Real-time analysis of multiple anion mixtures in aqueous media
using a single receptor

J 2015

Real-time analysis of multiple anion mixtures in aqueous media using a single receptor

HAVEL, Václav, Mirza Arfan YAWER and Vladimír ŠINDELÁŘ

Basic information

Original name

Real-time analysis of multiple anion mixtures in aqueous media using a single receptor

Authors

HAVEL, Václav (203 Czech Republic, belonging to the institution), Mirza Arfan YAWER (586 Pakistan, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution)

Edition

J. Chem. Soc. Chem. Commun. CAMBRIDGE (ENGLAND), Royal Society of Chemistry, 2015, 1359-7345

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 6.567

RIV identification code

RIV/00216224:14310/15:00080750

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1039/c4cc10108a

UT WoS

000350486300029

Keywords in English

SUPRAMOLECULAR CHEMISTRY; WATER; RECOGNITION; BINDING;

Abstract

V originále

Bambusuril-based receptors have been used in conjunction with H-1 NMR spectroscopy to recognize mixtures of inorganic anions in aqueous solutions. This was achieved by examining complexationinduced changes in the receptors' H-1 NMR fingerprints. This approach enables the simultaneous identification of up to 9 anions and the quantification of up to 5 anions using a single receptor in DMSO-d(6) containing 5% D2O. Toxic perchlorate was recognized and quantified at 0.1 mu M (1.8 ppb, mol mol(-1)) concentration in pure water.

Links

GA13-15576S, research and development project

Name: Syntéza a supramolekulární vlastnosti bambusurilů

Investor: Czech Science Foundation

LM2011028, research and development project

Name: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministry of Education, Youth and Sports of the CR

LO1214, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

HAVEL, Václav, Mirza Arfan YAWER and Vladimír ŠINDELÁŘ. Real-time analysis of multiple anion mixtures in aqueous media using a single receptor. J. Chem. Soc. Chem. Commun. CAMBRIDGE (ENGLAND): Royal Society of Chemistry, 2015, vol. 51, No 22, p. 4666-4669. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c4cc10108a.

@article{1297757,
   author = {Havel, Václav and Yawer, Mirza Arfan and Šindelář, Vladimír},
   article_location = {CAMBRIDGE (ENGLAND)},
   article_number = {22},
   doi = {http://dx.doi.org/10.1039/c4cc10108a},
   keywords = {SUPRAMOLECULAR CHEMISTRY; WATER; RECOGNITION; BINDING;},
   language = {eng},
   issn = {1359-7345},
   journal = {J. Chem. Soc. Chem. Commun.},
   title = {Real-time analysis of multiple anion mixtures in aqueous media using a single receptor},
   url = {http://pubs.rsc.org/en/content/articlepdf/2015/cc/c4cc10108a},
   volume = {51},
   year = {2015}
}

TY  - JOUR
ID  - 1297757
AU  - Havel, Václav - Yawer, Mirza Arfan - Šindelář, Vladimír
PY  - 2015
TI  - Real-time analysis of multiple anion mixtures in aqueous media using a single receptor
JF  - J. Chem. Soc. Chem. Commun.
VL  - 51
IS  - 22
SP  - 4666-4669
EP  - 4666-4669
PB  - Royal Society of Chemistry
SN  - 13597345
KW  - SUPRAMOLECULAR CHEMISTRY
KW  - WATER
KW  - RECOGNITION
KW  - BINDING;
UR  - http://pubs.rsc.org/en/content/articlepdf/2015/cc/c4cc10108a
L2  - http://pubs.rsc.org/en/content/articlepdf/2015/cc/c4cc10108a
N2  - Bambusuril-based receptors have been used in conjunction with H-1 NMR spectroscopy to recognize mixtures of inorganic anions in aqueous solutions. This was achieved by examining complexationinduced changes in the receptors' H-1 NMR fingerprints. This approach enables the simultaneous identification of up to 9 anions and the quantification of up to 5 anions using a single receptor in DMSO-d(6) containing 5% D2O. Toxic perchlorate was recognized and quantified at 0.1 mu M (1.8 ppb, mol mol(-1)) concentration in pure water.
ER  -

HAVEL, Václav, Mirza Arfan YAWER and Vladimír ŠINDELÁŘ. Real-time analysis of multiple anion mixtures in aqueous media using a single receptor. \textit{J. Chem. Soc. Chem. Commun.}. CAMBRIDGE (ENGLAND): Royal Society of Chemistry, 2015, vol.~51, No~22, p.~4666-4669. ISSN~1359-7345. Available from: https://dx.doi.org/10.1039/c4cc10108a.

Detailed Information on Publication Record