Diethyl [4-(2,2:6,2-terpyridine-4-yl)phenyl]phosphonate

CHYBA, Jan, Marek NEČAS and Jiří PINKAS. Diethyl [4-(2,2:6,2-terpyridine-4-yl)phenyl]phosphonate. Acta Crystallographica Section E: Structure Reports Online. International Union of Crystallography, 2013, vol. 69, No 12, p. "o1824-1"- "o1824-9", 9 pp. ISSN 1600-5368. Available from: https://dx.doi.org/10.1107/S1600536813031541.

Basic information

• Original name: Diethyl [4-(2,2:6,2-terpyridine-4-yl)phenyl]phosphonate
• Authors: CHYBA, Jan (203 Czech Republic, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution) and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution).
• Edition: Acta Crystallographica Section E: Structure Reports Online, International Union of Crystallography, 2013, 1600-5368.

Other information

• Original language: English
• Type of outcome: Article in a journal
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: United Kingdom of Great Britain and Northern Ireland
• Confidentiality degree: is not subject to a state or trade secret
• WWW: URL
• Impact factor: Impact factor: 0.347 in 2011
• RIV identification code: RIV/00216224:14740/13:00066759
• Organization unit: Central European Institute of Technology
• Doi: http://dx.doi.org/10.1107/S1600536813031541
• UT WoS: 000421638200114
• Keywords in English: terpyridine; phosphonate; structure
• Tags: rivok
• Tags: International impact, Reviewed

Abstract

The title compound, C25H24N3O3P, was obtained by catalytic phosphonation of 4'-(4-bromphenyl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9) deg. The N atoms in the two pyridine rings are oriented nearly antiperiplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6) deg.

Links

• ED1.1.00/02.0068, research and development project: Name: CEITEC - central european institute of technology
• GAP207/11/0555, research and development project: Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation