PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ and Kamil WICHTERLE. Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties. Polyhedron. Pergamon Press, 2016, vol. 107, March, p. 89-96. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2016.01.014.
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Basic information
Original name Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties
Authors PAVELEK, Lubomír (203 Czech Republic), Vít LADÁNYI (203 Czech Republic, guarantor, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution), Silvie VALLOVÁ (203 Czech Republic) and Kamil WICHTERLE (203 Czech Republic).
Edition Polyhedron, Pergamon Press, 2016, 0277-5387.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
WWW Záznam v databázi WoS URL
Impact factor Impact factor: 1.926
RIV identification code RIV/00216224:14310/16:00089362
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1016/j.poly.2016.01.014
UT WoS 000374613700011
Keywords (in Czech) Uranyl(VI); komplexy; triazinové ligandy, rentgenová struktura, optické vlastnosti
Keywords in English Uranyl(VI); Complexes; Triazine ligands; X-ray structure; Optical properties
Tags AKR, CF SAXS, rivok
Tags International impact, Reviewed
Changed by Changed by: doc. Mgr. Marek Nečas, Ph.D., učo 18809. Changed: 13/3/2018 10:18.
Abstract
The article reports on the synthesis of three new organic ligands (s-triazine derivatives with salicylaldehyde and o-vanillin) and their complexes with uranyl(VI) salts. The uranyl(VI) complexes were characterized by single-crystal X-ray diffraction, UV–vis, fluorescence and IR spectroscopy. Thermal stabilities of the complexes were investigated using thermogravimetric analysis. The uranyl(VI) complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the uranyl(VI) ion in organic polydentate ligands.
Links
ED1.1.00/02.0068, research and development projectName: CEITEC - central european institute of technology
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