PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION

DOROSHENKO, Iaroslav, Michal BABIAK and Jiří PINKAS. PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION. In 66. sjezd chemických společností. Ostrava. Česka republika. 2014. ISSN 0009-2770.

Basic information

• Original name: PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION
• Authors: DOROSHENKO, Iaroslav (804 Ukraine, belonging to the institution), Michal BABIAK (703 Slovakia, belonging to the institution) and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution).
• Edition: 66. sjezd chemických společností. Ostrava. Česka republika. 2014.

Other information

• Original language: English
• Type of outcome: Conference abstract
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: Czech Republic
• Confidentiality degree: is not subject to a state or trade secret
• Impact factor: Impact factor: 0.272
• RIV identification code: RIV/00216224:14740/14:00073851
• Organization unit: Central European Institute of Technology
• ISSN: 0009-2770
• Keywords (in Czech): Koordinacni clouceniny; fosfonaty; fosfonova kyselina
• Keywords in English: Coordination compounds; Phosphonates; phosphonic acid

Abstract

Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+

Links

• ED1.1.00/02.0068, research and development project: Name: CEITEC - central european institute of technology
• GAP207/11/0555, research and development project: Name: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Acronym: OPNW)

Investor: Czech Science Foundation