Synthesis of Cyclic Phosphazenes - Potential Additives to
Polymer Nanofibres

D 2013

Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres

BAČOVSKÁ, Radka; Jiří PŘÍHODA; Milan ALBERTI; Zbyněk VORÁČ; Patty WISIAN-NEILSON et. al.

Základní údaje

Originální název

Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres

Název česky

Syntéza Cyklických Fosfazenů - Potenciálních Aditiv do Polymerních Nanovláken

Autoři

BAČOVSKÁ, Radka (203 Česká republika, garant, domácí); Jiří PŘÍHODA (203 Česká republika); Milan ALBERTI (203 Česká republika); Zbyněk VORÁČ (203 Česká republika) a Patty WISIAN-NEILSON (703 Slovensko)

Vydání

1st Edition, 2013. Ostrava, NANOCON 2013, od s. 26-136, 111 s. 2013

Nakladatel

2013 TAGER Ltd., Ostrava

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Forma vydání

tištěná verze "print"

Kód RIV

RIV/00216224:14310/13:00076050

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-80-87294-44-4

Klíčová slova česky

Fosfazeny; Nanovlákna

Klíčová slova anglicky

Phosphazene; Nanofibres

Změněno: 27. 4. 2015 15:36, Ing. Andrea Mikešková

Anotace

V originále

Most practically applied synthetic polymers are created by chains of organic molecules. We tried to modify their properties using phosphazenic additives. Polyphosphazenes are inorganic polymers with a backbone of alternating phosphorus and nitrogen atoms with two organic or organometallic side groups linked to each phosphorus atom. The stability and strength of nitrogen-phosphorus bonds are well known in synthetic chemistry. These properties give polyphosphazenes many unique characteristics and possibilities of practical applications, e.g. flame retardants. The syntheses of fully substituted phosphazeno derivatives have been investigated in our research. The derivatives containing NH2-, PhO- or CF3CH2O- side groups were synthetized by substitution reactions from the most common cyclic phosphazene P3N3Cl6, the other derivatives having PC bond in their side groups were synthetized from (Me3Si)2NH and PPhCl2 using condensation method. The prepared phosphazene derivatives with required properties were tested as additives to common polymers. Some these mixtures are able to create nanofibres, made by electrospinning technology, that could have potential applications.

Citovat

BAČOVSKÁ, Radka; Jiří PŘÍHODA; Milan ALBERTI; Zbyněk VORÁČ a Patty WISIAN-NEILSON. Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres. In AMOS repro Ltd. Čs. Legií 8. NANOCON 2013. 1st Edition, 2013. Ostrava: 2013 TAGER Ltd., Ostrava, 2013, s. 26-136. ISBN 978-80-87294-44-4.

@inproceedings{1193770,
   author = {Bačovská, Radka and Příhoda, Jiří and Alberti, Milan and Voráč, Zbyněk and WisianandNeilson, Patty},
   address = {Ostrava},
   booktitle = {NANOCON 2013},
   edition = {1st Edition, 2013},
   editor = {AMOS repro Ltd. Čs. Legií 8},
   keywords = {Phosphazene; Nanofibres},
   howpublished = {tištěná verze "print"},
   language = {eng},
   location = {Ostrava},
   isbn = {978-80-87294-44-4},
   pages = {26-136},
   publisher = {2013 TAGER Ltd., Ostrava},
   title = {Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres},
   year = {2013}
}

TY  - CONF
ID  - 1193770
AU  - Bačovská, Radka - Příhoda, Jiří - Alberti, Milan - Voráč, Zbyněk - Wisian-Neilson, Patty
PY  - 2013
TI  - Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres
PB  - 2013 TAGER Ltd., Ostrava
CY  - Ostrava
SN  - 9788087294444
KW  - Phosphazene
KW  - Nanofibres
N2  - Most practically applied synthetic polymers are created by chains of organic molecules. We tried to modify their properties using phosphazenic additives. Polyphosphazenes are inorganic polymers with a backbone of alternating phosphorus and nitrogen atoms with two organic or organometallic side groups linked to each phosphorus atom. The stability and strength of nitrogen-phosphorus bonds are well known in synthetic chemistry. These properties give polyphosphazenes many unique characteristics and possibilities of practical applications, e.g. flame retardants. The syntheses of fully substituted phosphazeno derivatives have been investigated in our research. The derivatives containing NH2-, PhO- or CF3CH2O- side groups were synthetized by substitution reactions from the most common cyclic phosphazene P3N3Cl6, the other derivatives having PC bond in their side groups were synthetized from (Me3Si)2NH and PPhCl2 using condensation method. The prepared phosphazene derivatives with required properties were tested as additives to common polymers. Some these mixtures are able to create nanofibres, made by electrospinning technology, that could have potential applications.
ER  -

BAČOVSKÁ, Radka; Jiří PŘÍHODA; Milan ALBERTI; Zbyněk VORÁČ a Patty WISIAN-NEILSON. Synthesis of Cyclic Phosphazenes - Potential Additives to Polymer Nanofibres. In AMOS repro Ltd. Čs. Legií 8. \textit{NANOCON 2013}. 1st Edition, 2013. Ostrava: 2013 TAGER Ltd., Ostrava, 2013, s.~26-136. ISBN~978-80-87294-44-4.

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