Alpine oxidation of lithium micas in Permian S-type granites
(Gemeric unit, Western Carpathians, Slovakia)

J 2014

Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia)

PETŘÍK, I., M. ČÍK, M. MIGLIERINI, Tomáš VACULOVIČ, I. DIANIŠKA et. al.

Basic information

Original name

Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia)

Authors

PETŘÍK, I. (703 Slovakia, guarantor), M. ČÍK (703 Slovakia), M. MIGLIERINI (703 Slovakia), Tomáš VACULOVIČ (703 Slovakia, belonging to the institution), I. DIANIŠKA (703 Slovakia) and D. OZDÍN (703 Slovakia)

Edition

Mineralogical Magazine, Middlesex, Mineralogical Society, 2014, 0026-461X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 2.026

RIV identification code

RIV/00216224:14740/14:00079354

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1180/minmag.2014.078.3.03

UT WoS

000344420400003

Keywords in English

lithium micas; zinnwaldite; phengite; Permian granite; oxidation; Alpine metamorphism; Gemeric unit; Western Carpathians; Slovakia

Abstract

V originále

Lithium micas of the zinnwaldite and phengite-Li-phengite series occur as characteristic minerals in Permian Li-F-(P) granites of the western Gemeric unit (Western Carpathians) accompanied by topaz, tourmaline, Nb, Ta, Ti, Sn oxides and aluminophosphates. The calculated Li2O contents of all the mica analysed, together with Rb2O and Cs2O were confirmed by LA-ICP-MS analyses for all the identified micas. Samples from three localities were investigated: two surficial (Surovec, Vrchsul'ova); and one drill hole (Dlha dolina). Zinnwaldite (polylithionite) occurs in the upper level of the Dlha dolina granitic intrusion and in the nearby shallow satellite body of Surovec. The lower level porphyritic granites contain only siderophyllite. The Vrchsul'ova micas are closer in composition to Li-annite and siderophyllite. Dioctahedral micas are mostly phengites, although zinnwaldite-bearing granites are rich in late-crystallizing Li-phengite, which extensively replaces earlier zinnwaldite. The secondary Li-phengite and phengite are interpreted as products of Alpine metamorphism during Cretaceous burial and subsequent exhumation of the Gemeric unit. Reactions are suggested explaining the formation of Li-phengite by reaction of zinnwaldite with phengite or with muscovite. All mica types were investigated by Mossbauer spectroscopy, which showed high degrees of oxidation (25-50% Fe3+ of total Fe) with the exception of zinnwaldite from Vrchsul'ova, which may have preserved an original, reduced value of 10%. The metamorphic assemblage present permitted calculation of P-T-X conditions: T = 184 degrees C, P = 320 MPa, with oxidation of siderophyllite to phengite + goethite and f(O2) at Delta NN = 4.7, confirming the low-grade conditions of the Alpine metamorphism in agreement with previous estimates.

Citovat

PETŘÍK, I., M. ČÍK, M. MIGLIERINI, Tomáš VACULOVIČ, I. DIANIŠKA and D. OZDÍN. Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia). Mineralogical Magazine. Middlesex: Mineralogical Society, 2014, vol. 78, No 3, p. 507-533. ISSN 0026-461X. Available from: https://dx.doi.org/10.1180/minmag.2014.078.3.03.

@article{1228990,
   author = {Petřík, I. and Čík, M. and Miglierini, M. and Vaculovič, Tomáš and Dianiška, I. and Ozdín, D.},
   article_location = {Middlesex},
   article_number = {3},
   doi = {http://dx.doi.org/10.1180/minmag.2014.078.3.03},
   keywords = {lithium micas; zinnwaldite; phengite; Permian granite; oxidation; Alpine metamorphism; Gemeric unit; Western Carpathians; Slovakia},
   language = {eng},
   issn = {0026-461X},
   journal = {Mineralogical Magazine},
   title = {Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia)},
   url = {http://minmag.geoscienceworld.org/content/78/3/507.abstract},
   volume = {78},
   year = {2014}
}

TY  - JOUR
ID  - 1228990
AU  - Petřík, I. - Čík, M. - Miglierini, M. - Vaculovič, Tomáš - Dianiška, I. - Ozdín, D.
PY  - 2014
TI  - Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia)
JF  - Mineralogical Magazine
VL  - 78
IS  - 3
SP  - 507-533
EP  - 507-533
PB  - Mineralogical Society
SN  - 0026461X
KW  - lithium micas
KW  - zinnwaldite
KW  - phengite
KW  - Permian granite
KW  - oxidation
KW  - Alpine metamorphism
KW  - Gemeric unit
KW  - Western Carpathians
KW  - Slovakia
UR  - http://minmag.geoscienceworld.org/content/78/3/507.abstract
L2  - http://minmag.geoscienceworld.org/content/78/3/507.abstract
N2  - Lithium micas of the zinnwaldite and phengite-Li-phengite series occur as characteristic minerals in Permian Li-F-(P) granites of the western Gemeric unit (Western Carpathians) accompanied by topaz, tourmaline, Nb, Ta, Ti, Sn oxides and aluminophosphates. The calculated Li2O contents of all the mica analysed, together with Rb2O and Cs2O were confirmed by LA-ICP-MS analyses for all the identified micas. Samples from three localities were investigated: two surficial (Surovec, Vrchsul'ova); and one drill hole (Dlha dolina). Zinnwaldite (polylithionite) occurs in the upper level of the Dlha dolina granitic intrusion and in the nearby shallow satellite body of Surovec. The lower level porphyritic granites contain only siderophyllite. The Vrchsul'ova micas are closer in composition to Li-annite and siderophyllite. Dioctahedral micas are mostly phengites, although zinnwaldite-bearing granites are rich in late-crystallizing Li-phengite, which extensively replaces earlier zinnwaldite. The secondary Li-phengite and phengite are interpreted as products of Alpine metamorphism during Cretaceous burial and subsequent exhumation of the Gemeric unit. Reactions are suggested explaining the formation of Li-phengite by reaction of zinnwaldite with phengite or with muscovite. All mica types were investigated by Mossbauer spectroscopy, which showed high degrees of oxidation (25-50% Fe3+ of total Fe) with the exception of zinnwaldite from Vrchsul'ova, which may have preserved an original, reduced value of 10%. The metamorphic assemblage present permitted calculation of P-T-X conditions: T = 184 degrees C, P = 320 MPa, with oxidation of siderophyllite to phengite + goethite and f(O2) at Delta NN = 4.7, confirming the low-grade conditions of the Alpine metamorphism in agreement with previous estimates.
ER  -

PETŘÍK, I., M. ČÍK, M. MIGLIERINI, Tomáš VACULOVIČ, I. DIANIŠKA and D. OZDÍN. Alpine oxidation of lithium micas in Permian S-type granites (Gemeric unit, Western Carpathians, Slovakia). \textit{Mineralogical Magazine}. Middlesex: Mineralogical Society, 2014, vol.~78, No~3, p.~507-533. ISSN~0026-461X. Available from: https://dx.doi.org/10.1180/minmag.2014.078.3.03.

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