HAVEL, Václav, Vladimír ŠINDELÁŘ, Marek NEČAS and Angel E KAIFER. Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle. CHEMICAL COMMUNICATIONS. Royal Society of Chemistry, 2014, vol. 50, No 11, p. 1372-1374. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c3cc47828a.
Other formats:   BibTeX LaTeX RIS
Basic information
Original name Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle
Name in Czech Vodou zprostředkovaná interakce benzoátů a tosylátů uvnitř bambusurilového makrocyklu
Authors HAVEL, Václav (203 Czech Republic, belonging to the institution), Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution) and Angel E KAIFER (840 United States of America).
Edition CHEMICAL COMMUNICATIONS, Royal Society of Chemistry, 2014, 1359-7345.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10401 Organic chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 6.834
RIV identification code RIV/00216224:14310/14:00073514
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1039/c3cc47828a
UT WoS 000329469800027
Keywords (in Czech) Protein; Capsules; Solvents; Family
Keywords in English Protein; Capsules; Solvents; Family
Tags AKR, rivok
Tags International impact, Reviewed
Changed by Changed by: doc. Mgr. Marek Nečas, Ph.D., učo 18809. Changed: 13/3/2018 10:25.
Abstract
A supramolecular complex between benzoates and a bambusuril crystallizes out immediately after mixing in chloroform but only in the presence of residual water molecules. In this complex each of the two portals of the macrocycle is occupied by one benzoate. Carboxylate groups are connected through hydrogen bonding interactions with one molecule of water positioned between them in the center of the bambusuril cavity. Similar water assisted host–guest behavior was also observed when tosylates instead of benzoates were used.
Links
ED0001/01/01, research and development projectName: CETOCOEN
GA13-15576S, research and development projectName: Syntéza a supramolekulární vlastnosti bambusurilů
Investor: Czech Science Foundation
LH11012, research and development projectName: Cucurbiturily a jejich deriváty umožňující tvorbu vodíkové vazby mezi ogranickými molekulami ve vodě (Acronym: CB-H)
Investor: Ministry of Education, Youth and Sports of the CR
PrintDisplayed: 25/7/2024 07:50