Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity

PODHORSKÝ, Ján, Zdeněk MORAVEC, Jiří PINKAS, Corinna HEGEMANN, Lisa CZYMPIEL and Sanjay MATHUR. Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity. In Third EuCheMS Inorganic Chemistry Conference. 2015. ISBN 978-83-60043-26-4.

Basic information

• Original name: Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity
• Name in Czech: Syntézy heteroleptických N,O-B-Heteroarylaketonátových komplexů cínu, jejich vlastnosti a reaktivita
• Authors: PODHORSKÝ, Ján (703 Slovakia), Zdeněk MORAVEC (203 Czech Republic, belonging to the institution), Jiří PINKAS (203 Czech Republic), Corinna HEGEMANN (276 Germany), Lisa CZYMPIEL (276 Germany) and Sanjay MATHUR (276 Germany).
• Edition: Third EuCheMS Inorganic Chemistry Conference, 2015.

Other information

• Original language: English
• Type of outcome: Conference abstract
• Field of Study: 10402 Inorganic and nuclear chemistry
• Confidentiality degree: is not subject to a state or trade secret
• RIV identification code: RIV/00216224:14310/15:00083294
• Organization unit: Faculty of Science
• ISBN: 978-83-60043-26-4
• Keywords in English: Fluorinations; Tin Tin N O-B-Heteroarylaketonate Complexes; CVD precursors
• Tags: International impact

Abstract

In our work, we synthetized two novel heteroleptic alkoxidic compounds, containing tin (IV) coordinated with N,O–B–heteroarylalkenolato ligands, Sn(4,5–Me–OxCHCOCF3)2(OtBu)2 and Sn(2–PyCHCOCF3)2(OtBu)2: Those compounds were fully structurally characterized and their properties and reactivity towards water and fluorination agents were investigated. Obtained results were compared with homoleptic tin (II) N,O–B–heteroarylalkenolato complexes already published in literature, Sn(4,5–Me–OxCHCOCF3)2 and Sn(2–PyCHCOCF3)2.

Links

• ED1.1.00/02.0068, research and development project: Name: CEITEC - central european institute of technology