Phenyl-methyl phosphazene derivatives for preparation and
modification of hydrophobic properties of polymeric nonwoven
textiles

J 2016

Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ et. al.

Basic information

Original name

Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles

Authors

BAČOVSKÁ, Radka (203 Czech Republic, guarantor, belonging to the institution), Patty WISIAN-NEILSON (840 United States of America), Milan ALBERTI (203 Czech Republic, belonging to the institution), Jiří PŘÍHODA (203 Czech Republic, belonging to the institution), Lucie ZÁRYBNICKÁ (203 Czech Republic) and Zbyněk VORÁČ (840 United States of America, belonging to the institution)

Edition

Reactive and Functional Polymers, 2016, 1381-5148

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 3.151

RIV identification code

RIV/00216224:14310/16:00088827

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013

UT WoS

000371943600007

Keywords in English

Polymeric nanofibers; Electrospinning technology; hydrophobicity; Ph-Me (t) additive; Ph-Me (p) polyphosphazene

Abstract

V originále

This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolayers that have significant hydrophobicity and thermal stability. The preparation of Ph-Me(p) is a multi-step reaction which produces a relatively low amount of the product. The second area of our interest was the creation of nanofibers formed from a mixture of some commercially available organic polymers and a cyclo-phosphazene derivative. In this case, tri(phenyl)-trimethyl-cyclo-triphosphazene, Ph-Me(t), whose synthesis is less complicated than its polymeric form, was used as an additive. The influence of the Ph-Me(t) additive in the nanofibers on the affinity to water was compared with the affinity of nanolayers made from a pure commercial polymer, i.e. without any phosphazene additive. It was also shown that the hydrophobic properties of fibers formed from Ph-Me(p) dissolved especially in THF are better than those of the nanofibers composed of a commercial polymer with the addition of Ph-Me(t).

Links

FR-TI1/413, research and development project

Name: *Nové technické polymery pro síťovatelné kompozity 2

Investor: Ministry of Industry and Trade of the CR

Citovat

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ and Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. Reactive and Functional Polymers. 2016, vol. 100, March, p. 53-63. ISSN 1381-5148. Available from: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013.

@article{1332555,
   author = {Bačovská, Radka and WisianandNeilson, Patty and Alberti, Milan and Příhoda, Jiří and Zárybnická, Lucie and Voráč, Zbyněk},
   article_number = {March},
   doi = {http://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013},
   keywords = {Polymeric nanofibers; Electrospinning technology; hydrophobicity; Ph-Me (t) additive; Ph-Me (p) polyphosphazene},
   language = {eng},
   issn = {1381-5148},
   journal = {Reactive and Functional Polymers},
   title = {Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles},
   volume = {100},
   year = {2016}
}

TY  - JOUR
ID  - 1332555
AU  - Bačovská, Radka - Wisian-Neilson, Patty - Alberti, Milan - Příhoda, Jiří - Zárybnická, Lucie - Voráč, Zbyněk
PY  - 2016
TI  - Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles
JF  - Reactive and Functional Polymers
VL  - 100
IS  - March
SP  - 53-63
EP  - 53-63
SN  - 13815148
KW  - Polymeric nanofibers
KW  - Electrospinning technology
KW  - hydrophobicity
KW  - Ph-Me (t) additive
KW  - Ph-Me (p) polyphosphazene
N2  - This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolayers that have significant hydrophobicity and thermal stability. The preparation of Ph-Me(p) is a multi-step reaction which produces a relatively low amount of the product. The second area of our interest was the creation of nanofibers formed from a mixture of some commercially available organic polymers and a cyclo-phosphazene derivative. In this case, tri(phenyl)-trimethyl-cyclo-triphosphazene, Ph-Me(t), whose synthesis is less complicated than its polymeric form, was used as an additive. The influence of the Ph-Me(t) additive in the nanofibers on the affinity to water was compared with the affinity of nanolayers made from a pure commercial polymer, i.e. without any phosphazene additive. It was also shown that the hydrophobic properties of fibers formed from Ph-Me(p) dissolved especially in THF are better than those of the nanofibers composed of a commercial polymer with the addition of Ph-Me(t).
ER  -

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ and Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. \textit{Reactive and Functional Polymers}. 2016, vol.~100, March, p.~53-63. ISSN~1381-5148. Available from: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013.

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