CIVIŠ, Svatopluk, Martin FERUS, Judit ŠPONEROVÁ, Jiří ŠPONER, Ladislav KAVAN and Markéta ZUKALOVÁ. Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface. Chemical Communications. Cambridge: Royal Society of Chemistry, 2014, vol. 50, No 57, p. 7712-7715. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c4cc01992j. |
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@article{1202581, author = {Civiš, Svatopluk and Ferus, Martin and Šponerová, Judit and Šponer, Jiří and Kavan, Ladislav and Zukalová, Markéta}, article_location = {Cambridge}, article_number = {57}, doi = {http://dx.doi.org/10.1039/c4cc01992j}, keywords = {TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR}, language = {eng}, issn = {1359-7345}, journal = {Chemical Communications}, title = {Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface}, url = {http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract}, volume = {50}, year = {2014} }
TY - JOUR ID - 1202581 AU - Civiš, Svatopluk - Ferus, Martin - Šponerová, Judit - Šponer, Jiří - Kavan, Ladislav - Zukalová, Markéta PY - 2014 TI - Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface JF - Chemical Communications VL - 50 IS - 57 SP - 7712-7715 EP - 7712-7715 PB - Royal Society of Chemistry SN - 13597345 KW - TITANIUM-DIOXIDE KW - OXYGEN-EXCHANGE KW - CARBON-MONOXIDE KW - HYDROCARBONS KW - CHEMISTRY KW - TIO2(101) KW - OXIDATION KW - ISOTOPE KW - METAL KW - FTIR UR - http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract L2 - http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract N2 - High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules. ER -
CIVIŠ, Svatopluk, Martin FERUS, Judit ŠPONEROVÁ, Jiří ŠPONER, Ladislav KAVAN and Markéta ZUKALOVÁ. Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface. \textit{Chemical Communications}. Cambridge: Royal Society of Chemistry, 2014, vol.~50, No~57, p.~7712-7715. ISSN~1359-7345. Available from: https://dx.doi.org/10.1039/c4cc01992j.
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