J 2014

Does an analysis of polychlorinated biphenyl (PCB) distribution in mountain soils across China reveal a latitudinal fractionation paradox?

ZHENG, Qian, Luca NIZZETTO, Marie Daniëlle MULDER, Ondřej SÁŇKA, Gerhard LAMMEL et. al.

Basic information

Original name

Does an analysis of polychlorinated biphenyl (PCB) distribution in mountain soils across China reveal a latitudinal fractionation paradox?

Authors

ZHENG, Qian (156 China), Luca NIZZETTO (380 Italy, guarantor, belonging to the institution), Marie Daniëlle MULDER (528 Netherlands, belonging to the institution), Ondřej SÁŇKA (203 Czech Republic, belonging to the institution), Gerhard LAMMEL (276 Germany, belonging to the institution), Jun LI (156 China), Haijian BING (156 China), Xin LIU (156 China), Yishan JIANG (156 China), Chunlin LUO (156 China) and Gan ZHANG (156 China)

Edition

Environmental Pollution, OXFORD, OXON, ENGLAND, ELSEVIER SCI LTD, 2014, 0269-7491

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10511 Environmental sciences

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 4.143

RIV identification code

RIV/00216224:14310/14:00079391

Organization unit

Faculty of Science

UT WoS

000344437600015

Keywords in English

POP; PCB; Fractionation; Cold trapping; Mountain; Soil; Latitude; Forest

Tags

Tags

International impact, Reviewed
Změněno: 5/3/2015 12:43, Ing. Filip Vaculovič

Abstract

V originále

Organic and mineral soil horizons from forests in 30 mountains across China were analysed for polychlorinated biphenyl (PCB). Soil total organic carbon (TOC) content was a key determinant of PCB distribution explaining over 90% of the differences between organic and mineral soils, and between 30% and 60% of the variance along altitudinal and regional transects. The residual variance (after normalization by TOC) was small. Tri- to tetra-CB levels were higher in the South in relation to high source density and precipitation. Heavier congeners were instead more abundant at mid/high-latitudes where the advection pattern was mainly from long range transport. This resulted in a latitudinal fractionation opposite to theoretical expectations. The study showed that exposure to sources with different characteristics, and possibly accumulation/degradation trends of different congeners in soils being out-of-phase at different latitudes, can lead to an unsteady large scale distribution scenario conflicting with the thermodynamic equilibrium perception. (C) 2014 Elsevier Ltd. All rights reserved.

Links

LM2011028, research and development project
Name: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí
Investor: Ministry of Education, Youth and Sports of the CR