Other formats:
BibTeX
LaTeX
RIS
@article{1232059, author = {Yawer, Mirza Arfan and Havel, Václav and Šindelář, Vladimír}, article_location = {WEINHEIM (GERMANY)}, article_number = {1}, doi = {http://dx.doi.org/10.1002/anie.201409895}, keywords = {anion recognition; host–guest systems; macrocycles; self-assembly; supramolecular chemistry}, language = {eng}, issn = {1433-7851}, journal = {Angewandte Chemie International Edition}, title = {A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity}, url = {http://onlinelibrary.wiley.com/doi/10.1002/anie.201409895/abstract;jsessionid=ABCDEB2B3122226D3B80E184E66BCDB5.f02t03}, volume = {54}, year = {2015} }
TY - JOUR ID - 1232059 AU - Yawer, Mirza Arfan - Havel, Václav - Šindelář, Vladimír PY - 2015 TI - A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity JF - Angewandte Chemie International Edition VL - 54 IS - 1 SP - 276-279 EP - 276-279 PB - Verlag Chemie SN - 14337851 KW - anion recognition KW - host–guest systems KW - macrocycles KW - self-assembly KW - supramolecular chemistry UR - http://onlinelibrary.wiley.com/doi/10.1002/anie.201409895/abstract;jsessionid=ABCDEB2B3122226D3B80E184E66BCDB5.f02t03 L2 - http://onlinelibrary.wiley.com/doi/10.1002/anie.201409895/abstract;jsessionid=ABCDEB2B3122226D3B80E184E66BCDB5.f02t03 N2 - Synthetic receptors that function in water are important for the qualitative and quantitative detection of anions, which may act as pollutants in the environment or play important roles in biological processes. Neutral receptors are particularly appealing because they are often more selective than positively charged receptors; however, their affinity towards anions in pure water is only in range of 1-10(3)Lmol(-1). The anion-templated synthesis of a water-soluble bambusuril derivative is shown to be an outstanding receptor for various inorganic anions in pure water, with association constants of up to 10(7)Lmol(-1). Furthermore, the macrocycle discriminates between anions with unprecedented selectivity (up to 500000-fold). We anticipate that the combination of remarkable affinity and selectivity of this macrocycle will enable the efficient detection and isolation of diverse anions in aqueous solutions, which is not possible with current supramolecular systems. ER -
YAWER, Mirza Arfan, Václav HAVEL and Vladimír ŠINDELÁŘ. A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity. \textit{Angewandte Chemie International Edition}. WEINHEIM (GERMANY): Verlag Chemie, 2015, vol.~54, No~1, p.~276-279. ISSN~1433-7851. Available from: https://dx.doi.org/10.1002/anie.201409895.
|