Nonaqueous synthesis of molecular zinc amide phosphate

J 2014

Nonaqueous synthesis of molecular zinc amide phosphate

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR, Jiří PINKAS et. al.

Basic information

Original name

Nonaqueous synthesis of molecular zinc amide phosphate

Authors

CHYBA, Jan (203 Czech Republic, belonging to the institution), Zdeněk MORAVEC (203 Czech Republic, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution), Sanjay MATHUR (276 Germany) and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

Journal of Organometallic Chemistry, Lausanne, Elsevier Science, 2014, 0022-328X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 2.173

RIV identification code

RIV/00216224:14740/14:00074783

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1016/j.jorganchem.2013.09.040

UT WoS

000327939000030

Keywords in English

Zinc; Amide; Phosphate; X-ray structure; Nonaqueous

Abstract

V originále

Three new molecular zinc compounds were prepared by nonaqueous reactions of Zn[N(SiMe3)2]2 and ZnEt2 with trimethylsilylesters of phosphoric acid, OP(OSiMe3)3 and OP(OSiMe3)2(OH). Single-crystal Xray diffraction analyses of crystalline products revealed molecular structures of two mononuclear complexes [ZnX2OP(OSiMe3)3] (X = N(SiMe3)2 (1), hfacac = hexafluoroacetylacetonate, (2)) and one dinuclear zinc phosphate [(Zn{(py)N(SiMe3)2}{m2-O2P(OSiMe3)2})2] (3). Compound 1 is only the second structurally characterized adduct of zinc bisamide with an oxygen donor and a three-coordinate Zn atom. The cyclic inorganic core {Zn(m2-O2PO2)}2 in 3 is a model for the most common single four-ring (S4R) building unit of open-framework zinc phosphates. The molecule of 3 possesses reactive amide and trimethylsiloxy groups that can be employed in further studies on the formation of extended structures by condensation reactions. Spectroscopic properties and thermal behavior of the molecular products were examined. Compounds 1 and 3 were converted to a-Zn2P2O7 by calcination.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

EE2.3.30.0037, research and development project

Name: Zaměstnáním nejlepších mladých vědců k rozvoji mezinárodní spolupráce

7AMB13DE006, research and development project

Name: Chemické syntézy nano-fosforečnanů kovů pomocí mikrovlných, sonochemických a elektrospinningových metod (Acronym: SYNPHOSO)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR and Jiří PINKAS. Nonaqueous synthesis of molecular zinc amide phosphate. Journal of Organometallic Chemistry. Lausanne: Elsevier Science, 2014, vol. 749, Jan, p. 197-203. ISSN 0022-328X. Available from: https://dx.doi.org/10.1016/j.jorganchem.2013.09.040.

@article{1127162,
   author = {Chyba, Jan and Moravec, Zdeněk and Nečas, Marek and Mathur, Sanjay and Pinkas, Jiří},
   article_location = {Lausanne},
   article_number = {Jan},
   doi = {http://dx.doi.org/10.1016/j.jorganchem.2013.09.040},
   keywords = {Zinc; Amide; Phosphate; X-ray structure; Nonaqueous},
   language = {eng},
   issn = {0022-328X},
   journal = {Journal of Organometallic Chemistry},
   title = {Nonaqueous synthesis of molecular zinc amide phosphate},
   url = {http://www.sciencedirect.com/science/article/pii/S0022328X13007171},
   volume = {749},
   year = {2014}
}

TY  - JOUR
ID  - 1127162
AU  - Chyba, Jan - Moravec, Zdeněk - Nečas, Marek - Mathur, Sanjay - Pinkas, Jiří
PY  - 2014
TI  - Nonaqueous synthesis of molecular zinc amide phosphate
JF  - Journal of Organometallic Chemistry
VL  - 749
IS  - Jan
SP  - 197-203
EP  - 197-203
PB  - Elsevier Science
SN  - 0022328X
KW  - Zinc
KW  - Amide
KW  - Phosphate
KW  - X-ray structure
KW  - Nonaqueous
UR  - http://www.sciencedirect.com/science/article/pii/S0022328X13007171
L2  - http://www.sciencedirect.com/science/article/pii/S0022328X13007171
N2  - Three new molecular zinc compounds were prepared by nonaqueous reactions of Zn[N(SiMe3)2]2 and ZnEt2 with trimethylsilylesters of phosphoric acid, OP(OSiMe3)3 and OP(OSiMe3)2(OH). Single-crystal Xray diffraction analyses of crystalline products revealed molecular structures of two mononuclear complexes [ZnX2OP(OSiMe3)3] (X = N(SiMe3)2 (1), hfacac = hexafluoroacetylacetonate, (2)) and one dinuclear zinc phosphate [(Zn{(py)N(SiMe3)2}{m2-O2P(OSiMe3)2})2] (3). Compound 1 is only the second structurally characterized adduct of zinc bisamide with an oxygen donor and a three-coordinate Zn atom. The cyclic inorganic core {Zn(m2-O2PO2)}2 in 3 is a model for the most common single four-ring (S4R) building unit of open-framework zinc phosphates. The molecule of 3 possesses reactive amide and trimethylsiloxy groups that can be employed in further studies on the formation of extended structures by condensation reactions. Spectroscopic properties and thermal behavior of the molecular products were examined. Compounds 1 and 3 were converted to a-Zn2P2O7 by calcination.
ER  -

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR and Jiří PINKAS. Nonaqueous synthesis of molecular zinc amide phosphate. \textit{Journal of Organometallic Chemistry}. Lausanne: Elsevier Science, 2014, vol.~749, Jan, p.~197-203. ISSN~0022-328X. Available from: https://dx.doi.org/10.1016/j.jorganchem.2013.09.040.

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