| ANGEL P. A., Lovely, Tomáš SLANINA, Peter ŠEBEJ, Tomáš ŠOLOMEK and Petr KLÁN. Fluorescein Analogue Xanthene-9-Carboxylic Acid: A Transition-Metal Free CO Releasing Molecule Activated by Green Light. Organic Letters. Washington D.C., USA: American Chemical Society, 2013, vol. 15, No 17, p. 4552-4555. ISSN 1523-7060. Available from: https://dx.doi.org/10.1021/ol4021089. |
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@article{1159866,
author = {Angel P. A., Lovely and Slanina, Tomáš and Šebej, Peter and Šolomek, Tomáš and Klán, Petr},
article_location = {Washington D.C., USA},
article_number = {17},
doi = {http://dx.doi.org/10.1021/ol4021089},
keywords = {Photochemistry; photoremovable protecting group; carbon monoxide},
language = {eng},
issn = {1523-7060},
journal = {Organic Letters},
title = {Fluorescein Analogue Xanthene-9-Carboxylic Acid: A Transition-Metal Free CO Releasing Molecule Activated by Green Light},
url = {http://pubs.acs.org/doi/abs/10.1021/ol4021089},
volume = {15},
year = {2013}
}
TY - JOUR
ID - 1159866
AU - Angel P. A., Lovely - Slanina, Tomáš - Šebej, Peter - Šolomek, Tomáš - Klán, Petr
PY - 2013
TI - Fluorescein Analogue Xanthene-9-Carboxylic Acid: A Transition-Metal Free CO Releasing Molecule Activated by Green Light
JF - Organic Letters
VL - 15
IS - 17
SP - 4552-4555
EP - 4552-4555
PB - American Chemical Society
SN - 15237060
KW - Photochemistry
KW - photoremovable protecting group
KW - carbon monoxide
UR - http://pubs.acs.org/doi/abs/10.1021/ol4021089
N2 - 6-Hydroxy-3-oxo-3H-xanthene-9-carboxylic acid is introduced as the first transition-metal-free carbon monoxide releasing molecule activated by visible light (photoCORM). This water-soluble fluorescein analogue releases carbon monoxide in both water and methanol upon irradiation at 500 nm. When selectively irradiated in the presence of hemoglobin (Hb) under physiological conditions, released CO is quantitatively trapped to form carboxyhemoglobin (COHb). The reaction progress can be accurately monitored by characteristic absorption and emission properties of the reactants and products.
ER -
ANGEL P. A., Lovely, Tomáš SLANINA, Peter ŠEBEJ, Tomáš ŠOLOMEK and Petr KLÁN. Fluorescein Analogue Xanthene-9-Carboxylic Acid: A Transition-Metal Free CO Releasing Molecule Activated by Green Light. \textit{Organic Letters}. Washington D.C., USA: American Chemical Society, 2013, vol.~15, No~17, p.~4552-4555. ISSN~1523-7060. Available from: https://dx.doi.org/10.1021/ol4021089.
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