PREPARATION OF NEW COORDINATION   COMPOUNDS OF
(1-AMINO-1-METHYL-ETHYL)  PHOSPHONIC ACID WITH SOME d-METALS  
AND URANYL ION

a 2014

PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION

DOROSHENKO, Iaroslav, Michal BABIAK and Jiří PINKAS

Basic information

Original name

PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION

Authors

DOROSHENKO, Iaroslav (804 Ukraine, belonging to the institution), Michal BABIAK (703 Slovakia, belonging to the institution) and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

66. sjezd chemických společností. Ostrava. Česka republika. 2014

Other information

Language

English

Type of outcome

Konferenční abstrakt

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.272

RIV identification code

RIV/00216224:14740/14:00073851

Organization unit

Central European Institute of Technology

ISSN

Keywords (in Czech)

Koordinacni clouceniny; fosfonaty; fosfonova kyselina;

Keywords in English

Coordination compounds; Phosphonates; phosphonic acid;

Změněno: 1/12/2014 01:21, prof. RNDr. Jiří Pinkas, Ph.D.

Abstract

V originále

Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

GAP207/11/0555, research and development project

Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation

Citovat

DOROSHENKO, Iaroslav, Michal BABIAK and Jiří PINKAS. PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION. In 66. sjezd chemických společností. Ostrava. Česka republika. 2014. ISSN 0009-2770.

@proceedings{1197347,
   author = {Doroshenko, Iaroslav and Babiak, Michal and Pinkas, Jiří},
   booktitle = {66. sjezd chemických společností. Ostrava. Česka republika.},
   keywords = {Coordination compounds; Phosphonates; phosphonic acid;},
   language = {eng},
   title = {PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION},
   year = {2014}
}

TY  - CONF
ID  - 1197347
AU  - Doroshenko, Iaroslav - Babiak, Michal - Pinkas, Jiří
PY  - 2014
TI  - PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION
KW  - Coordination compounds
KW  - Phosphonates
KW  - phosphonic acid;
N2  - Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+
ER  -

DOROSHENKO, Iaroslav, Michal BABIAK and Jiří PINKAS. PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION. In \textit{66. sjezd chemických společností. Ostrava. Česka republika.}. 2014. ISSN~0009-2770.

Detailed Information on Publication Record