Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane

SPÍCHAL, Zdeněk, Andrej JANČAŘÍK, Ctibor MAZAL, Jiří PINKAS, Pavla PEKÁRKOVÁ and Marek NEČAS. Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane. Polyhedron. Elsevier Science Ltd., 2013, vol. 62, OCT 7 2013, p. 83-88. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2013.06.026.

Basic information

• Original name: Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane
• Authors: SPÍCHAL, Zdeněk (203 Czech Republic, belonging to the institution), Andrej JANČAŘÍK (203 Czech Republic, belonging to the institution), Ctibor MAZAL (203 Czech Republic, belonging to the institution), Jiří PINKAS (203 Czech Republic, belonging to the institution), Pavla PEKÁRKOVÁ (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, guarantor, belonging to the institution).
• Edition: Polyhedron, Elsevier Science Ltd. 2013, 0277-5387.

Other information

• Original language: English
• Type of outcome: Article in a journal
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: United Kingdom of Great Britain and Northern Ireland
• Confidentiality degree: is not subject to a state or trade secret
• WWW: URL
• Impact factor: Impact factor: 2.047
• RIV identification code: RIV/00216224:14310/13:00066742
• Organization unit: Faculty of Science
• Doi: http://dx.doi.org/10.1016/j.poly.2013.06.026
• UT WoS: 000324226200011
• Keywords in English: Bicyclopentanes;Lanthanides;Coordination polymers;X-ray crystallography
• Tags: AKR, rivok

Abstract

The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)1.5(NO3)3 (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques.

Links

• ED1.1.00/02.0068, research and development project: Name: CEITEC - central european institute of technology
• GAP207/11/0555, research and development project: Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation

• GA203/08/1111, research and development project: Name: Syntéza a vlastnosti anorganicko-organických polymerních materiálů

Investor: Czech Science Foundation, Synthesis and properties of inorganic-organic polymeric materials

• MUNI/A/0980/2009, interní kód MU: Name: Molekulární a supramolekulární stavební bloky pro nanostrukturované materiály (Acronym: MOSTNAMAT)

Investor: Masaryk University, Category A