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@article{1316105,
author = {Drusan, Michal and Rakovský, Erik and Marek, Jaromír and Šebesta, Radovan},
article_location = {WEINHEIM},
article_number = {7},
doi = {http://dx.doi.org/10.1002/adsc.201500074},
keywords = {asymmetric catalysis; carbocations; conjugate addition; domino reactions; ferrocene ligands},
language = {eng},
issn = {1615-4150},
journal = {ADVANCED SYNTHESIS & CATALYSIS},
title = {Asymmetric One-Pot Conjugate Addition of Grignard Reagents to alpha,beta-Unsaturated Compounds Followed by Reaction with Carbenium Ions},
url = {http://onlinelibrary.wiley.com/doi/10.1002/adsc.201500074/abstract;jsessionid=6039F4AD8F14C5AFBD11F8B684CAF703.f03t04},
volume = {357},
year = {2015}
}
TY - JOUR
ID - 1316105
AU - Drusan, Michal - Rakovský, Erik - Marek, Jaromír - Šebesta, Radovan
PY - 2015
TI - Asymmetric One-Pot Conjugate Addition of Grignard Reagents to alpha,beta-Unsaturated Compounds Followed by Reaction with Carbenium Ions
JF - ADVANCED SYNTHESIS & CATALYSIS
VL - 357
IS - 7
SP - 1493-1498
EP - 1493-1498
PB - WILEY-V C H VERLAG GMBH
SN - 16154150
KW - asymmetric catalysis
KW - carbocations
KW - conjugate addition
KW - domino reactions
KW - ferrocene ligands
UR - http://onlinelibrary.wiley.com/doi/10.1002/adsc.201500074/abstract;jsessionid=6039F4AD8F14C5AFBD11F8B684CAF703.f03t04
L2 - http://onlinelibrary.wiley.com/doi/10.1002/adsc.201500074/abstract;jsessionid=6039F4AD8F14C5AFBD11F8B684CAF703.f03t04
N2 - Asymmetric catalytic multistep reactions enable the formation of structurally complex compounds from simple starting materials. Enantioselective Cu-catalyzed 1,4-additions of Grignard reagents to Michael acceptors form reactive chiral enolates. We show here that these chiral enolates react in a one-pot fashion with naked carbenium ions, such as tropylium, 1,3-benzodithiolium, and dianisylmethylium ions. The corresponding products were obtained in good yields, with enantioselectivities up to 96% ee and high diastereomeric purities.
ER -
DRUSAN, Michal, Erik RAKOVSKÝ, Jaromír MAREK and Radovan ŠEBESTA. Asymmetric One-Pot Conjugate Addition of Grignard Reagents to alpha,beta-Unsaturated Compounds Followed by Reaction with Carbenium Ions. \textit{ADVANCED SYNTHESIS \&{} CATALYSIS}. WEINHEIM: WILEY-V C H VERLAG GMBH, 2015, vol.~357, No~7, p.~1493-1498. ISSN~1615-4150. Available from: https://dx.doi.org/10.1002/adsc.201500074.
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