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@article{1159644, author = {Loos, Robert and Carvalho, Raquel and Antonio, Diana C and Cornero, Sara and Locoro, Giovanni and Tavazzi, Simona and Paracchini, Bruno and Ghiani, Michela and Lettieri, Teresa and Bláha, Luděk and Jarošová, Barbora and Voorspoels, Stefan and Servaes, Kelly and Haglund, Peter and Fick, Jerker and Lindberg, Richard H and Schwesig, David and Gawlik, Bernd M}, article_location = {OXFORD}, article_number = {17}, doi = {http://dx.doi.org/10.1016/j.watres.2013.08.024}, keywords = {Wastewater treatment plants (WWTPs); Effluent water; European wide monitoring; Polar organic contaminants; Pharmaceuticals and personal care products (PPCPs)}, language = {eng}, issn = {0043-1354}, journal = {Water Research}, title = {EU-wide monitoring survey on emerging polar organic contaminants in wastewater treatment plant effluents}, volume = {47}, year = {2013} }
TY - JOUR ID - 1159644 AU - Loos, Robert - Carvalho, Raquel - Antonio, Diana C - Cornero, Sara - Locoro, Giovanni - Tavazzi, Simona - Paracchini, Bruno - Ghiani, Michela - Lettieri, Teresa - Bláha, Luděk - Jarošová, Barbora - Voorspoels, Stefan - Servaes, Kelly - Haglund, Peter - Fick, Jerker - Lindberg, Richard H - Schwesig, David - Gawlik, Bernd M PY - 2013 TI - EU-wide monitoring survey on emerging polar organic contaminants in wastewater treatment plant effluents JF - Water Research VL - 47 IS - 17 SP - 6475-6487 EP - 6475-6487 PB - Elsevier SN - 00431354 KW - Wastewater treatment plants (WWTPs) KW - Effluent water KW - European wide monitoring KW - Polar organic contaminants KW - Pharmaceuticals and personal care products (PPCPs) N2 - In the year 2010, effluents from 90 European wastewater treatment plants (WWTPs) were analyzed for 156 polar organic chemical contaminants. The analyses were complemented by effect-based monitoring approaches aiming at estrogenicity and dioxin-like toxicity analyzed by in vitro reporter gene bioassays, and yeast and diatom culture acute toxicity optical bioassays. Analyses of organic substances were performed by SPE or LLE followed by LC-MS-MS or GC-HRMS. Target microcontaminants were pharmaceuticals and personal care products (PPCPs), veterinary drugs, perfluoroalkyl substances (PFASs), organophosphate ester flame retardants, pesticides (and some metabolites), industrial chemicals such as benzotriazoles (corrosion inhibitors), iodinated x-ray contrast agents, and gadolinium magnetic resonance imaging agents; in addition biological endpoints were measured. The obtained results show the presence of 125 substances (80% of the target compounds) in European wastewater effluents, in concentrations ranging from low nanograms to milligrams per liter. These results allow for an estimation to be made of a European median level for the chemicals investigated in WWTP effluents. The most relevant compounds in the effluent waters with the highest median concentration levels were the artificial sweeteners acesulfame and sucralose, benzotriazoles (corrosion inhibitors), several organophosphate ester flame retardants and plasticizers (e.g. tris(2-chloroisopropyl)phosphate; TCPP), pharmaceutical compounds such as carbamazepine, tramadol, telmisartan, venlafaxine, irbesartan, fluconazole, oxazepam, fexofenadine, diclofenac, citalopram, codeine, bisoprolol, eprosartan, the antibiotics trimethoprim, ciprofloxacine, sulfamethoxazole, and clindamycine, the insect repellent N,N'-diethyltoluamide (DEET), the pesticides MCPA and mecoprop, perfluoroalkyl substances (such as PFOS and PFOA), caffeine, and gadolinium. ER -
LOOS, Robert, Raquel CARVALHO, Diana C ANTONIO, Sara CORNERO, Giovanni LOCORO, Simona TAVAZZI, Bruno PARACCHINI, Michela GHIANI, Teresa LETTIERI, Luděk BLÁHA, Barbora JAROŠOVÁ, Stefan VOORSPOELS, Kelly SERVAES, Peter HAGLUND, Jerker FICK, Richard H LINDBERG, David SCHWESIG and Bernd M GAWLIK. EU-wide monitoring survey on emerging polar organic contaminants in wastewater treatment plant effluents. \textit{Water Research}. OXFORD: Elsevier, 2013, vol.~47, No~17, p.~6475-6487. ISSN~0043-1354. Available from: https://dx.doi.org/10.1016/j.watres.2013.08.024.
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