| BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ and Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. Reactive and Functional Polymers. 2016, vol. 100, March, p. 53-63. ISSN 1381-5148. Available from: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013. |
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@article{1332555,
author = {Bačovská, Radka and WisianandNeilson, Patty and Alberti, Milan and Příhoda, Jiří and Zárybnická, Lucie and Voráč, Zbyněk},
article_number = {March},
doi = {http://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013},
keywords = {Polymeric nanofibers; Electrospinning technology; hydrophobicity; Ph-Me (t) additive; Ph-Me (p) polyphosphazene},
language = {eng},
issn = {1381-5148},
journal = {Reactive and Functional Polymers},
title = {Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles},
volume = {100},
year = {2016}
}
TY - JOUR
ID - 1332555
AU - Bačovská, Radka - Wisian-Neilson, Patty - Alberti, Milan - Příhoda, Jiří - Zárybnická, Lucie - Voráč, Zbyněk
PY - 2016
TI - Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles
JF - Reactive and Functional Polymers
VL - 100
IS - March
SP - 53-63
EP - 53-63
SN - 13815148
KW - Polymeric nanofibers
KW - Electrospinning technology
KW - hydrophobicity
KW - Ph-Me (t) additive
KW - Ph-Me (p) polyphosphazene
N2 - This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolayers that have significant hydrophobicity and thermal stability. The preparation of Ph-Me(p) is a multi-step reaction which produces a relatively low amount of the product. The second area of our interest was the creation of nanofibers formed from a mixture of some commercially available organic polymers and a cyclo-phosphazene derivative. In this case, tri(phenyl)-trimethyl-cyclo-triphosphazene, Ph-Me(t), whose synthesis is less complicated than its polymeric form, was used as an additive. The influence of the Ph-Me(t) additive in the nanofibers on the affinity to water was compared with the affinity of nanolayers made from a pure commercial polymer, i.e. without any phosphazene additive. It was also shown that the hydrophobic properties of fibers formed from Ph-Me(p) dissolved especially in THF are better than those of the nanofibers composed of a commercial polymer with the addition of Ph-Me(t).
ER -
BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ and Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. \textit{Reactive and Functional Polymers}. 2016, vol.~100, March, p.~53-63. ISSN~1381-5148. Available from: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013.
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