Low pressure plasmachemical processing of multi-walled carbon
nanotubes for the production of polyurethane composite films
with improved mechanical properties

J 2013

Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties

ZAJÍČKOVÁ, Lenka, Marek ELIÁŠ, Vilma BURŠÍKOVÁ, Zuzana STUDÝNKOVÁ, Věra MAZÁNKOVÁ et. al.

Basic information

Original name

Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties

Authors

ZAJÍČKOVÁ, Lenka (203 Czech Republic, guarantor, belonging to the institution), Marek ELIÁŠ (203 Czech Republic, belonging to the institution), Vilma BURŠÍKOVÁ (203 Czech Republic, belonging to the institution), Zuzana STUDÝNKOVÁ (203 Czech Republic, belonging to the institution), Věra MAZÁNKOVÁ (203 Czech Republic, belonging to the institution), Miroslav MICHLÍČEK (203 Czech Republic, belonging to the institution) and Jana HOUDKOVÁ (203 Czech Republic)

Edition

Thin Solid Films, Lausanne, Elsevier Science, 2013, 0040-6090

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10305 Fluids and plasma physics

Country of publisher

Switzerland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.867

RIV identification code

RIV/00216224:14740/13:00066977

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1016/j.tsf.2012.11.126

UT WoS

000320584800003

Keywords in English

Plasma functionalization; CCP; Carbon nanotubes; Polyurethane composites; XPS; FTIR; Depth sensing indentation

Abstract

V originále

Multiwalled carbon nanotubes (CNTs) were modified in low pressure capacitively coupled discharges (13.56 and 27.12 MHz) in Ar/NH3 and oxygen-containing gas mixtures. A direct functionalization by nitrogen groups was not possible but 1-3 percentage of carbon-oxygen bonds increased with the total oxygen content on the expenses of sp(2)C almost independently on the plasma conditions. The plasma modified CNTs were used as fillers for polyurethane (PU) composites prepared by in situ polymerization. The composites were investigated by depth sensing indentation that revealed the existence of surface harder layer caused probably by different polymerization process in the bulk and at the surface that was in a contact with air. The significant improvement of the hardness and elastic modulus was observed when plasma-modified CNTs with high amount of oxygen were added to PU. It also improved the creep resistance of the PU, whereas the ability to recover from a deformation, i.e. anelastic recovery, did not change much. (c) 2012 Elsevier B.V. All rights reserved.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

ED2.1.00/03.0086, research and development project

Name: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GAP205/10/1374, research and development project

Name: Syntéza uhlíkových nanotrubek plazmochemickou metodou a studium jejich funkčních vlastností

Investor: Czech Science Foundation

286154, interní kód MU

Name: SYLICA - Synergies of Life and Material Sciences to Create a New Future (Acronym: SYLICA)

Investor: European Union, Capacities

Files attached

ZVV_2013_1168496.pdf

Request the author's version of the file

Citovat

ZAJÍČKOVÁ, Lenka, Marek ELIÁŠ, Vilma BURŠÍKOVÁ, Zuzana STUDÝNKOVÁ, Věra MAZÁNKOVÁ, Miroslav MICHLÍČEK and Jana HOUDKOVÁ. Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties. Thin Solid Films. Lausanne: Elsevier Science, 2013, vol. 538, July, p. 7-15. ISSN 0040-6090. Available from: https://dx.doi.org/10.1016/j.tsf.2012.11.126.

@article{1168496,
   author = {Zajíčková, Lenka and Eliáš, Marek and Buršíková, Vilma and Studýnková, Zuzana and Mazánková, Věra and Michlíček, Miroslav and Houdková, Jana},
   article_location = {Lausanne},
   article_number = {July},
   doi = {http://dx.doi.org/10.1016/j.tsf.2012.11.126},
   keywords = {Plasma functionalization; CCP; Carbon nanotubes; Polyurethane composites; XPS; FTIR; Depth sensing indentation},
   language = {eng},
   issn = {0040-6090},
   journal = {Thin Solid Films},
   title = {Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties},
   url = {http://www.sciencedirect.com/science/article/pii/S0040609012016276?via=ihub},
   volume = {538},
   year = {2013}
}

TY  - JOUR
ID  - 1168496
AU  - Zajíčková, Lenka - Eliáš, Marek - Buršíková, Vilma - Studýnková, Zuzana - Mazánková, Věra - Michlíček, Miroslav - Houdková, Jana
PY  - 2013
TI  - Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties
JF  - Thin Solid Films
VL  - 538
IS  - July
SP  - 7-15
EP  - 7-15
PB  - Elsevier Science
SN  - 00406090
KW  - Plasma functionalization
KW  - CCP
KW  - Carbon nanotubes
KW  - Polyurethane composites
KW  - XPS
KW  - FTIR
KW  - Depth sensing indentation
UR  - http://www.sciencedirect.com/science/article/pii/S0040609012016276?via=ihub
L2  - http://www.sciencedirect.com/science/article/pii/S0040609012016276?via=ihub
N2  - Multiwalled carbon nanotubes (CNTs) were modified in low pressure capacitively coupled discharges (13.56 and 27.12 MHz) in Ar/NH3 and oxygen-containing gas mixtures. A direct functionalization by nitrogen groups was not possible but 1-3 percentage of carbon-oxygen bonds increased with the total oxygen content on the expenses of sp(2)C almost independently on the plasma conditions. The plasma modified CNTs were used as fillers for polyurethane (PU) composites prepared by in situ polymerization. The composites were investigated by depth sensing indentation that revealed the existence of surface harder layer caused probably by different polymerization process in the bulk and at the surface that was in a contact with air. The significant improvement of the hardness and elastic modulus was observed when plasma-modified CNTs with high amount of oxygen were added to PU. It also improved the creep resistance of the PU, whereas the ability to recover from a deformation, i.e. anelastic recovery, did not change much. (c) 2012 Elsevier B.V. All rights reserved.
ER  -

ZAJÍČKOVÁ, Lenka, Marek ELIÁŠ, Vilma BURŠÍKOVÁ, Zuzana STUDÝNKOVÁ, Věra MAZÁNKOVÁ, Miroslav MICHLÍČEK and Jana HOUDKOVÁ. Low pressure plasmachemical processing of multi-walled carbon nanotubes for the production of polyurethane composite films with improved mechanical properties. \textit{Thin Solid Films}. Lausanne: Elsevier Science, 2013, vol.~538, July, p.~7-15. ISSN~0040-6090. Available from: https://dx.doi.org/10.1016/j.tsf.2012.11.126.

Detailed Information on Publication Record