Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new
member of the lindackerite supergroup from Jachymov, Czech
Republic

J 2014

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN et. al.

Basic information

Original name

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic

Authors

PLÁŠIL, Jakub (203 Czech Republic, guarantor), Jiří SEJKORA (203 Czech Republic), Radek ŠKODA (203 Czech Republic, belonging to the institution), Milan NOVÁK (203 Czech Republic, belonging to the institution), Anatoly V KASATKIN (643 Russian Federation), Pavel ŠKACHA (203 Czech Republic), František VESELOVSKY (203 Czech Republic), Kristýna FEJFAROVÁ (203 Czech Republic) and Petr ONDRUŠ (203 Czech Republic)

Edition

Mineralogical Magazine, London, Mineralogical Society, 2014, 0026-461X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10500 1.5. Earth and related environmental sciences

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.026

RIV identification code

RIV/00216224:14310/14:00079323

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1180/minmag.2014.078.5.16

UT WoS

000348531400016

Keywords in English

hloušekite; new mineral; arsenate; lindackerite supergroup; lindackerite group; ondrusite group; crystal structure

Abstract

V originále

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), is a new supergene arsenate mineral from the Geister vein (Rovnost mine), Jachymov (St Joachimsthal), Western Bohemia, Czech Republic. It was found along with veselovskyite, pradetite, lavendulan, arsenolite, babanekite and gypsum on the surface of strongly altered ore fragments containing dominant tennantite and chalcopyrite. Hlous. ekite forms thin, lath-like crystals, locally elongated reaching up to 3 mm across. It is transparent, has a pale green colour with vitreous lustre, has a greyish-white streak and it is very brittle with an uneven fracture. It does not fluoresce under shortwave or longwave ultraviolet radiation. Cleavage on {010} is perfect; the Mohs hardness is 2-3. The calculated density is 3.295 g cm(-3). Hlous. ekite is optically biaxial with alpha' = 1.653(2) and gamma' = 1.73. The estimated optical orientation is gamma' vs. elongation (c) = 14(1)degrees. In larger grains it is weakly to moderately pleochroic (alpha = colourless, gamma = pale green to green). Hlousekite is triclinic, space group P (1) over bar, a = 6.4010(6), b = 8.0041(6), c = 10.3969(14) angstrom, alpha = 85.824(8), beta = 79.873(9), gamma = 84.655(7)degrees and V = 521.23(10) angstrom(3), with Z = 1, a:b:c = 0.800: 1: 1.299. The eight strongest lines in the powder X-ray diffraction (XRD) pattern [ d in angstrom (I)(hkl)] are 10.211(100)(001), 7.974(9)(010), 3.984(6)(020), 3.656(5)(1 (1) over bar2), 3.631(5)(0 (2) over bar1), 3.241(5)(022), 3.145(5)(200) and 3.006(5)(210). Chemical analysis by electron microprobe yielded MgO 0.20, FeO 0.10, NiO 5.79, CoO 1.80, CuO 29.53, ZnO 0.66, Al2O3 0.14, P2O5 0.11, As2O5 45.01, H2O 17.71 (calc.), for a total of 101.05 wt.%. The resulting empirical formula, calculated by stoichiometry (9H(2)O + 2OH), obtained from the crystal structure, is (Ni0.79Co0.25)(Sigma 1.04)(Cu3.78Zn0.08Mg0.05Al0.03Fe0.01)(Sigma 3.95) (AsO4)(1. 98)(PO4)(0.02)(AsO3OH)(2.00)(H2O)(9.00). The ideal endmember formula, NiCu4(AsO4)(2)(AsO3OH)(2)(H2O)(9.00), requires NiO 7.23, CuO 30.81, As2O5 44.51, H2O 17.45, total 100.00 wt.%. The crystal structure of hlous. ekite was solved by charge flipping from single-crystal XRD data and refined to R-1 = 0.0599 for 1441 reflections with [I-obs > 3 sigma(I)]. Hlousekite is a new member of the lindackerite group (also including lindackerite, pradetite and veselovskyite) of the lindackerite supergroup. The ondrusite group of the lindackerite supergroup includes ondrus. ite, chudobaite, geigerite and klajite. The establishment of these two groups reflects the difference between the crystal structures of their members, mainly in the coordination environment of the Me cations.

Citovat

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN, Pavel ŠKACHA, František VESELOVSKY, Kristýna FEJFAROVÁ and Petr ONDRUŠ. Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic. Mineralogical Magazine. London: Mineralogical Society, 2014, vol. 78, No 5, p. 1341-1353. ISSN 0026-461X. Available from: https://dx.doi.org/10.1180/minmag.2014.078.5.16.

@article{1228834,
   author = {Plášil, Jakub and Sejkora, Jiří and Škoda, Radek and Novák, Milan and Kasatkin, Anatoly V and Škacha, Pavel and Veselovsky, František and Fejfarová, Kristýna and Ondruš, Petr},
   article_location = {London},
   article_number = {5},
   doi = {http://dx.doi.org/10.1180/minmag.2014.078.5.16},
   keywords = {hloušekite; new mineral; arsenate; lindackerite supergroup; lindackerite group; ondrusite group; crystal structure},
   language = {eng},
   issn = {0026-461X},
   journal = {Mineralogical Magazine},
   title = {Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic},
   volume = {78},
   year = {2014}
}

TY  - JOUR
ID  - 1228834
AU  - Plášil, Jakub - Sejkora, Jiří - Škoda, Radek - Novák, Milan - Kasatkin, Anatoly V - Škacha, Pavel - Veselovsky, František - Fejfarová, Kristýna - Ondruš, Petr
PY  - 2014
TI  - Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic
JF  - Mineralogical Magazine
VL  - 78
IS  - 5
SP  - 1341-1353
EP  - 1341-1353
PB  - Mineralogical Society
SN  - 0026461X
KW  - hloušekite
KW  - new mineral
KW  - arsenate
KW  - lindackerite supergroup
KW  - lindackerite group
KW  - ondrusite group
KW  - crystal structure
N2  - Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), is a new supergene arsenate mineral from the Geister vein (Rovnost mine), Jachymov (St Joachimsthal), Western Bohemia, Czech Republic. It was found along with veselovskyite, pradetite, lavendulan, arsenolite, babanekite and gypsum on the surface of strongly altered ore fragments containing dominant tennantite and chalcopyrite. Hlous. ekite forms thin, lath-like crystals, locally elongated reaching up to 3 mm across. It is transparent, has a pale green colour with vitreous lustre, has a greyish-white streak and it is very brittle with an uneven fracture. It does not fluoresce under shortwave or longwave ultraviolet radiation. Cleavage on {010} is perfect; the Mohs hardness is 2-3. The calculated density is 3.295 g cm(-3). Hlous. ekite is optically biaxial with alpha' = 1.653(2) and gamma' = 1.73. The estimated optical orientation is gamma' vs. elongation (c) = 14(1)degrees. In larger grains it is weakly to moderately pleochroic (alpha = colourless, gamma = pale green to green). Hlousekite is triclinic, space group P (1) over bar, a = 6.4010(6), b = 8.0041(6), c = 10.3969(14) angstrom, alpha = 85.824(8), beta = 79.873(9), gamma = 84.655(7)degrees and V = 521.23(10) angstrom(3), with Z = 1, a:b:c = 0.800: 1: 1.299. The eight strongest lines in the powder X-ray diffraction (XRD) pattern [ d in angstrom (I)(hkl)] are 10.211(100)(001), 7.974(9)(010), 3.984(6)(020), 3.656(5)(1 (1) over bar2), 3.631(5)(0 (2) over bar1), 3.241(5)(022), 3.145(5)(200) and 3.006(5)(210). Chemical analysis by electron microprobe yielded MgO 0.20, FeO 0.10, NiO 5.79, CoO 1.80, CuO 29.53, ZnO 0.66, Al2O3 0.14, P2O5 0.11, As2O5 45.01, H2O 17.71 (calc.), for a total of 101.05 wt.%. The resulting empirical formula, calculated by stoichiometry (9H(2)O + 2OH), obtained from the crystal structure, is (Ni0.79Co0.25)(Sigma 1.04)(Cu3.78Zn0.08Mg0.05Al0.03Fe0.01)(Sigma 3.95) (AsO4)(1. 98)(PO4)(0.02)(AsO3OH)(2.00)(H2O)(9.00). The ideal endmember formula, NiCu4(AsO4)(2)(AsO3OH)(2)(H2O)(9.00), requires NiO 7.23, CuO 30.81, As2O5 44.51, H2O 17.45, total 100.00 wt.%. The crystal structure of hlous. ekite was solved by charge flipping from single-crystal XRD data and refined to R-1 = 0.0599 for 1441 reflections with [I-obs > 3 sigma(I)]. Hlousekite is a new member of the lindackerite group (also including lindackerite, pradetite and veselovskyite) of the lindackerite supergroup. The ondrusite group of the lindackerite supergroup includes ondrus. ite, chudobaite, geigerite and klajite. The establishment of these two groups reflects the difference between the crystal structures of their members, mainly in the coordination environment of the Me cations.
ER  -

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN, Pavel ŠKACHA, František VESELOVSKY, Kristýna FEJFAROVÁ and Petr ONDRUŠ. Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic. \textit{Mineralogical Magazine}. London: Mineralogical Society, 2014, vol.~78, No~5, p.~1341-1353. ISSN~0026-461X. Available from: https://dx.doi.org/10.1180/minmag.2014.078.5.16.

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