-Dihydroxy-9,10-dioxo-2-anthracenesulfonic acid sodium salt (ALS), 8-Hydroxyquinoline-5-sulphonic acid (8HQS) and Ammonium pyrrolidinedithiocarbamate (APDC).The sorption process was studied under various conditions with respect to pH. Sorbents were also conditioned with different surfactants: Benzyldimethyltetradecylammonium chloride (Zephyramine), 1-etoxycarbonyl-pentadecyl-trimethyl-ammonium bromide (Septonex (R)), Brij 35 or Sodium Dodecylsulphate (SDS). Various elution mixtures were also tested, the best results were obtained for the mixture of acetone and ethanol (1:1) in the presence of 1 mol.l(-1) HCl. The excess of acid and organic solvents were evaporated in Teflon (R) dishes prior to the determination by ICP-MS. The Thamnocephalus platyurus as THAMNOTOXKIT F (TM), Daphnia magna as a DAPHTOXKIT F (TM) and Artemia sauna as Artoxkit M (TM) are organisms, which were used for ecotoxicology assessment of water samples after mining of uranium.
ER  -

HOLUBOVA, Z., L. SOMMER, M. MOOS and Jan KUTA. Simultaneous determination of metal traces using SPE preconcentration on Amberlite XAD-7 by ICP-MS in environmental water and sample ecotoxicology assessment. \textit{Fresenius Environmental Bulletin}. FREISING, Germany: PARLAR SCIENTIFIC PUBLICATIONS (P S P), 2012, vol.~21, 10A, p.~3127-3135. ISSN~1018-4619.

Detailed Information on Publication Record