ZEBRET, Soumalia, Eliane VÖGELE, Tomáš KLUMPLER and Josef HAMÁČEK. Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium. Chemistry - A European Journal. Weinheim: WILEY-VCH Verlag, 2015, vol. 21, No 18, p. 6695-6699. ISSN 0947-6539. Available from: https://dx.doi.org/10.1002/chem.201500006. |
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@article{1297163, author = {Zebret, Soumalia and Vögele, Eliane and Klumpler, Tomáš and Hamáček, Josef}, article_location = {Weinheim}, article_number = {18}, doi = {http://dx.doi.org/10.1002/chem.201500006}, keywords = {europium; helicates; octanuclear; self-assembly; supramolecular chemistry}, language = {eng}, issn = {0947-6539}, journal = {Chemistry - A European Journal}, title = {Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium}, url = {http://onlinelibrary.wiley.com/doi/10.1002/chem.201500006/epdf}, volume = {21}, year = {2015} }
TY - JOUR ID - 1297163 AU - Zebret, Soumalia - Vögele, Eliane - Klumpler, Tomáš - Hamáček, Josef PY - 2015 TI - Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium JF - Chemistry - A European Journal VL - 21 IS - 18 SP - 6695-6699 EP - 6695-6699 PB - WILEY-VCH Verlag SN - 09476539 KW - europium KW - helicates KW - octanuclear KW - self-assembly KW - supramolecular chemistry UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201500006/epdf L2 - http://onlinelibrary.wiley.com/doi/10.1002/chem.201500006/epdf N2 - Herein, we report on the rational design, preparation and characterization of a novel homo-octanuclear helicate, which results from a spatial extension of the central tetranuclear platform. The 3D supramolecular assembly is obtained by complexing europium(III) with a new hexatopic tripodal ligand. The isolated octanuclear helicate is fully characterized by different methods clearly evidencing the structure predicted with molecular modelling. The ligand preorganization plays a crucial role in a successful self-assembly process and induces the formation of a well-defined triple-stranded helical structure. This prototypal octanuclear edifice accommodating functional lanthanides within a 3D scaffold offers attractive perspectives for further applications. ER -
ZEBRET, Soumalia, Eliane VÖGELE, Tomáš KLUMPLER and Josef HAMÁČEK. Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium. \textit{Chemistry - A European Journal}. Weinheim: WILEY-VCH Verlag, 2015, vol.~21, No~18, p.~6695-6699. ISSN~0947-6539. Available from: https://dx.doi.org/10.1002/chem.201500006.
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