Fluorescein Analogues as Photoremovable Protecting Groups
Absorbing at 520 nm

J 2013

Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm

ŠEBEJ, Peter, Jürgen WINTNER, Pavel MÜLLER, Tomáš SLANINA, Jamaludin AL ANSHORI et. al.

Basic information

Original name

Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm

Authors

ŠEBEJ, Peter (703 Slovakia, belonging to the institution), Jürgen WINTNER (756 Switzerland), Pavel MÜLLER (203 Czech Republic), Tomáš SLANINA (203 Czech Republic, belonging to the institution), Jamaludin AL ANSHORI (360 Indonesia, belonging to the institution), Lovely ANGEL P. A. (356 India, belonging to the institution), Petr KLÁN (203 Czech Republic, guarantor, belonging to the institution) and Jakob WIRZ (756 Switzerland)

Edition

Journal of Organic Chemistry, Columbus, OH, USA, the American Chemical Society, 2013, 0022-3263

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 4.638

RIV identification code

RIV/00216224:14310/13:00066105

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1021/jo301455n

UT WoS

000315707500017

Keywords in English

Photochemistry; protecting groups

Abstract

V originále

A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coefficient epsilon of 4 x 104 m–1 cm–1 at 520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ and shown to release the ligands with quantum yields 2.4% in aqueous solution.

Links

ED0001/01/01, research and development project

Name: CETOCOEN

GA203/09/0748, research and development project

Name: Nové fotoaktivovatelné sloučeniny pro organickou chemii a biologii

Investor: Czech Science Foundation, New photoactivatable compounds for organic chemistry and biology

LM2011028, research and development project

Name: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

ŠEBEJ, Peter, Jürgen WINTNER, Pavel MÜLLER, Tomáš SLANINA, Jamaludin AL ANSHORI, Lovely ANGEL P. A., Petr KLÁN and Jakob WIRZ. Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm. Journal of Organic Chemistry. Columbus, OH, USA: the American Chemical Society, 2013, vol. 78, No 5, p. 1833-1843. ISSN 0022-3263. Available from: https://dx.doi.org/10.1021/jo301455n.

@article{1104118,
   author = {Šebej, Peter and Wintner, Jürgen and Müller, Pavel and Slanina, Tomáš and Al Anshori, Jamaludin and Angel P. A., Lovely and Klán, Petr and Wirz, Jakob},
   article_location = {Columbus, OH, USA},
   article_number = {5},
   doi = {http://dx.doi.org/10.1021/jo301455n},
   keywords = {Photochemistry; protecting groups},
   language = {eng},
   issn = {0022-3263},
   journal = {Journal of Organic Chemistry},
   title = {Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm},
   url = {http://pubs.acs.org/doi/abs/10.1021/jo301455n},
   volume = {78},
   year = {2013}
}

TY  - JOUR
ID  - 1104118
AU  - Šebej, Peter - Wintner, Jürgen - Müller, Pavel - Slanina, Tomáš - Al Anshori, Jamaludin - Angel P. A., Lovely - Klán, Petr - Wirz, Jakob
PY  - 2013
TI  - Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm
JF  - Journal of Organic Chemistry
VL  - 78
IS  - 5
SP  - 1833-1843
EP  - 1833-1843
PB  - the American Chemical Society
SN  - 00223263
KW  - Photochemistry
KW  - protecting groups
UR  - http://pubs.acs.org/doi/abs/10.1021/jo301455n
N2  - A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coefficient epsilon of 4 x 104 m–1 cm–1 at 520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ and shown to release the ligands with quantum yields 2.4% in aqueous solution.
ER  -

ŠEBEJ, Peter, Jürgen WINTNER, Pavel MÜLLER, Tomáš SLANINA, Jamaludin AL ANSHORI, Lovely ANGEL P. A., Petr KLÁN and Jakob WIRZ. Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm. \textit{Journal of Organic Chemistry}. Columbus, OH, USA: the American Chemical Society, 2013, vol.~78, No~5, p.~1833-1843. ISSN~0022-3263. Available from: https://dx.doi.org/10.1021/jo301455n.

Detailed Information on Publication Record