Dioxouranium complexes with pentadentate s-triazine Schiff base
ligands: Synthesis, crystal structure and optical properties

J 2016

Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ, Kamil WICHTERLE et. al.

Basic information

Original name

Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties

Authors

PAVELEK, Lubomír (203 Czech Republic), Vít LADÁNYI (203 Czech Republic, guarantor, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution), Silvie VALLOVÁ (203 Czech Republic) and Kamil WICHTERLE (203 Czech Republic)

Edition

Polyhedron, Pergamon Press, 2016, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Záznam v databázi WoS URL

Impact factor

Impact factor: 1.926

RIV identification code

RIV/00216224:14310/16:00089362

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.poly.2016.01.014

UT WoS

000374613700011

Keywords (in Czech)

Uranyl(VI); komplexy; triazinové ligandy, rentgenová struktura, optické vlastnosti

Keywords in English

Uranyl(VI); Complexes; Triazine ligands; X-ray structure; Optical properties

Abstract

V originále

The article reports on the synthesis of three new organic ligands (s-triazine derivatives with salicylaldehyde and o-vanillin) and their complexes with uranyl(VI) salts. The uranyl(VI) complexes were characterized by single-crystal X-ray diffraction, UV–vis, fluorescence and IR spectroscopy. Thermal stabilities of the complexes were investigated using thermogravimetric analysis. The uranyl(VI) complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the uranyl(VI) ion in organic polydentate ligands.

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

Citovat

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ and Kamil WICHTERLE. Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties. Polyhedron. Pergamon Press, 2016, vol. 107, March, p. 89-96. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2016.01.014.

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   author = {Pavelek, Lubomír and Ladányi, Vít and Nečas, Marek and Vallová, Silvie and Wichterle, Kamil},
   article_number = {March},
   doi = {http://dx.doi.org/10.1016/j.poly.2016.01.014},
   keywords = {Uranyl(VI); Complexes; Triazine ligands; X-ray structure; Optical properties},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties},
   url = {http://apps.webofknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=2&SID=N1ryueLHqgjaNJtWmkh&page=1&doc=1},
   volume = {107},
   year = {2016}
}

TY  - JOUR
ID  - 1334864
AU  - Pavelek, Lubomír - Ladányi, Vít - Nečas, Marek - Vallová, Silvie - Wichterle, Kamil
PY  - 2016
TI  - Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties
JF  - Polyhedron
VL  - 107
IS  - March
SP  - 89-96
EP  - 89-96
PB  - Pergamon Press
SN  - 02775387
KW  - Uranyl(VI)
KW  - Complexes
KW  - Triazine ligands
KW  - X-ray structure
KW  - Optical properties
UR  - http://apps.webofknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=2&SID=N1ryueLHqgjaNJtWmkh&page=1&doc=1
L2  - http://www.sciencedirect.com/science/article/pii/S0277538716000188
N2  - The article reports on the synthesis of three new organic ligands (s-triazine derivatives with salicylaldehyde and o-vanillin) and their complexes with uranyl(VI) salts. The uranyl(VI) complexes were characterized by single-crystal X-ray diffraction, UV–vis, fluorescence and IR spectroscopy. Thermal stabilities of the complexes were investigated using thermogravimetric analysis. The uranyl(VI) complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the uranyl(VI) ion in organic polydentate ligands.
ER  -

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ and Kamil WICHTERLE. Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties. \textit{Polyhedron}. Pergamon Press, 2016, vol.~107, March, p.~89-96. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2016.01.014.

Detailed Information on Publication Record