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@article{1135969,
author = {Sopoušek, Jiří and Vřešťál, Jan and Pinkas, Jiří and Brož, Pavel and Buršík, Jiří and Stýskalík, Aleš and Škoda, David and Zobač, Ondřej and Lee, Joonho},
article_location = {OXFORD},
article_number = {June},
doi = {http://dx.doi.org/10.1016/j.calphad.2013.11.004},
keywords = {nanoalloy; phase diagram;thermodynamic modeling;characterization;surface energy},
language = {eng},
issn = {0364-5916},
journal = {CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY},
title = {Cu–Ni nanoalloy phase diagram – Prediction and experiment},
url = {http://yadda.icm.edu.pl/yadda/element/bwmeta1.element.elsevier-10d0e0df-971c-36d4-9d50-3d8102c58420},
volume = {45},
year = {2014}
}
TY - JOUR
ID - 1135969
AU - Sopoušek, Jiří - Vřešťál, Jan - Pinkas, Jiří - Brož, Pavel - Buršík, Jiří - Stýskalík, Aleš - Škoda, David - Zobač, Ondřej - Lee, Joonho
PY - 2014
TI - Cu–Ni nanoalloy phase diagram – Prediction and experiment
JF - CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
VL - 45
IS - June
SP - 33-39
EP - 33-39
PB - Elsevier Science
SN - 03645916
KW - nanoalloy
KW - phase diagram;thermodynamic modeling;characterization;surface energy
UR - http://yadda.icm.edu.pl/yadda/element/bwmeta1.element.elsevier-10d0e0df-971c-36d4-9d50-3d8102c58420
L2 - http://yadda.icm.edu.pl/yadda/element/bwmeta1.element.elsevier-10d0e0df-971c-36d4-9d50-3d8102c58420
N2 - The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.
ER -
SOPOUŠEK, Jiří, Jan VŘEŠŤÁL, Jiří PINKAS, Pavel BROŽ, Jiří BURŠÍK, Aleš STÝSKALÍK, David ŠKODA, Ondřej ZOBAČ and Joonho LEE. Cu–Ni nanoalloy phase diagram – Prediction and experiment. \textit{CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY}. OXFORD: Elsevier Science, 2014, vol.~45, June, p.~33-39. ISSN~0364-5916. Available from: https://dx.doi.org/10.1016/j.calphad.2013.11.004.
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