Trigonal to tetrahedral transitions in Cu(I) six-membered inorganic true heterocycles

HORNÍ, Michal, Radim BINAR and Marek NEČAS. Trigonal to tetrahedral transitions in Cu(I) six-membered inorganic true heterocycles. In The 14th International Symposium on Inorganic Ring Systems. 2015.

Basic information

Original name

Trigonal to tetrahedral transitions in Cu(I) six-membered inorganic true heterocycles

Authors

HORNÍ, Michal, Radim BINAR and Marek NEČAS

Edition

The 14th International Symposium on Inorganic Ring Systems, 2015

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Other information

Language

English

Type of outcome

Konferenční abstrakt

Field of Study

10402 Inorganic and nuclear chemistry

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Organization unit

Faculty of Science

Keywords in English

Cu(I) coordination; PNC ligands; true heterocycles

Tags

International impact

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Abstract

V originále

In order to follow the influence of ligand substituents on the Cu(I) coordination geometry, a series of six-membered Cu(I) true heterocycles was prepared from reactions of Cu(PPh3)2NO3 with R2P(S)-NH-C(O)R’ {R’ = (CH2)3CH3, C6H5, C6H4F, C6H4Cl; R = Ph, PhO} ligands. The complexes were characterized by 31P NMR spectroscopy and single crystal X-ray diffraction.