Detailed Information on Publication Record
2015
Synthesis and characterization of Cu/Ag alloy nanoparticles
VYKOUKAL, Vít, Jan VŘEŠŤÁL, Jiří BURŠÍK, Jiří SOPOUŠEK, Ondřej ZOBAČ et. al.Basic information
Original name
Synthesis and characterization of Cu/Ag alloy nanoparticles
Name in Czech
Příprava a charakterizace nanočástic slitiny Cu/Ag
Authors
Edition
ANM 2015, 2015
Other information
Language
English
Type of outcome
Konferenční abstrakt
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Portugal
Confidentiality degree
není předmětem státního či obchodního tajemství
References:
Organization unit
Central European Institute of Technology
Keywords (in Czech)
nanočástice; slitina; stříbro; měď; DLS; SAXS; TEM; deprese bodu tání
Keywords in English
nanoparticles; alloy; silver; copper; DLS; SAXS; TEM; depression of melting point
Tags
International impact
Změněno: 18/3/2016 17:55, prof. RNDr. Jiří Pinkas, Ph.D.
Abstract
V originále
Nanoparticles of Cu/Ag alloy were prepared by solvothermal synthesis from different metal precursors. A mixture of metal precursors was dissolved in small amount of oleylamine and injected into mixture of octadecene and oleylamine at 230 °C. Oleylamine acted as a reducing agent and protecting layer on the surface of arising nanoparticles. After 10 minutes reaction mixture was cooled, centrifuged and three times washed with hexane. Obtained nanoparticles were dispersed in hexane. The colloidal solutions of nanoparticles were characterized by dynamic light scattering (DLS), small angle X-ray scattering (SAXS), ultraviolet-visible spectroscopy (UV-VIS). Isolated nanopowders were characterized by transmission and scanning electron microscopy (TEM, SEM) and powder X-ray diffraction (PXRD). Alloy phase transformations were studied by differential scanning calorimetry (DSC). Surface of nanoparticles was characterized by infrared spectroscopy (IR) and mass spectrometry (MS) The results of thermal analysis were compared with the calculated phase diagram. Acknowledgement: Financial support of the COST LD 11046, CEITEC-MU CZ.1.05/1.1.00/02.0068, and GACR 108/14-12653S are gratefully acknowledged. Authors thank Dr. T. Klumpler (Single Crystal X-ray Diffraction Core Facility CEITEC) for the SAXS measurements.
Links
| ED1.1.00/02.0068, research and development project |
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| GA14-12653S, research and development project |
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| LD11046, research and development project |
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