DAVID, Bohumil, Oldřich SCHNEEWEISS, Naděžda PIZÚROVÁ, Antonín REK, Vít KUDRLE and Ondřej JAŠEK. NANOSTRUCTURED ALPHA-FE LAYERS SYNTHESIZED IN LOW-PRESSURE MICROWAVE PLASMA. In Nanocon 2012. 2012. ISBN 978-80-87294-35-2.
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Basic information
Original name NANOSTRUCTURED ALPHA-FE LAYERS SYNTHESIZED IN LOW-PRESSURE MICROWAVE PLASMA
Authors DAVID, Bohumil, Oldřich SCHNEEWEISS, Naděžda PIZÚROVÁ, Antonín REK, Vít KUDRLE and Ondřej JAŠEK.
Edition Nanocon 2012, 2012.
Other information
Original language English
Type of outcome Conference abstract
Field of Study 10305 Fluids and plasma physics
Country of publisher Czech Republic
Confidentiality degree is not subject to a state or trade secret
Organization unit Faculty of Science
ISBN 978-80-87294-35-2
Keywords in English nanomaterial; plasma synthesis; iron layer
Changed by Changed by: prof. Mgr. Vít Kudrle, Ph.D., učo 2560. Changed: 11/7/2015 15:07.
Abstract
We have used microwave plasma at the low pressure of 2 kPa to synthesize nanostructured alpha-Fe layer. This layer was deposited on a glass substrate which was immersed in Ar plasma (microwave power of 250 W). Iron pentacarbonyl Fe(CO)5 was flown over the substrate and its decomposition resulted in the formation of a few micrometers thick fully nanostructured iron layer. The deposition time was 60 seconds. The synthesized samples were studied using XRD, SEM, EDAX and 57Fe Mossbauer spectrometry. Only alpha-Fe phase with the mean crystallite size of 14 nm was observed in the XRD pattern of the representative sample. It was observed in SEM that the fine structure of the layer exhibited a kind of columnar structure whereby the columns were formed of nanocrystals. No voids were observed and oxygen, due to its low concentration, was hardly detectable with EDAX. In the transmission Mossbauer spectrum, as well as in the conversion-electron Mossbauer spectrum, collected on the pieces of the layer, alpha-Fe sextet dominated and a surprisingly low amount of iron oxides was identified (respective spectrum area was about 1 %). It means that the pieces of alpha-Fe layer were very weakly oxidized.
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