Determination of Intrinsic Binding Modes by Mass Spectrometry:
Gas-Phase Behavior of Adamantylated Bisimidazolium Guests
Complexed to Cucurbiturils

J 2012

Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils

CERNOCHOVA, Jarmila, Petra BRANNA, Michal ROUCHAL, Petr KULHÁNEK, Ivo KURITKA et. al.

Basic information

Original name

Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils

Authors

CERNOCHOVA, Jarmila (203 Czech Republic), Petra BRANNA (203 Czech Republic), Michal ROUCHAL (203 Czech Republic), Petr KULHÁNEK (203 Czech Republic, belonging to the institution), Ivo KURITKA (203 Czech Republic) and Robert VICHA (203 Czech Republic, guarantor)

Edition

Chemistry - A European Journal, Weinheim, WILEY-VCH Verlag, 2012, 0947-6539

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10600 1.6 Biological sciences

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 5.831

RIV identification code

RIV/00216224:14740/12:00075523

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1002/chem.201201444

UT WoS

000310066700013

Keywords in English

adamantane; cucurbituril; host–guest systems; imidazolium salts; supramolecular chemistry

Abstract

V originále

Adamantylated bisimidazolium cations exhibit a distinct fragmentation pathway in contrast to their cucurbit[7]uril (CB7) complexes. The observed alternative fragmentation of the guest molecule in a complex clearly correlates to the supposed sterically hindered or allowed slippage of the macrocycle over the axel molecule.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

Citovat

CERNOCHOVA, Jarmila, Petra BRANNA, Michal ROUCHAL, Petr KULHÁNEK, Ivo KURITKA and Robert VICHA. Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils. Chemistry - A European Journal. Weinheim: WILEY-VCH Verlag, 2012, vol. 18, No 43, p. 13633-13637. ISSN 0947-6539. Available from: https://dx.doi.org/10.1002/chem.201201444.

@article{1183260,
   author = {Cernochova, Jarmila and Branna, Petra and Rouchal, Michal and Kulhánek, Petr and Kuritka, Ivo and Vicha, Robert},
   article_location = {Weinheim},
   article_number = {43},
   doi = {http://dx.doi.org/10.1002/chem.201201444},
   keywords = {adamantane; cucurbituril; host–guest systems; imidazolium salts; supramolecular chemistry},
   language = {eng},
   issn = {0947-6539},
   journal = {Chemistry - A European Journal},
   title = {Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/chem.201201444/epdf},
   volume = {18},
   year = {2012}
}

TY  - JOUR
ID  - 1183260
AU  - Cernochova, Jarmila - Branna, Petra - Rouchal, Michal - Kulhánek, Petr - Kuritka, Ivo - Vicha, Robert
PY  - 2012
TI  - Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils
JF  - Chemistry - A European Journal
VL  - 18
IS  - 43
SP  - 13633-13637
EP  - 13633-13637
PB  - WILEY-VCH Verlag
SN  - 09476539
KW  - adamantane
KW  - cucurbituril
KW  - host–guest systems
KW  - imidazolium salts
KW  - supramolecular chemistry
UR  - http://onlinelibrary.wiley.com/doi/10.1002/chem.201201444/epdf
L2  - http://onlinelibrary.wiley.com/doi/10.1002/chem.201201444/epdf
N2  - Adamantylated bisimidazolium cations exhibit a distinct fragmentation pathway in contrast to their cucurbit[7]uril (CB7) complexes. The observed alternative fragmentation of the guest molecule in a complex clearly correlates to the supposed sterically hindered or allowed slippage of the macrocycle over the axel molecule.
ER  -

CERNOCHOVA, Jarmila, Petra BRANNA, Michal ROUCHAL, Petr KULHÁNEK, Ivo KURITKA and Robert VICHA. Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils. \textit{Chemistry - A European Journal}. Weinheim: WILEY-VCH Verlag, 2012, vol.~18, No~43, p.~13633-13637. ISSN~0947-6539. Available from: https://dx.doi.org/10.1002/chem.201201444.

Detailed Information on Publication Record